Tetravanadium decaoxide
- Formula: O10V4
- Molecular weight: 363.7600
- CAS Registry Number: 12503-98-9
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 4.260 ± 0.030 | LPES | Zhai, Dobler, et al., 2007 | Vertical Detachment Energy: 4.31±0.03 eV; B |
| 4.16 ± 0.63 | R-A | Rudnyi, Kaibicheva, et al., 1993 | value altered from reference due to conversion from electron convention to ion convention; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.8 ± 0.3 | EI | Bennett, Lin, et al., 1974 | LLK |
| 12. ± 1. | EI | Farber, Uy, et al., 1972 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zhai, Dobler, et al., 2007
Zhai, H.J.; Dobler, J.; Sauer, J.; Wang, L.S.,
Probing the electronic structure of early transition-metal oxide clusters: Polyhedral cages of (V2O5)(n)(-) (n = 2-4) and (M2O5)(2)(-) (M = Nb, Ta),
J. Am. Chem. Soc., 2007, 129, 43, 13270-13276, https://doi.org/10.1021/ja0750874
. [all data]
Rudnyi, Kaibicheva, et al., 1993
Rudnyi, E.B.; Kaibicheva, E.A.; Sidorov, L.N.,
Negative Ions VO2(-), VO3(-), V2O5(-), V3O8(-), and V4O10(-) in the Vapors of Vanadium Oxides - Determining Enthalpies of Formation from Equ,
J. Chem. Thermodyn., 1993, 25, 8, 929, https://doi.org/10.1006/jcht.1993.1090
. [all data]
Bennett, Lin, et al., 1974
Bennett, S.L.; Lin, S.-S.; Gilles, P.W.,
High-temperature vaporization of ternary systems. I. Mass spectrometry of oxygen-rich vanadium-tungsten-oxygen species,
J. Phys. Chem., 1974, 78, 266. [all data]
Farber, Uy, et al., 1972
Farber, M.; Uy, O.M.; Srivastava, R.D.,
Effusion-mass spectrometric determination of the heats of formation of the gaseous molecules V4O10, V4O8, VO2, and VO,
J. Chem. Phys., 1972, 56, 5312. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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