Hydrogen cation
- Formula: H+
- Molecular weight: 1.00739
- IUPAC Standard InChIKey: GPRLSGONYQIRFK-UHFFFAOYSA-N
- CAS Registry Number: 12408-02-5
- Chemical structure:
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- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 250, reactions 251 to 300, reactions 301 to 350, reactions 351 to 400, reactions 401 to 450, reactions 451 to 500, reactions 501 to 550, reactions 551 to 600, reactions 601 to 650, reactions 651 to 700, reactions 701 to 750, reactions 801 to 850, reactions 851 to 900, reactions 901 to 950, reactions 951 to 1000, reactions 1001 to 1050, reactions 1051 to 1100, reactions 1101 to 1150, reactions 1151 to 1200, reactions 1201 to 1250, reactions 1251 to 1300, reactions 1301 to 1350, reactions 1351 to 1375
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 751 to 800
C4H4NO2- + =
By formula: C4H4NO2- + H+ = C4H5NO2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1445. ± 9.6 | kJ/mol | G+TS | Cumming and Kebarle, 1978 | gas phase |
ΔrH° | 1379. ± 19. | kJ/mol | EIAE | Cooper and Compton, 1973 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1414. ± 8.4 | kJ/mol | IMRE | Cumming and Kebarle, 1978 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1529.4 ± 0.71 | kJ/mol | D-EA | Scheer, Bilodeau, et al., 1998 | gas phase; Given: 1.262119(20) eV |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1506.2 ± 1.1 | kJ/mol | H-TS | Scheer, Bilodeau, et al., 1998 | gas phase; Given: 1.262119(20) eV |
Li- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1489.5 ± 0.42 | kJ/mol | D-EA | Haeffler, Hanstorp, et al., 1996 | gas phase; Given: 0.618049(20) eV |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1468.1 ± 1.3 | kJ/mol | H-TS | Haeffler, Hanstorp, et al., 1996 | gas phase; Given: 0.618049(20) eV |
C4H7O- + =
By formula: C4H7O- + H+ = C4H8O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1564. ± 12. | kJ/mol | G+TS | Graul, Schnute, et al., 1990 | gas phase; Mixture of cis and trans isomers |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1536. ± 12. | kJ/mol | CIDC | Graul, Schnute, et al., 1990 | gas phase; Mixture of cis and trans isomers |
C5H9O- + =
By formula: C5H9O- + H+ = C5H10O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1542. ± 9.2 | kJ/mol | G+TS | Cumming and Kebarle, 1978 | gas phase |
ΔrH° | 1518. ± 9.6 | kJ/mol | D-EA | Zimmerman, Reed, et al., 1977 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1512. ± 8.4 | kJ/mol | IMRE | Cumming and Kebarle, 1978 | gas phase |
C2H7Si- + =
By formula: C2H7Si- + H+ = C2H8Si
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1643. ± 26. | kJ/mol | G+TS | Damrauer, Kass, et al., 1988 | gas phase; Between Me2NH and fluorobenzene |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1607. ± 25. | kJ/mol | IMRB | Damrauer, Kass, et al., 1988 | gas phase; Between Me2NH and fluorobenzene |
By formula: CH4AlO2- + H+ = CH5AlO2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1502. ± 17. | kJ/mol | G+TS | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH and pyrrole. |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH and pyrrole. |
C5H4N3O2- + =
By formula: C5H4N3O2- + H+ = C5H5N3O2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1429. ± 12. | kJ/mol | G+TS | Breuker, Knochenmuss, et al., 1999 | gas phase; Acid: 2-amino-5-nitropyridine |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1399. ± 11. | kJ/mol | IMRB | Breuker, Knochenmuss, et al., 1999 | gas phase; Acid: 2-amino-5-nitropyridine |
C3HF6O- + =
By formula: C3HF6O- + H+ = C3H2F6O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1443. ± 8.8 | kJ/mol | G+TS | Taft, Koppel, et al., 1990 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1416. ± 8.4 | kJ/mol | IMRE | Taft, Koppel, et al., 1990 | gas phase |
ΔrG° | 1424.2 | kJ/mol | IMRB | Koppel, Pikver, et al., 1981 | gas phase |
By formula: C2H6AlO- + H+ = C2H7AlO
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1504. ± 17. | kJ/mol | G+TS | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH and pyrrole. |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Krempp, et al., 1991 | gas phase; Between CF3CH2OH and pyrrole. |
C7H6I- + =
By formula: C7H6I- + H+ = C7H7I
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1556. ± 8.8 | kJ/mol | G+TS | Poutsma, Nash, et al., 1997 | gas phase; between tBuCH(Me)OH, FCH2CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1525. ± 8.4 | kJ/mol | IMRB | Poutsma, Nash, et al., 1997 | gas phase; between tBuCH(Me)OH, FCH2CH2OH |
C5H7- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1613. ± 21. | kJ/mol | G+TS | Bartmess and McIver Jr., 1979 | gas phase; Between H2O, MeOH. Acid: isoprene |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1586. ± 21. | kJ/mol | IMRB | Bartmess and McIver Jr., 1979 | gas phase; Between H2O, MeOH. Acid: isoprene |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1511.6 ± 0.63 | kJ/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1484.0 ± 1.4 | kJ/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion |
C8H5- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1608. ± 21. | kJ/mol | G+TS | Broadus and Kass, 2000 | gas phase; between PhF, 1,3-diazine |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1574. ± 21. | kJ/mol | IMRB | Broadus and Kass, 2000 | gas phase; between PhF, 1,3-diazine |
