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Hydrogen cation


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 751 to 800

C4H4NO2- + Hydrogen cation = Succinimide

By formula: C4H4NO2- + H+ = C4H5NO2

Quantity Value Units Method Reference Comment
Deltar1445. ± 9.6kJ/molG+TSCumming and Kebarle, 1978gas phase
Deltar1379. ± 19.kJ/molEIAECooper and Compton, 1973gas phase
Quantity Value Units Method Reference Comment
Deltar1414. ± 8.4kJ/molIMRECumming and Kebarle, 1978gas phase

Carbon anion + Hydrogen cation = Methylidyne

By formula: C- + H+ = CH

Quantity Value Units Method Reference Comment
Deltar1529.4 ± 0.71kJ/molD-EAScheer, Bilodeau, et al., 1998gas phase; Given: 1.262119(20) eV
Quantity Value Units Method Reference Comment
Deltar1506.2 ± 1.1kJ/molH-TSScheer, Bilodeau, et al., 1998gas phase; Given: 1.262119(20) eV

Li- + Hydrogen cation = lithium hydride

By formula: Li- + H+ = HLi

Quantity Value Units Method Reference Comment
Deltar1489.5 ± 0.42kJ/molD-EAHaeffler, Hanstorp, et al., 1996gas phase; Given: 0.618049(20) eV
Quantity Value Units Method Reference Comment
Deltar1468.1 ± 1.3kJ/molH-TSHaeffler, Hanstorp, et al., 1996gas phase; Given: 0.618049(20) eV

C4H7O- + Hydrogen cation = 2-Buten-1-ol, (E)-

By formula: C4H7O- + H+ = C4H8O

Quantity Value Units Method Reference Comment
Deltar1564. ± 12.kJ/molG+TSGraul, Schnute, et al., 1990gas phase; Mixture of cis and trans isomers
Quantity Value Units Method Reference Comment
Deltar1536. ± 12.kJ/molCIDCGraul, Schnute, et al., 1990gas phase; Mixture of cis and trans isomers

C5H9O- + Hydrogen cation = 3-Pentanone

By formula: C5H9O- + H+ = C5H10O

Quantity Value Units Method Reference Comment
Deltar1542. ± 9.2kJ/molG+TSCumming and Kebarle, 1978gas phase
Deltar1518. ± 9.6kJ/molD-EAZimmerman, Reed, et al., 1977gas phase
Quantity Value Units Method Reference Comment
Deltar1512. ± 8.4kJ/molIMRECumming and Kebarle, 1978gas phase

C2H7Si- + Hydrogen cation = Silane, dimethyl-

By formula: C2H7Si- + H+ = C2H8Si

Quantity Value Units Method Reference Comment
Deltar1643. ± 26.kJ/molG+TSDamrauer, Kass, et al., 1988gas phase; Between Me2NH and fluorobenzene
Quantity Value Units Method Reference Comment
Deltar1607. ± 25.kJ/molIMRBDamrauer, Kass, et al., 1988gas phase; Between Me2NH and fluorobenzene

CH4AlO2- + Hydrogen cation = CH5AlO2

By formula: CH4AlO2- + H+ = CH5AlO2

Quantity Value Units Method Reference Comment
Deltar1502. ± 17.kJ/molG+TSDamrauer, Krempp, et al., 1991gas phase; Between CF3CH2OH and pyrrole.
Quantity Value Units Method Reference Comment
Deltar1475. ± 17.kJ/molIMRBDamrauer, Krempp, et al., 1991gas phase; Between CF3CH2OH and pyrrole.

C5H4N3O2- + Hydrogen cation = 2-Amino-5-nitropyridine

By formula: C5H4N3O2- + H+ = C5H5N3O2

Quantity Value Units Method Reference Comment
Deltar1429. ± 12.kJ/molG+TSBreuker, Knochenmuss, et al., 1999gas phase; Acid: 2-amino-5-nitropyridine
Quantity Value Units Method Reference Comment
Deltar1399. ± 11.kJ/molIMRBBreuker, Knochenmuss, et al., 1999gas phase; Acid: 2-amino-5-nitropyridine

