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Dimethylamine

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-45. ± 2.kJ/molEqkIssoire and Long, 1960Heat of formation derived by Cox and Pilcher, 1970; ALS
Deltafliquid-49.8kJ/molCcbLemoult, 1907ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1792.kJ/molCcbMuller, 1910At 288 K; ALS
Deltacliquid-1750.kJ/molCcbLemoult, 1907ALS
Quantity Value Units Method Reference Comment
liquid173.85J/mol*KN/AAston, Eidinoff, et al., 1939Saturated liquid at boiling point.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
136.77280.44Aston, Eidinoff, et al., 1939T = 14 to 280 K. Value for saturated liquid.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Issoire and Long, 1960
Issoire, J.; Long, C., Etude de la thermodynamique chimique de la reaction de formation des methylamines, Bull. Soc. Chim. France, 1960, 2004-2012. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Lemoult, 1907
Lemoult, M.P., Recherches theoriques et experimentales sur les chaleurs de combustion et de formation des composes organiques, Ann. Chim. Phys., 1907, 12, 395-432. [all data]

Muller, 1910
Muller, J.-A., Sur les chaleurs de combustion et les poids specifiques des methylamines, Ann. Chim. Phys., 1910, 20, 116-130. [all data]

Aston, Eidinoff, et al., 1939
Aston, J.G.; Eidinoff, M.L.; Forster, W.S., The heat capacity and entropy, heats of fusion and vaporization and the vapor pressure of dimethylamine, J. Am. Chem. Soc., 1939, 61, 1539-1543. [all data]


Notes

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