Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Decane

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-249.7 ± 1.1kJ/molCcbProsen and Rossini, 1945ALS
Quantity Value Units Method Reference Comment
gas545.8 ± 1.1J/mol*KN/AScott D.W., 1974This reference does not contain the original experimental data. Experimental entropy value is based on the results [ Messerly J.F., 1967] for S(liquid).; GT

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
179.08200.Scott D.W., 1974, 2Recommended values were obtained from the consistent correlation scheme for alkanes [ Scott D.W., 1974, Scott D.W., 1974, 2]. This approach gives a good agreement with experimental data available for alkanes. However, large uncertainties could be expected at high temperatures.; GT
217.90273.15
233.1 ± 0.6298.15
234.18300.
297.98400.
356.43500.
405.85600.
446.43700.
479.90800.
508.36900.
531.791000.
551.871100.
569.441200.
585.761300.
598.311400.
610.861500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-301.0 ± 1.1kJ/molCcbProsen and Rossini, 1945ALS
Quantity Value Units Method Reference Comment
Deltacliquid-6778.33 ± 0.88kJ/molCcbProsen and Rossini, 1945Corresponding «DELTA»fliquid = -300.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-6778.6 ± 1.5kJ/molCcbProsen and Rossini, 1944Corresponding «DELTA»fliquid = -300.6 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-6774.2kJ/molCcbJessup, 1937Corresponding «DELTA»fliquid = -305.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid425.89J/mol*KN/AFinke, Gross, et al., 1954DH
liquid428.9J/mol*KN/AHuffman, Parks, et al., 1931Extrapolation below 90 K, 92.05 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
314.45298.9Czarnota, 1993p = 0.1 MPa.; DH
323.87318.15Banipal, Garg, et al., 1991T = 313 to 373 K. p = 0.1 MPa.; DH
315.46298.15Trejo, Costas, et al., 1991DH
315.46298.15Andreoli-Ball, Patterson, et al., 1988DH
315.32298.15Costas, Huu, et al., 1988DH
315.0298.23Kuznetsov, Kharin, et al., 1988T = 293 to 420 K. p = 0.1 MPa. Unsmoothed experimental datum given as 2.214 kJ/kg*K.; DH
313.46298.15Perez-Casas, Aicart, et al., 1988DH
313.13298.15Pintos, Bravo, et al., 1988DH
315.46298.15Wilhelm, Inglese, et al., 1987DH
313.56298.15Gates, Wood, et al., 1986T = 298.15 to 368.15 K.; DH
315.46298.15Tardajos, Aicart, et al., 1986DH
313.24298.15Baluja, Bravo, et al., 1985DH
314.82298.15Costas and Patterson, 1985T = 283.15, 298.15, 313.15 K.; DH
312.99298.15Lainez, Rodrigo, et al., 1985DH
313.09298.15Lainez, Roux-Desgranges, et al., 1985DH
313.09298.15Lainez, Wilhelm, et al., 1985DH
313.93298.15Grolier, Inglese, et al., 1984DH
314.21298.15Roux, Grolier, et al., 1984DH
310.26293.15Siddiqi, Svejda, et al., 1983DH
312.5298.15Wilhelm, Inglese, et al., 1982DH
312.8298.Zaripov, 1982T = 298, 323, 363 K.; DH
313.3298.15Grolier, Hamedi, et al., 1979DH
311.7298.Grigor'ev, Rastorguev, et al., 1975T = 300 to 463 K.; DH
314.47298.15Finke, Gross, et al., 1954T = 12 to 300 K.; DH
312.29299.8Schlinger and Sage, 1952T = 80 to 200°F.; DH
313.97298.15Osborne and Ginnings, 1947T = 278 to 318 K.; DH
311.3297.7Huffman, Parks, et al., 1931T = 91 to 298 K. Value is unsmoothed experimental datum.; DH
309.6295.5Parks, Huffman, et al., 1930T = 242 to 296 K. Value is unsmoothed experimental datum.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + 1-Decene = Decane

By formula: H2 + C10H20 = C10H22

Quantity Value Units Method Reference Comment
Deltar-124.2 ± 1.2kJ/molChydRogers and Skanupong, 1974liquid phase; solvent: Hexane
Deltar-125.1 ± 1.3kJ/molChydBretschneider and Rogers, 1970liquid phase; solvent: galcial acetic acid

