Tetradecanal
- Formula: C14H28O
- Molecular weight: 212.3715
- IUPAC Standard InChI: InChI=1S/C14H28O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h14H,2-13H2,1H3
- IUPAC Standard InChIKey: UHUFTBALEZWWIH-UHFFFAOYSA-N
- CAS Registry Number: 124-25-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Myristaldehyde; Myristylaldehyde; Tetradecylaldehyde; n-Tetradecanal; Aldehyde C-14; Aldehyde C-14, myristic; C-14 Aldehyde, myristic; Myristic aldehyde; 1-Tetradecanal; 1-Tetradecyl aldehyde; NSC 66435; n-Tetradecyl aldehyde; 511542-15-7
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Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | Elite-5 MS | HP-5 | HP-5 | HP-5 MS | HP-5 MS |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | Helium | Helium | Helium | Helium |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 40. | 50. | 60. | 60. | 70. |
| Tend (C) | 220. | 300. | 240. | 220. | 290. |
| Heat rate (K/min) | 4. | 50. | 3. | 5. | 5. |
| Initial hold (min) | 5. | 2. | 10. | ||
| Final hold (min) | 5. | 10. | |||
| I | 1614. | 1613. | 1613. | 1614. | 1614. |
| Reference | Baharum, Bunawan, et al., 2010 | Bi Kouame, Bedi, et al., 2010 | Kahriman, Tosun, et al., 2010 | Ogunwande, Flamini, et al., 2010 | Radulovic, Blagojevic, et al., 2010 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | DB-5 MS | DB-5 | DB-5 | HP-1 |
| Column length (m) | 30. | 30. | 30. | 30. | 25. |
| Carrier gas | Hydrogen | Helium | Helium | Nitrogen | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.17 |
| Tstart (C) | 70. | 60. | 50. | 40. | 50. |
| Tend (C) | 290. | 240. | 250. | 230. | 260. |
| Heat rate (K/min) | 5. | 3. | 5. | 2. | 1. |
| Initial hold (min) | 2. | 5. | |||
| Final hold (min) | 5. | ||||
| I | 1615. | 1613. | 1613. | 1613. | 1593. |
| Reference | Radulovic, Dordevic, et al., 2010 | Silva, Pott, et al., 2010 | Ho, Wang, et al., 2009 | Scrivanti, Anton, et al., 2009 | Wetwiayaklung, Thavanapong, et al., 2009 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 MS | SLB-5 MS | HP-5 | HP-5 | DB-5MS |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | Helium | Nitrogen | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 50. | 50. | 50. | 70. | 60. |
| Tend (C) | 230. | 250. | 280. | 240. | 280. |
| Heat rate (K/min) | 4. | 3. | 5. | 5. | 3. |
| Initial hold (min) | 4. | 2. | 1. | ||
| Final hold (min) | 10. | 10. | 1. | 30. | |
| I | 1613. | 1614. | 1610. | 1614. | 1579. |
| Reference | Forero, Quijano, et al., 2008 | Lo Presti, Sciarrone, et al., 2008 | Saidana, Mahjoub, et al., 2008 | Asekun, Olusegun, et al., 2007 | Marongiu B., Piras A., et al., 2007 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | HP-5 MS | DB-5 | NB-30 | PE-5 |
| Column length (m) | 25. | 25. | 30. | 30. | 50. |
| Carrier gas | Helium | Helium | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.25 | 0.25 | 0.2 | 0.32 |
| Phase thickness (μm) | 0.52 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 40. | 100. | 50. | 50. | 100. |
| Tend (C) | 280. | 280. | 250. | 250. | 280. |
| Heat rate (K/min) | 4. | 4. | 4. | 2. | 3. |
| Initial hold (min) | 3. | 1. | |||
| Final hold (min) | 5. | ||||
| I | 1609. | 1617. | 1623. | 1600. | 1610. |
| Reference | Pavlovic, Petrovic, et al., 2007 | Phutdhawong, Kawaree, et al., 2007 | Najafpour Navaei, Mirza, et al., 2006 | Orav, Raal, et al., 2006 | Pandey-Rai S., Mallavarapu G.R., et al., 2006 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | DB-5 MS | DB-5MS | CP Sil 5 CB | CP Sil 5 CB |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | H2 | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 40. | 60. | 40. | 40. |