C3HF6O- + Hydrogen cation = 2-Propanol, 1,1,1,3,3,3-hexafluoro-

By formula: C3HF6O- + H+ = C3H2F6O

Quantity Value Units Method Reference Comment
Deltar1443. ± 8.8kJ/molG+TSTaft, Koppel, et al., 1990gas phase
Quantity Value Units Method Reference Comment
Deltar1416. ± 8.4kJ/molIMRETaft, Koppel, et al., 1990gas phase
Deltar1424.2kJ/molIMRBKoppel, Pikver, et al., 1981gas phase

C2H6AlO- + Hydrogen cation = C2H7AlO

By formula: C2H6AlO- + H+ = C2H7AlO

Quantity Value Units Method Reference Comment
Deltar1504. ± 17.kJ/molG+TSDamrauer, Krempp, et al., 1991gas phase; Between CF3CH2OH and pyrrole.
Quantity Value Units Method Reference Comment
Deltar1475. ± 17.kJ/molIMRBDamrauer, Krempp, et al., 1991gas phase; Between CF3CH2OH and pyrrole.

C7H6I- + Hydrogen cation = Benzene, (iodomethyl)-

By formula: C7H6I- + H+ = C7H7I

Quantity Value Units Method Reference Comment
Deltar1556. ± 8.8kJ/molG+TSPoutsma, Nash, et al., 1997gas phase; between tBuCH(Me)OH, FCH2CH2OH
Quantity Value Units Method Reference Comment
Deltar1525. ± 8.4kJ/molIMRBPoutsma, Nash, et al., 1997gas phase; between tBuCH(Me)OH, FCH2CH2OH

C5H7- + Hydrogen cation = Isoprene

By formula: C5H7- + H+ = C5H8

Quantity Value Units Method Reference Comment
Deltar1613. ± 21.kJ/molG+TSBartmess and McIver Jr., 1979gas phase; Between H2O, MeOH. Acid: isoprene
Quantity Value Units Method Reference Comment
Deltar1586. ± 21.kJ/molIMRBBartmess and McIver Jr., 1979gas phase; Between H2O, MeOH. Acid: isoprene

Nitric oxide anion + Hydrogen cation = Nitrosyl hydride

By formula: NO- + H+ = HNO

Quantity Value Units Method Reference Comment
Deltar1511.6 ± 0.63kJ/molD-EATravers, Cowles, et al., 1989gas phase; ground state triplet anion
Quantity Value Units Method Reference Comment
Deltar1484.0 ± 1.4kJ/molH-TSTravers, Cowles, et al., 1989gas phase; ground state triplet anion

C8H5- + Hydrogen cation = Bicyclo[4.2.0]octa-1,3,5,7-tetraene

By formula: C8H5- + H+ = C8H6

Quantity Value Units Method Reference Comment
Deltar1608. ± 21.kJ/molG+TSBroadus and Kass, 2000gas phase; between PhF, 1,3-diazine
Quantity Value Units Method Reference Comment
Deltar1574. ± 21.kJ/molIMRBBroadus and Kass, 2000gas phase; between PhF, 1,3-diazine

C2H5S2- + Hydrogen cation = C2H6S2

By formula: C2H5S2- + H+ = C2H6S2

Quantity Value Units Method Reference Comment
Deltar1466. ± 17.kJ/molG+TSGrabowski and Zhang, 1989gas phase; Acidity between H2S, MeCO2H.
Quantity Value Units Method Reference Comment
Deltar1435. ± 17.kJ/molIMRBGrabowski and Zhang, 1989gas phase; Acidity between H2S, MeCO2H.

HOSi- + Hydrogen cation = H2OSi

By formula: HOSi- + H+ = H2OSi

Quantity Value Units Method Reference Comment
Deltar1521. ± 34.kJ/molG+TSGronert, O'Hair, et al., 1990gas phase; Between acetone, nitromethane
Quantity Value Units Method Reference Comment
Deltar1490. ± 33.kJ/molIMRBGronert, O'Hair, et al., 1990gas phase; Between acetone, nitromethane

HP2- + Hydrogen cation = H2P2

By formula: HP2- + H+ = H2P2

Quantity Value Units Method Reference Comment
Deltar1490. ± 13.kJ/molG+TSO'Hair, Krempp, et al., 1992gas phase; Acidity between MeNO2, tBuSH
Quantity Value Units Method Reference Comment
Deltar1456. ± 13.kJ/molIMRBO'Hair, Krempp, et al., 1992gas phase; Acidity between MeNO2, tBuSH