3Hydrogen + 3-Decen-1-yne, (Z)- = Decane

By formula: 3H2 + C10H16 = C10H22

Quantity Value Units Method Reference Comment
Deltar-400. ± 2.kJ/molChydSkinner and Snelson, 1959liquid phase; solvent: Acetic acid

3Hydrogen + 3-Decen-1-yne, (E)- = Decane

By formula: 3H2 + C10H16 = C10H22

Quantity Value Units Method Reference Comment
Deltar-401.3 ± 0.8kJ/molChydSkinner and Snelson, 1959liquid phase; solvent: Acetic acid

Hydrogen + (Z)-5-Decene = Decane

By formula: H2 + C10H20 = C10H22

Quantity Value Units Method Reference Comment
Deltar-119.5 ± 1.5kJ/molChydRogers and Siddiqui, 1975liquid phase; solvent: n-Hexane

2Hydrogen + 2-Decyne = Decane

By formula: 2H2 + C10H18 = C10H22

Quantity Value Units Method Reference Comment
Deltar-273.1 ± 2.1kJ/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

2Hydrogen + 3-Decyne = Decane

By formula: 2H2 + C10H18 = C10H22

Quantity Value Units Method Reference Comment
Deltar-271.4 ± 2.0kJ/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

2Hydrogen + 4-Decyne = Decane

By formula: 2H2 + C10H18 = C10H22

Quantity Value Units Method Reference Comment
Deltar-269.4 ± 1.7kJ/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

2Hydrogen + 5-Decyne = Decane

By formula: 2H2 + C10H18 = C10H22

Quantity Value Units Method Reference Comment
Deltar-268.2 ± 2.0kJ/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

2Hydrogen + 1-Decyne = Decane

By formula: 2H2 + C10H18 = C10H22

Quantity Value Units Method Reference Comment
Deltar-291.4 ± 2.1kJ/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Prosen and Rossini, 1945
Prosen, E.J.; Rossini, F.D., Heats of combustion and formation of the paraffin hydrocarbons at 25° C, J. Res. NBS, 1945, 263-267. [all data]

Scott D.W., 1974
Scott D.W., Correlation of the chemical thermodynamic properties of alkane hydrocarbons, J. Chem. Phys., 1974, 60, 3144-3165. [all data]

Messerly J.F., 1967
Messerly J.F., Low-temperature thermal data for n-pentane, n-heptadecane, and n-octadecane. Revised thermodynamic functions for the n-alkanes, C5-C18, J. Chem. Eng. Data, 1967, 12, 338-346. [all data]

Scott D.W., 1974, 2
Scott D.W., Chemical Thermodynamic Properties of Hydrocarbons and Related Substances. Properties of the Alkane Hydrocarbons, C1 through C10 in the Ideal Gas State from 0 to 1500 K. U.S. Bureau of Mines, Bulletin 666, 1974. [all data]

Prosen and Rossini, 1944
Prosen, E.J.; Rossini, F.D., Heats of combustion of eight normal paraffin hydrocarbons in the liquid state, J. Res. NBS, 1944, 33, 255-272. [all data]

Jessup, 1937
Jessup, R.S., Heats of combustion of the liquid normal paraffin hydrocarbons from hexane to dodecane, J. Res. NBS, 1937, 18, 114-128. [all data]

Finke, Gross, et al., 1954
Finke, H.L.; Gross, M.E.; Waddington, G.; Huffman, H.M., Low-temperature thermal data for the nine normal paraffin hydrocarbons from octane to hexadecane, J. Am. Chem. Soc., 1954, 76, 333-341. [all data]

Huffman, Parks, et al., 1931
Huffman, H.M.; Parks, G.S.; Barmore, M., Thermal data on organic compounds. X. Further studies on the heat capacities, entropies and free energies of hydrocarbons, J. Am. Chem. Soc., 1931, 53, 3876-3888. [all data]

Czarnota, 1993
Czarnota, I., Heat capacity of decane at high pressures, J. Chem. Thermodynam., 1993, 25, 639-642. [all data]

Banipal, Garg, et al., 1991
Banipal, T.S.; Garg, S.K.; Ahluwalia, J.C., Heat capacities and densities of liquid n-octane, n-nonane, n-decane, and n-hexadecane at temperatures from 318.15 to 373.15 K and at pressures up to 10 MPa, J. Chem. Thermodynam., 1991, 23, 923-931. [all data]