By formula: C2H5S2- + H+ = C2H6S2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1466. ± 17. | kJ/mol | G+TS | Grabowski and Zhang, 1989 | gas phase; Acidity between H2S, MeCO2H. |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1435. ± 17. | kJ/mol | IMRB | Grabowski and Zhang, 1989 | gas phase; Acidity between H2S, MeCO2H. |
By formula: HOSi- + H+ = H2OSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1521. ± 34. | kJ/mol | G+TS | Gronert, O'Hair, et al., 1990 | gas phase; Between acetone, nitromethane |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1490. ± 33. | kJ/mol | IMRB | Gronert, O'Hair, et al., 1990 | gas phase; Between acetone, nitromethane |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1490. ± 13. | kJ/mol | G+TS | O'Hair, Krempp, et al., 1992 | gas phase; Acidity between MeNO2, tBuSH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1456. ± 13. | kJ/mol | IMRB | O'Hair, Krempp, et al., 1992 | gas phase; Acidity between MeNO2, tBuSH |
C3H4Br- + =
By formula: C3H4Br- + H+ = C3H5Br
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1570. ± 8.8 | kJ/mol | G+TS | Poutsma, Nash, et al., 1997 | gas phase; Between iPrOH, HF; near tBuOH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1540. ± 8.4 | kJ/mol | IMRB | Poutsma, Nash, et al., 1997 | gas phase; Between iPrOH, HF; near tBuOH |
C6H3Cl2- + =
By formula: C6H3Cl2- + H+ = C6H4Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1577. ± 8.8 | kJ/mol | G+TS | Schlosser, Marzi, et al., 2001 | gas phase; Acid: p-dichlorobenzene. |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1543. ± 8.4 | kJ/mol | IMRE | Schlosser, Marzi, et al., 2001 | gas phase; Acid: p-dichlorobenzene. |
K- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1439.840 ± 0.042 | kJ/mol | D-EA | Andersson, Sandstrom, et al., 2000 | gas phase; Given: 0.501459(12) eV |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1420.4 ± 1.3 | kJ/mol | H-TS | Andersson, Sandstrom, et al., 2000 | gas phase; Given: 0.501459(12) eV |
C8H9- + =
By formula: C8H9- + H+ = C8H10
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1482. ± 13. | kJ/mol | G+TS | Brickhouse and Squires, 1988 | gas phase; Acidity between nPrSH, iPrSH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1454. ± 13. | kJ/mol | IMRB | Brickhouse and Squires, 1988 | gas phase; Acidity between nPrSH, iPrSH |
By formula: C3F6NO3S- + H+ = C3HF6NO3S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1248. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299 |
C6F12NO3S- + = C6HF12NO3S
By formula: C6F12NO3S- + H+ = C6HF12NO3S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1242. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299 |
C9F18NO3S- + = C9HF18NO3S
By formula: C9F18NO3S- + H+ = C9HF18NO3S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1234. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299 |
C6F12NO3S- + = C6HF12NO3S
By formula: C6F12NO3S- + H+ = C6HF12NO3S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1233. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299 |
C8F16NO3S- + = C8HF16NO3S
By formula: C8F16NO3S- + H+ = C8HF16NO3S
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1231. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299 |
By formula: C13F21O3- + H+ = C13HF21O3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 1250. ± 8.4 | kJ/mol | IMRE | Koppel, Taft, et al., 1994 | gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299 |
By formula: C2NO2- + H+ = C2HNO2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1490. ± 18. | kJ/mol | G+TS | Schmitt, Krempp, et al., 1992 | gas phase; acidity between MeSH, tBuSH. |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1457. ± 18. | kJ/mol | IMRB | Schmitt, Krempp, et al., 1992 | gas phase; acidity between MeSH, tBuSH. |
By formula: H3FNSi- + H+ = H4FNSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1563. ± 13. | kJ/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between MeCN, nHxOH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1531. ± 13. | kJ/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between MeCN, nHxOH |
By formula: C6H8NSi- + H+ = C6H9NSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1563. ± 13. | kJ/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between MeCN, nHxOH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1531. ± 13. | kJ/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between MeCN, nHxOH |
Ge- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1457. ± 21. | kJ/mol | D-EA | Scheer, Bilodeau, et al., 1998 | gas phase; Given: 1.232712(15) eV |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1434. ± 22. | kJ/mol | H-TS | Scheer, Bilodeau, et al., 1998 | gas phase; Given: 1.232712(15) eV |
By formula: H4NSi- + H+ = H5NSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1571. ± 13. | kJ/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nBuOH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1540. ± 13. | kJ/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nBuOH |
