Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Tetravanadium decaoxide


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
4.260 ± 0.030LPESZhai, Dobler, et al., 2007Vertical Detachment Energy: 4.31±0.03 eV; B
4.16 ± 0.63R-ARudnyi, Kaibicheva, et al., 1993value altered from reference due to conversion from electron convention to ion convention; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.8 ± 0.3EIBennett, Lin, et al., 1974LLK
12. ± 1.EIFarber, Uy, et al., 1972LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zhai, Dobler, et al., 2007
Zhai, H.J.; Dobler, J.; Sauer, J.; Wang, L.S., Probing the electronic structure of early transition-metal oxide clusters: Polyhedral cages of (V2O5)(n)(-) (n = 2-4) and (M2O5)(2)(-) (M = Nb, Ta), J. Am. Chem. Soc., 2007, 129, 43, 13270-13276, https://doi.org/10.1021/ja0750874 . [all data]

Rudnyi, Kaibicheva, et al., 1993
Rudnyi, E.B.; Kaibicheva, E.A.; Sidorov, L.N., Negative Ions VO2(-), VO3(-), V2O5(-), V3O8(-), and V4O10(-) in the Vapors of Vanadium Oxides - Determining Enthalpies of Formation from Equ, J. Chem. Thermodyn., 1993, 25, 8, 929, https://doi.org/10.1006/jcht.1993.1090 . [all data]

Bennett, Lin, et al., 1974
Bennett, S.L.; Lin, S.-S.; Gilles, P.W., High-temperature vaporization of ternary systems. I. Mass spectrometry of oxygen-rich vanadium-tungsten-oxygen species, J. Phys. Chem., 1974, 78, 266. [all data]

Farber, Uy, et al., 1972
Farber, M.; Uy, O.M.; Srivastava, R.D., Effusion-mass spectrometric determination of the heats of formation of the gaseous molecules V4O10, V4O8, VO2, and VO, J. Chem. Phys., 1972, 56, 5312. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References