C3H4Br- + Hydrogen cation = 1-Propene, 3-bromo-

By formula: C3H4Br- + H+ = C3H5Br

Quantity Value Units Method Reference Comment
Deltar1570. ± 8.8kJ/molG+TSPoutsma, Nash, et al., 1997gas phase; Between iPrOH, HF; near tBuOH
Quantity Value Units Method Reference Comment
Deltar1540. ± 8.4kJ/molIMRBPoutsma, Nash, et al., 1997gas phase; Between iPrOH, HF; near tBuOH

C6H3Cl2- + Hydrogen cation = Benzene, 1,4-dichloro-

By formula: C6H3Cl2- + H+ = C6H4Cl2

Quantity Value Units Method Reference Comment
Deltar1577. ± 8.8kJ/molG+TSSchlosser, Marzi, et al., 2001gas phase; Acid: p-dichlorobenzene.
Quantity Value Units Method Reference Comment
Deltar1543. ± 8.4kJ/molIMRESchlosser, Marzi, et al., 2001gas phase; Acid: p-dichlorobenzene.

K- + Hydrogen cation = potassium hydride

By formula: K- + H+ = HK

Quantity Value Units Method Reference Comment
Deltar1439.840 ± 0.042kJ/molD-EAAndersson, Sandstrom, et al., 2000gas phase; Given: 0.501459(12) eV
Quantity Value Units Method Reference Comment
Deltar1420.4 ± 1.3kJ/molH-TSAndersson, Sandstrom, et al., 2000gas phase; Given: 0.501459(12) eV

C8H9- + Hydrogen cation = 1,3-Cyclopentadiene, 5-(1-methylethylidene)-

By formula: C8H9- + H+ = C8H10

Quantity Value Units Method Reference Comment
Deltar1482. ± 13.kJ/molG+TSBrickhouse and Squires, 1988gas phase; Acidity between nPrSH, iPrSH
Quantity Value Units Method Reference Comment
Deltar1454. ± 13.kJ/molIMRBBrickhouse and Squires, 1988gas phase; Acidity between nPrSH, iPrSH

C3F6NO3S- + Hydrogen cation = C3HF6NO3S

By formula: C3F6NO3S- + H+ = C3HF6NO3S

Quantity Value Units Method Reference Comment
Deltar1248. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299

C6F12NO3S- + Hydrogen cation = C6HF12NO3S

By formula: C6F12NO3S- + H+ = C6HF12NO3S

Quantity Value Units Method Reference Comment
Deltar1242. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299

C9F18NO3S- + Hydrogen cation = C9HF18NO3S

By formula: C9F18NO3S- + H+ = C9HF18NO3S

Quantity Value Units Method Reference Comment
Deltar1234. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299

C6F12NO3S- + Hydrogen cation = C6HF12NO3S

By formula: C6F12NO3S- + H+ = C6HF12NO3S

Quantity Value Units Method Reference Comment
Deltar1233. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299

C8F16NO3S- + Hydrogen cation = C8HF16NO3S

By formula: C8F16NO3S- + H+ = C8HF16NO3S

Quantity Value Units Method Reference Comment
Deltar1231. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299

C13F21O3- + Hydrogen cation = C13HF21O3

By formula: C13F21O3- + H+ = C13HF21O3

Quantity Value Units Method Reference Comment
Deltar1250. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase; Per Leito, Raamat, et al., 2009, dGacid is likely too weak by at least 1.3 kcal/mol, and possibly 5.3, due to problems in the ladder at dGacid=299

C2NO2- + Hydrogen cation = C2HNO2

By formula: C2NO2- + H+ = C2HNO2

Quantity Value Units Method Reference Comment
Deltar1490. ± 18.kJ/molG+TSSchmitt, Krempp, et al., 1992gas phase; acidity between MeSH, tBuSH.
Quantity Value Units Method Reference Comment
Deltar1457. ± 18.kJ/molIMRBSchmitt, Krempp, et al., 1992gas phase; acidity between MeSH, tBuSH.

