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Deuterium, deuteronated


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(D3+ bullet 9Deuterium) + Deuterium = (D3+ bullet 10Deuterium)

By formula: (D3+ bullet 9D2) + D2 = (D3+ bullet 10D2)

Quantity Value Units Method Reference Comment
Deltar0.6kcal/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated

(D3+ bullet 2Argon) + Argon = (D3+ bullet 3Argon)

By formula: (D3+ bullet 2Ar) + Ar = (D3+ bullet 3Ar)

Quantity Value Units Method Reference Comment
Deltar4.4 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989, 2gas phase
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KPHPMSHiraoka and Mori, 1989, 2gas phase

(D3+ bullet 3Argon) + Argon = (D3+ bullet 4Argon)

By formula: (D3+ bullet 3Ar) + Ar = (D3+ bullet 4Ar)

Quantity Value Units Method Reference Comment
Deltar2.4 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989, 2gas phase
Quantity Value Units Method Reference Comment
Deltar16.6cal/mol*KPHPMSHiraoka and Mori, 1989, 2gas phase

(D3+ bullet 4Argon) + Argon = (D3+ bullet 5Argon)

By formula: (D3+ bullet 4Ar) + Ar = (D3+ bullet 5Ar)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989, 2gas phase
Quantity Value Units Method Reference Comment
Deltar17.4cal/mol*KPHPMSHiraoka and Mori, 1989, 2gas phase

(D3+ bullet 5Argon) + Argon = (D3+ bullet 6Argon)

By formula: (D3+ bullet 5Ar) + Ar = (D3+ bullet 6Ar)

Quantity Value Units Method Reference Comment
Deltar2.2 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989, 2gas phase
Quantity Value Units Method Reference Comment
Deltar19.1cal/mol*KPHPMSHiraoka and Mori, 1989, 2gas phase

(D3+ bullet 6Argon) + Argon = (D3+ bullet 7Argon)

By formula: (D3+ bullet 6Ar) + Ar = (D3+ bullet 7Ar)

Quantity Value Units Method Reference Comment
Deltar1.6 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989, 2gas phase
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KPHPMSHiraoka and Mori, 1989, 2gas phase

(D3+ bullet Argon) + Argon = (D3+ bullet 2Argon)

By formula: (D3+ bullet Ar) + Ar = (D3+ bullet 2Ar)

Quantity Value Units Method Reference Comment
Deltar4.8 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989, 2gas phase
Quantity Value Units Method Reference Comment
Deltar17.5cal/mol*KPHPMSHiraoka and Mori, 1989, 2gas phase

(D3+ bullet 2Deuterium) + Deuterium = (D3+ bullet 3Deuterium)

By formula: (D3+ bullet 2D2) + D2 = (D3+ bullet 3D2)

Quantity Value Units Method Reference Comment
Deltar3.4 ± 0.2kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 3Deuterium) + Deuterium = (D3+ bullet 4Deuterium)

By formula: (D3+ bullet 3D2) + D2 = (D3+ bullet 4D2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 4Deuterium) + Deuterium = (D3+ bullet 5Deuterium)

By formula: (D3+ bullet 4D2) + D2 = (D3+ bullet 5D2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar19.1cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 5Deuterium) + Deuterium = (D3+ bullet 6Deuterium)

By formula: (D3+ bullet 5D2) + D2 = (D3+ bullet 6D2)

Quantity Value Units Method Reference Comment
Deltar1.7 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 6Deuterium) + Deuterium = (D3+ bullet 7Deuterium)

By formula: (D3+ bullet 6D2) + D2 = (D3+ bullet 7D2)

Quantity Value Units Method Reference Comment
Deltar0.9 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar12.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 7Deuterium) + Deuterium = (D3+ bullet 8Deuterium)

By formula: (D3+ bullet 7D2) + D2 = (D3+ bullet 8D2)

Quantity Value Units Method Reference Comment
Deltar0.8 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar15.3cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet 8Deuterium) + Deuterium = (D3+ bullet 9Deuterium)

By formula: (D3+ bullet 8D2) + D2 = (D3+ bullet 9D2)

Quantity Value Units Method Reference Comment
Deltar0.7 ± 0.1kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar19.4cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(D3+ bullet Deuterium) + Deuterium = (D3+ bullet 2Deuterium)

By formula: (D3+ bullet D2) + D2 = (D3+ bullet 2D2)

Quantity Value Units Method Reference Comment
Deltar3.5 ± 0.2kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar17.9cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

D3+ + Argon = (D3+ bullet Argon)

By formula: D3+ + Ar = (D3+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar7.0 ± 0.2kcal/molPHPMSHiraoka and Mori, 1989, 2gas phase
Quantity Value Units Method Reference Comment
Deltar14.5cal/mol*KPHPMSHiraoka and Mori, 1989, 2gas phase

D3+ + Deuterium = (D3+ bullet Deuterium)

By formula: D3+ + D2 = (D3+ bullet D2)

Quantity Value Units Method Reference Comment
Deltar7.1 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar18.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Thermochemical Stabilities of D3+(D2)n with n = 1 - 10, Chem. Phys. Lett., 1989, 157, 5, 467, https://doi.org/10.1016/0009-2614(89)87282-3 . [all data]

Hiraoka and Mori, 1989, 2
Hiraoka, K.; Mori, T., Isotope Effect and Nature of Bonding in the Cluster Ions H3+(Ar)n and D3+(Ar)n, J. Chem. Phys., 1989, 91, 8, 4821, https://doi.org/10.1063/1.456720 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References