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Ozone anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(O3- bullet Water) + Water = (O3- bullet 2Water)

By formula: (O3- bullet H2O) + H2O = (O3- bullet 2H2O)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.2296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O3- bullet 2Water) + Water = (O3- bullet 3Water)

By formula: (O3- bullet 2H2O) + H2O = (O3- bullet 3H2O)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.5296.FAFehsenfeld and Ferguson, 1974gas phase; M

O3- + Nitrogen = (O3- bullet Nitrogen)

By formula: O3- + N2 = (O3- bullet N2)

Quantity Value Units Method Reference Comment
Deltar2.70 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.80 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

(O3- bullet Nitrogen) + Nitrogen = (O3- bullet 2Nitrogen)

By formula: (O3- bullet N2) + N2 = (O3- bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar2.6 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 2Nitrogen) + Nitrogen = (O3- bullet 3Nitrogen)

By formula: (O3- bullet 2N2) + N2 = (O3- bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar2.5 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 3Nitrogen) + Nitrogen = (O3- bullet 4Nitrogen)

By formula: (O3- bullet 3N2) + N2 = (O3- bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 4Nitrogen) + Nitrogen = (O3- bullet 5Nitrogen)

By formula: (O3- bullet 4N2) + N2 = (O3- bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar2.1 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 5Nitrogen) + Nitrogen = (O3- bullet 6Nitrogen)

By formula: (O3- bullet 5N2) + N2 = (O3- bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 6Nitrogen) + Nitrogen = (O3- bullet 7Nitrogen)

By formula: (O3- bullet 6N2) + N2 = (O3- bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 7Nitrogen) + Nitrogen = (O3- bullet 8Nitrogen)

By formula: (O3- bullet 7N2) + N2 = (O3- bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar1.7 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.5cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 8Nitrogen) + Nitrogen = (O3- bullet 9Nitrogen)

By formula: (O3- bullet 8N2) + N2 = (O3- bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar1.5 ± 0.4kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar16.9cal/mol*KPHPMSHiraoka, 1988gas phase; M

O3- + Oxygen = (O3- bullet Oxygen)

By formula: O3- + O2 = (O3- bullet O2)

Quantity Value Units Method Reference Comment
Deltar2.10 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar-3.60 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

(O3- bullet Oxygen) + Oxygen = (O3- bullet 2Oxygen)

By formula: (O3- bullet O2) + O2 = (O3- bullet 2O2)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 2Oxygen) + Oxygen = (O3- bullet 3Oxygen)

By formula: (O3- bullet 2O2) + O2 = (O3- bullet 3O2)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 3Oxygen) + Oxygen = (O3- bullet 4Oxygen)

By formula: (O3- bullet 3O2) + O2 = (O3- bullet 4O2)

Quantity Value Units Method Reference Comment
Deltar1.6 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar15.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 4Oxygen) + Oxygen = (O3- bullet 5Oxygen)

By formula: (O3- bullet 4O2) + O2 = (O3- bullet 5O2)

Quantity Value Units Method Reference Comment
Deltar1.54kcal/molPHPMSHiraoka, 1988gas phase; «DELTA»rH, «DELTA»rS approximate; M
Quantity Value Units Method Reference Comment
Deltar16.4cal/mol*KPHPMSHiraoka, 1988gas phase; «DELTA»rH, «DELTA»rS approximate; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Hiraoka, 1988
Hiraoka, K., Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]


Notes

Go To: Top, Ion clustering data, References