By formula: CH6NOSi- + H+ = CH7NOSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1571. ± 13. | kJ/mol | G+TS | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nPrOH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1540. ± 13. | kJ/mol | IMRB | Krempp and Damrauer, 1995 | gas phase; Acidity between EtCN, nPrOH |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1436.7 ± 2.1 | kJ/mol | D-EA | Frey, Breyer, et al., 1978 | gas phase; Given: 3919.18(16) cm-1 |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1417.4 ± 2.4 | kJ/mol | H-TS | Frey, Breyer, et al., 1978 | gas phase; Given: 3919.18(16) cm-1 |
By formula: C3H9O2Si- + H+ = C3H10O2Si
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1502. ± 17. | kJ/mol | G+TS | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1488. ± 17. | kJ/mol | G+TS | O'Hair, Krempp, et al., 1992 | gas phase; Acidity between MeSH, H2S |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1456. ± 17. | kJ/mol | IMRB | O'Hair, Krempp, et al., 1992 | gas phase; Acidity between MeSH, H2S |
C2H4NO2- + =
By formula: C2H4NO2- + H+ = C2H5NO2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1449. ± 9.6 | kJ/mol | G+TS | Decouzon, Exner, et al., 1990 | gas phase; Acid: Acetohydroxamic acid |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1419. ± 8.4 | kJ/mol | IMRE | Decouzon, Exner, et al., 1990 | gas phase; Acid: Acetohydroxamic acid |
By formula: CH2NO2- + H+ = CH3NO2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1538. ± 8.8 | kJ/mol | G+TS | Thomas, Bloor, et al., 1990 | gas phase; Between PhCH2OH, acetoxime |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1510. ± 8.4 | kJ/mol | IMRB | Thomas, Bloor, et al., 1990 | gas phase; Between PhCH2OH, acetoxime |
By formula: C5H13OSi- + H+ = C5H14OSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1502. ± 17. | kJ/mol | G+TS | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
By formula: CH5OSi- + H+ = CH6OSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1502. ± 17. | kJ/mol | G+TS | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
C7H6I- + =
By formula: C7H6I- + H+ = C7H7I
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1557. ± 13. | kJ/mol | G+TS | Wenthold, Wierschke, et al., 1994 | gas phase; Between MeCN and FCH2CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1527. ± 13. | kJ/mol | IMRB | Wenthold, Wierschke, et al., 1994 | gas phase; Between MeCN and FCH2CH2OH |
C7H6I- + =
By formula: C7H6I- + H+ = C7H7I
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1557. ± 13. | kJ/mol | G+TS | Wenthold, Wierschke, et al., 1994 | gas phase; Between MeCN and FCH2CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1527. ± 13. | kJ/mol | IMRB | Wenthold, Wierschke, et al., 1994 | gas phase; Between MeCN and FCH2CH2OH |
C7H6I- + =
By formula: C7H6I- + H+ = C7H7I
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1558. ± 13. | kJ/mol | G+TS | Wenthold, Wierschke, et al., 1994 | gas phase; Between MeCN and FCH2CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1527. ± 13. | kJ/mol | IMRB | Wenthold, Wierschke, et al., 1994 | gas phase; Between MeCN and FCH2CH2OH |
By formula: CH3N2- + H+ = CH2N2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1633. ± 13. | kJ/mol | G+TS | Broadus and Kass, 1999 | gas phase; Betweeen D2O, fluorobenzene |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1598. ± 13. | kJ/mol | IMRB | Broadus and Kass, 1999 | gas phase; Betweeen D2O, fluorobenzene |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1555.2 ± 2.9 | kJ/mol | D-EA | Scheer, Bilodeau, et al., 1998, 2 | gas phase; Given: 432.83(5) meV |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1528.7 ± 3.3 | kJ/mol | H-TS | Scheer, Bilodeau, et al., 1998, 2 | gas phase; Given: 432.83(5) meV |
C2H7OSi- + =
By formula: C2H7OSi- + H+ = C2H8OSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1502. ± 17. | kJ/mol | G+TS | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
C4H11OSi- + =
By formula: C4H11OSi- + H+ = C4H12OSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1502. ± 17. | kJ/mol | G+TS | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
By formula: C8H11OSi- + H+ = C8H12OSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1502. ± 17. | kJ/mol | G+TS | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1475. ± 17. | kJ/mol | IMRB | Damrauer, Simon, et al., 1991 | gas phase; between pyrrole, CF3CH2OH |
C23H31OSi- + = C23H32OSi
By formula: C23H31OSi- + H+ = C23H32OSi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1427. ± 10. | kJ/mol | G+TS | Mishima, Mustanir, et al., 2000 | gas phase; Keto acidity: 323 K |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1397. ± 8.4 | kJ/mol | IMRE | Mishima, Mustanir, et al., 2000 | gas phase; Keto acidity: 323 K |
Se- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1422. ± 4.6 | kJ/mol | D-EA | Vandevraye, Drag, et al., 2012 | gas phase; Given: 2.0206046(11) eV |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1397. ± 5.0 | kJ/mol | H-TS | Vandevraye, Drag, et al., 2012 | gas phase; Given: 2.0206046(11) eV |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P.,
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Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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