Trejo, Costas, et al., 1991
Trejo, L.M.; Costas, M.; Patterson, D., Excess heat capacity of organic mixtures, Internat. DATA Series, Selected Data Mixt., 1991, Ser. [all data]

Andreoli-Ball, Patterson, et al., 1988
Andreoli-Ball, L.; Patterson, D.; Costas, M.; Caceres-Alonso, M., Heat capacity and corresponding states in alkan-1-ol-n-alkane systems, J. Chem. Soc., Faraday Trans. 1, 1988, 84(11), 3991-4012. [all data]

Costas, Huu, et al., 1988
Costas, M.; Huu, V.T.; Patterson, D.; Caceres-Alonso, M.; Tardajos, G.; Aicart, E., Liquid structure and second-order mixing functions for l-chloronaphthalene with linear and branched alkanes, J. Chem. Soc., Faraday Trans., 1988, 1 84(5), 1603-1616. [all data]

Kuznetsov, Kharin, et al., 1988
Kuznetsov, M.A.; Kharin, V.E.; Gerasimov, A.A.; Grigor'ev, M.D., Isobaric heat capacity of n-alkanes C7 to C10 at temperatures 293 to 630 K and pressures up to 60 MPa, Izv. Vyssh. Ucheb. Zabed., Neft i Gaz, 1988, 31(11), 49-52. [all data]

Perez-Casas, Aicart, et al., 1988
Perez-Casas, S.; Aicart, E.; Trojo, L.M.; Costas, M., Excess heat capacity. Chlorobenzene-2,2,4,4,6,8,8-heptamethylnonane, Int. Data Ser., Sel. Data Mixtures, 1988, (2)A, 123. [all data]

Pintos, Bravo, et al., 1988
Pintos, M.; Bravo, R.; Baluja, M.C.; Paz Andrade, M.I.; Roux-Desgranges, G.; Grolier, J.-P.E., Can. J. Chem., 1988, 1179. [all data]

Wilhelm, Inglese, et al., 1987
Wilhelm, E.; Inglese, A.; Roux, A.H.; Grolier, J.-P.E., Excess enthalpy, excess heat capacity and excess volume of 1,2,4-trimethylbenzene +, and 1-methylnaphthalene + an n-alkane, Fluid Phase Equilibria, 1987, 34, 49-67. [all data]

Gates, Wood, et al., 1986
Gates, J.A.; Wood, R.H.; Cobos, J.C.; Casanova, C.; Roux, A.H.; Roux-Desgranges, G.; Grolier, J.-P.E., Densities and heat capacities of 1-butanol + n-decane from 298 K to 400 K, Fluid Phase Equilib., 1986, 27, 137-151. [all data]

Tardajos, Aicart, et al., 1986
Tardajos, G.; Aicart, E.; Costas, M.; Patterson, D., Liquid structure and second-order mixing functions for benzene, toluene, and p-xylene with n-alkanes, J. Chem. Soc., Faraday Trans., 1986, 1 82, 2977-2987. [all data]

Baluja, Bravo, et al., 1985
Baluja, M.C.; Bravo, R.; Pintos, M.; Paz Andrade, M.I.; Roux-Desgranges, G.; Grolier, J.-P.E., Unusual dependence on concentration of the excess heat capacities of ester solutions in alkanes, Calorim. Anal. Therm., 1985, 16, 138-144. [all data]

Costas and Patterson, 1985
Costas, M.; Patterson, D., Self-association of alcohols in inert solvents, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 635-654. [all data]

Lainez, Rodrigo, et al., 1985
Lainez, A.; Rodrigo, M.; Roux, A.H.; Grolier, J.-P.E.; Wilhelm, E., Relations between structure and thermodynamic properties. Heat capacities of polar substances (nitrobenzene and benzonitrile) in alkane solutions, Calorim. Anal. Therm., 1985, 16, 153-158. [all data]

Lainez, Roux-Desgranges, et al., 1985
Lainez, A.; Roux-Desgranges, G.; Grolier, J.-P.E.; Wilhelm, E., Mixtures of alkanes with polar molecules showing integral rotation: an unusual composition dependence of CpE of 1,2-dichloroethane + an n-alkane, Fluid Phase Equilib., 1985, 20, 47-56. [all data]