| Tend (C) | 280. | 200. | 280. | 220. | 220. |
| Heat rate (K/min) | 4. | 8. | 3. | 4. | 4. |
| Initial hold (min) | 2. | 3. | 30. | 1. | 1. |
| Final hold (min) | 10. | 20. | |||
| I | 1613. | 1618. | 1576. | 1613. | 1613. |
| Reference | Pino, Sauri-Duch, et al., 2006 | Schirack, Drake, et al., 2006 | Marongiu, Piras, et al., 2005 | Rohloff and Bones, 2005 | Rohloff and Bones, 2005 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 | DB-1 | HP-5MS | DB-1 | DB-5 |
| Column length (m) | 30. | 25. | 30. | 30. | 60. |
| Carrier gas | He | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 40. | 60. | 60. | 50. | 35. |
| Tend (C) | 260. | 180. | 280. | 265. | 280. |
| Heat rate (K/min) | 2. | 3. | 3. | 2.5 | 5. |
| Initial hold (min) | 5. | 10. | 1. | 2. | |
| Final hold (min) | 20. | 10. | 20. | 4. | |
| I | 1608. | 1617. | 1621. | 1586. | 1610. |
| Reference | Senatore, Apostolides Arnold, et al., 2005 | bin Jantan, Ayop, et al., 2004 | Malencic, Couladis, et al., 2004 | Sarkhail, Amin, et al., 2004 | Dhanda, Pegg, et al., 2003 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | HP-1 | DB-1 | DB-5 | DB-5 |
| Column length (m) | 30. | 50. | 30. | 30. | 30. |
| Carrier gas | He | He | H2 | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.2 | 0.32 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.5 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 60. | 40. | 60. | 60. |
| Tend (C) | 280. | 220. | 245. | 250. | 300. |
| Heat rate (K/min) | 4. | 2. | 3. | 3. | 2. |
| Initial hold (min) | 20. | ||||
| Final hold (min) | 40. | ||||
| I | 1607. | 1586. | 1584. | 1606. | 1607. |
| Reference | Sajjadi and Mehregan, 2003 | Valette, Fernandez, et al., 2003 | Gancel, Ollé, et al., 2002 | Limberger, Simões-Pires, et al., 2002 | Ruberto, Biondi, et al., 2002 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | SPB-5 | DB-5 | OV-101 | Ultra-2 |
| Column length (m) | 30. | 60. | 30. | 50. | 50. |
| Carrier gas | H2 | He | N2 | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.32 | 0.25 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.25 | 1. | 0.25 | 0.52 | |
| Tstart (C) | 40. | 40. | 140. | 80. | 40. |
| Tend (C) | 280. | 200. | 240. | 200. | 250. |
| Heat rate (K/min) | 4. | 3. | 5. | 2. | 4. |
| Initial hold (min) | 3. | ||||
| Final hold (min) | 30. | ||||
| I | 1611. | 1616. | 1610.8 | 1592. | 1619. |
| Reference | Velickovic, Randjelovic, et al., 2002 | Poligné, Collignan, et al., 2001 | Svatos, Kalinová, et al., 2001 | Yang, 2001 | King, Matthews, et al., 1995 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | Cross-Linked Methylsilicone | Ultra-2 | OV-101 | OV-101 | DB-5 |
| Column length (m) | 25. | 50. | 50. | 50. | 60. |
| Carrier gas | He | He | He | ||
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.52 | 1.0 | |||
| Tstart (C) | 35. | 40. | 80. | 80. | 40. |
| Tend (C) | 225. | 250. | 200. | 200. | 240. |
| Heat rate (K/min) | 4. | 4. | 2. | 2. | 3. |
| Initial hold (min) | 3. | 3. | |||
| Final hold (min) | 30. | ||||
| I | 1584. | 1614. | 1591. | 1592. | 1610. |
| Reference | Bravo and Hotchkiss, 1993 | King, Hamilton, et al., 1993 | Tamura, Yang, et al., 1993 | Tamura, Yang, et al., 1993 | Berdague, Denoyer, et al., 1991 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 | CP Sil 8 CB | OV-101 | OV-101 | OV-101 |
