Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Carbon hexamer

Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C6+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
4.1800 ± 0.0010LPESArnold, Zhao, et al., 1992There is a bound state at 47.107 kcal/mol up; Zhao, de Beer, et al., 1996; B
4.1850 ± 0.0060LPESArnold, Bradforth, et al., 1991Linear structure for both neutral and anion; B
<2.35 ± 0.10LPDVager, Feldman, et al., 1991Cyclic isomer, by Coulomb explosion, Zhao, de Beer, et al., 1996 claims hot ions are the source.; B
4.10 ± 0.10LPESYang, Taylor, et al., 1989EA given is Vertical Detachment Energy. probably linear structure.; B

Ionization energy determinations

IE (eV) Method Reference Comment
9.7 ± 0.2PERamathan, Zimmerman, et al., 1993LL
12.5 ± 0.3EIDibeler, Reese, et al., 1961RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold, Zhao, et al., 1992
Arnold, C.C.; Zhao, Y.X.; Kitsopoulos, T.N.; Neumark, D.M., Study of C6(-) and C6 with Threshold Photodetachment Spectroscopy and Autodetachment Spectroscopy, J. Chem. Phys., 1992, 97, 9, 6121, https://doi.org/10.1063/1.463722 . [all data]

Zhao, de Beer, et al., 1996
Zhao, Y.; de Beer, E.; Xu, C.; Taylor, T.; Neumark, D.M., Spectroscopy and Electron Detachment Dynamics of C4-, C6- and C8-, J. Chem. Phys., 1996, 105, 12, 4905, https://doi.org/10.1063/1.472341 . [all data]

Arnold, Bradforth, et al., 1991
Arnold, D.W.; Bradforth, S.E.; Kitsopoulos, T.N.; Neumark, D.M., Vibrationally Resolved Spectra of C2-C11 by Anion Photoelectron Spectroscopy, J. Chem. Phys., 1991, 95, 12, 8753, https://doi.org/10.1063/1.461211 . [all data]

Vager, Feldman, et al., 1991
Vager, Z.; Feldman, H.; Kella, D.; Malkin, E.; Miklazky, E.; Zajfman, J.; Naaman, R., The Structure of Small Carbon Clusters, Z. Phys. D, 1991, 19, 1-4, 413, https://doi.org/10.1007/BF01448341 . [all data]

Yang, Taylor, et al., 1989
Yang, S.; Taylor, K.J.; Craycraft, M.J.; Conceicao, J.; Pettiette, C.L.; Cherhnovsky, O.; Smalley, R.E., UPS of 2-30 Atom Carbon Clusters: Chains and Rings, Chem. Phys. Lett., 1989, 144, 5-6, 431, https://doi.org/10.1016/0009-2614(88)87291-9 . [all data]

Ramathan, Zimmerman, et al., 1993
Ramathan, R.; Zimmerman, J.A.; Eyler, J.R., Ionization potentials of small carbon clusters, J. Chem. Phys., 1993, 98, 7838. [all data]

Dibeler, Reese, et al., 1961
Dibeler, V.H.; Reese, R.M.; Franklin, J.L., Mass spectrometric study of cyanogen and cyanoacetylenes, J. Am. Chem. Soc., 1961, 83, 1813. [all data]


Go To: Top, Gas phase ion energetics data, References