Lainez, Wilhelm, et al., 1985
Lainez, A.; Wilhelm, E.; Roux-Desgranges, G.; Grolier, J.-P.E., Excess molar quantities of (a halogenated n-alkane + an n-alkane). A comparative study of mixtures containing either 1-chlorobutane or 1,4-dichlorobutane, J. Chem. Thermodynam., 1985, 17, 1153-1161. [all data]

Grolier, Inglese, et al., 1984
Grolier, J.-P.E.; Inglese, A.; Wilhelm, E., Excess molar heat capacities of (1,4-dioxane + an n-alkane): an unusual composition dependence, J. Chem. Thermodynam., 1984, 16, 67-71. [all data]

Roux, Grolier, et al., 1984
Roux, A.H.; Grolier, J.-P.E.; Inglese, A.; Wilhelm, E., Excess molar enthalpies, excess molar heat capacities and excess molar volumes of (fluorobenzene + an n-alkane), Ber. Bunsenges. Phys. Chem., 1984, 88, 986-992. [all data]

Siddiqi, Svejda, et al., 1983
Siddiqi, M.A.; Svejda, P.; Kohler, F., A generalized van der Waals equation of state II. Excess heat capacities of mixtures containing cycloalkanes (C5,C6), methylcycloalkanes (C5,C6) and n-decane, Ber. Bunsenges. Phys. Chem., 1983, 87, 1176-1181. [all data]

Wilhelm, Inglese, et al., 1982
Wilhelm, E.; Inglese, A.; Quint, J.R.; Grolier, J.-P.E., Molar excess volumes and excess heat capacities of (1,2,4-trichlorobenzene + an alkane), J. Chem. Thermodynam., 1982, 14, 303-308. [all data]

Zaripov, 1982
Zaripov, Z.I., Experimental study of the isobaric heat capacity of liquid organic compounds with molecular weights of up to 4000 a.e.m., 1982, Teplomassoobmen Teplofiz. [all data]

Grolier, Hamedi, et al., 1979
Grolier, J-P.E.; Hamedi, M.H.; Wilhelm, E.; Kehiaian, H.V., Excess heat capacities of binary mixtures of carbon tetrachloride with n-alkanes at 298.15 K, Thermochim. Acta, 1979, 31, 79-84. [all data]

Grigor'ev, Rastorguev, et al., 1975
Grigor'ev, B.A.; Rastorguev, Yu.L.; Yanin, G.S., Experimental determination of the isobaric specific heat of n-alkanes, Iz. Vyssh. Uchebn. Zaved. Neft Gaz 18, 1975, No.10, 63-66. [all data]

Schlinger and Sage, 1952
Schlinger, W.G.; Sage, B.H., Isobaric heat capacities at bubble point. cis-2-butene, isopropylbenzene, and n-decane, Ind. Eng. Chem., 1952, 44, 2454-2456. [all data]

Osborne and Ginnings, 1947
Osborne, N.S.; Ginnings, D.C., Measurements of heat of vaporization and heat capacity of a number of hydrocarbons, J. Res. NBS, 1947, 39, 453-477. [all data]

Parks, Huffman, et al., 1930
Parks, G.S.; Huffman, H.M.; Thomas, S.B., Thermal data on organic compounds. VI. The heat capacities, entropies and free energies of some saturated, non-benzenoid hydrocarbons, J. Am. Chem. Soc., 1930, 52, 1032-1041. [all data]

Rogers and Skanupong, 1974
Rogers, D.W.; Skanupong, S., Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect, J. Phys. Chem., 1974, 78, 2569-2572. [all data]

Bretschneider and Rogers, 1970
Bretschneider, E.; Rogers, D.W., A new microcalorimeter: heats of hydrogenation of four monoolefins, Mikrochim. Acta, 1970, 482-490. [all data]

Skinner and Snelson, 1959
Skinner, H.A.; Snelson, A., Heats of hydrogenation Part 3., Trans. Faraday Soc., 1959, 55, 405-407. [all data]

Rogers and Siddiqui, 1975
Rogers, D.W.; Siddiqui, N.A., Heats of hydrogenation of large molecules. I. Esters of unsaturated fatty acids, J. Phys. Chem., 1975, 79, 574-577. [all data]

Rogers, Dagdagan, et al., 1979
Rogers, D.W.; Dagdagan, O.A.; Allinger, N.L., Heats of hydrogenation and formation of linear alkynes and a molecular mechanics interpretation, J. Am. Chem. Soc., 1979, 101, 671-676. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References