| Column length (m) | 60. | 25. | 50. | 50. | 50. |
| Carrier gas | Nitrogen | Nitrogen | N2 | ||
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.20 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | ||||
| Tstart (C) | 40. | 60. | 70. | 80. | 80. |
| Tend (C) | 250. | 230. | 200. | 200. | 200. |
| Heat rate (K/min) | 2. | 3. | 2. | 2. | 2. |
| Initial hold (min) | 5. | 10. | |||
| Final hold (min) | |||||
| I | 1614. | 1579. | 1591. | 1595. | 1591. |
| Reference | Lee, Macku, et al., 1991 | Jantan and Goh, 1990 | Sugisawa, Nakamura, et al., 1990 | Sugisawa, Nakamura, et al., 1990 | Yang and Sugisawa, 1990 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | OV-101 | OV-101 | OV-101 | OV-101 | OV-101 |
| Column length (m) | 50. | 50. | 50. | 50. | 50. |
| Carrier gas | N2 | N2 | N2 | N2 | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.32 |
| Phase thickness (μm) | |||||
| Tstart (C) | 80. | 80. | 80. | 80. | 40. |
| Tend (C) | 200. | 200. | 200. | 200. | 225. |
| Heat rate (K/min) | 2. | 2. | 2. | 2. | 4. |
| Initial hold (min) | 0.1 | ||||
| Final hold (min) | 30. | ||||
| I | 1591. | 1591. | 1593. | 1594. | 1592. |
| Reference | Yang and Sugisawa, 1990 | Sugisawa, Yamamoto, et al., 1989 | Sugisawa, Yang, et al., 1989 | Sugisawa, Yang, et al., 1989 | Stern, Flath, et al., 1985 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary |
|---|---|---|---|
| Active phase | OV-101 | Methyl Silicone | Methyl Silicone |
| Column length (m) | 50. | 25. | 25. |
| Carrier gas | |||
| Substrate | |||
| Column diameter (mm) | 0.32 | 0.2 | 0.2 |
| Phase thickness (μm) | |||
| Tstart (C) | 50. | 80. | 80. |
| Tend (C) | 225. | 225. | 225. |
| Heat rate (K/min) | 4. | 4. | 4. |
| Initial hold (min) | 0.1 | ||
| Final hold (min) | 30. | 20. | 20. |
| I | 1591. | 1592. | 1595. |
| Reference | Stern, Flath, et al., 1985 | Lorenz, Stern, et al., 1983 | Lorenz, Stern, et al., 1983 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Baharum, Bunawan, et al., 2010
Baharum, S.N.; Bunawan, H.; Ghani, M.A.; Mustafa, W.A.W.; Noor, N.M.,
Analysis of the chemical composition of the essential oil of Polygonum minus Huds. using two-dimensional gas chromatography - time of flight mass spectrometry (GC-TOF-MS),
Molecules, 2010, 15, 10, 7006-7015, https://doi.org/10.3390/molecules15107006
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Bi Kouame, Bedi, et al., 2010
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Kahriman, Tosun, et al., 2010
Kahriman, N.; Tosun, G.; Genc, H.; Yayli, N.,
Comparative essential oil analysis of Geranium sylvaticum estracted by hydrodistillation and microwave distillation,
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Ogunwande, Flamini, et al., 2010
Ogunwande, I.A.; Flamini, G.; Cioni, P.L.; Omikorede, O.; Azeez, R.A.; Ayodele, A.A.; Kamil, Y.O.,
Aromatic plants growing in Nigeria: essential oil constituents of Cassia alata (Linn.) Roxb. and Helianthus annuus L.,
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Essential oil compositions and bioactivities of the various parts of Cinnamomum camphora Sieb. var. linallolifera Fujuta,
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Ruberto, Biondi, et al., 2002
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Sugisawa, Yang, et al., 1989
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. [all data]
Notes
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