H3FNSi- + Hydrogen cation = H4FNSi

By formula: H3FNSi- + H+ = H4FNSi

Quantity Value Units Method Reference Comment
Deltar1563. ± 13.kJ/molG+TSKrempp and Damrauer, 1995gas phase; Acidity between MeCN, nHxOH
Quantity Value Units Method Reference Comment
Deltar1531. ± 13.kJ/molIMRBKrempp and Damrauer, 1995gas phase; Acidity between MeCN, nHxOH

C6H8NSi- + Hydrogen cation = C6H9NSi

By formula: C6H8NSi- + H+ = C6H9NSi

Quantity Value Units Method Reference Comment
Deltar1563. ± 13.kJ/molG+TSKrempp and Damrauer, 1995gas phase; Acidity between MeCN, nHxOH
Quantity Value Units Method Reference Comment
Deltar1531. ± 13.kJ/molIMRBKrempp and Damrauer, 1995gas phase; Acidity between MeCN, nHxOH

Ge- + Hydrogen cation = Germanium monohydride

By formula: Ge- + H+ = GeH

Quantity Value Units Method Reference Comment
Deltar1457. ± 21.kJ/molD-EAScheer, Bilodeau, et al., 1998gas phase; Given: 1.232712(15) eV
Quantity Value Units Method Reference Comment
Deltar1434. ± 22.kJ/molH-TSScheer, Bilodeau, et al., 1998gas phase; Given: 1.232712(15) eV

H4NSi- + Hydrogen cation = H5NSi

By formula: H4NSi- + H+ = H5NSi

Quantity Value Units Method Reference Comment
Deltar1571. ± 13.kJ/molG+TSKrempp and Damrauer, 1995gas phase; Acidity between EtCN, nBuOH
Quantity Value Units Method Reference Comment
Deltar1540. ± 13.kJ/molIMRBKrempp and Damrauer, 1995gas phase; Acidity between EtCN, nBuOH

CH6NOSi- + Hydrogen cation = CH7NOSi

By formula: CH6NOSi- + H+ = CH7NOSi

Quantity Value Units Method Reference Comment
Deltar1571. ± 13.kJ/molG+TSKrempp and Damrauer, 1995gas phase; Acidity between EtCN, nPrOH
Quantity Value Units Method Reference Comment
Deltar1540. ± 13.kJ/molIMRBKrempp and Damrauer, 1995gas phase; Acidity between EtCN, nPrOH

Rb- + Hydrogen cation = HRb

By formula: Rb- + H+ = HRb

Quantity Value Units Method Reference Comment
Deltar1436.7 ± 2.1kJ/molD-EAFrey, Breyer, et al., 1978gas phase; Given: 3919.18(16) cm-1
Quantity Value Units Method Reference Comment
Deltar1417.4 ± 2.4kJ/molH-TSFrey, Breyer, et al., 1978gas phase; Given: 3919.18(16) cm-1

C3H9O2Si- + Hydrogen cation = C3H10O2Si

By formula: C3H9O2Si- + H+ = C3H10O2Si

Quantity Value Units Method Reference Comment
Deltar1502. ± 17.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Deltar1475. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

FP2- + Hydrogen cation = HFP2

By formula: FP2- + H+ = HFP2

Quantity Value Units Method Reference Comment
Deltar1488. ± 17.kJ/molG+TSO'Hair, Krempp, et al., 1992gas phase; Acidity between MeSH, H2S
Quantity Value Units Method Reference Comment
Deltar1456. ± 17.kJ/molIMRBO'Hair, Krempp, et al., 1992gas phase; Acidity between MeSH, H2S

C2H4NO2- + Hydrogen cation = Acetohydroxamic acid

By formula: C2H4NO2- + H+ = C2H5NO2

Quantity Value Units Method Reference Comment
Deltar1449. ± 9.6kJ/molG+TSDecouzon, Exner, et al., 1990gas phase; Acid: Acetohydroxamic acid
Quantity Value Units Method Reference Comment
Deltar1419. ± 8.4kJ/molIMREDecouzon, Exner, et al., 1990gas phase; Acid: Acetohydroxamic acid

CH2NO2- + Hydrogen cation = CH3NO2

By formula: CH2NO2- + H+ = CH3NO2

Quantity Value Units Method Reference Comment
Deltar1538. ± 8.8kJ/molG+TSThomas, Bloor, et al., 1990gas phase; Between PhCH2OH, acetoxime
Quantity Value Units Method Reference Comment
Deltar1510. ± 8.4kJ/molIMRBThomas, Bloor, et al., 1990gas phase; Between PhCH2OH, acetoxime

C5H13OSi- + Hydrogen cation = C5H14OSi

By formula: C5H13OSi- + H+ = C5H14OSi

Quantity Value Units Method Reference Comment
Deltar1502. ± 17.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Deltar1475. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

CH5OSi- + Hydrogen cation = CH6OSi

By formula: CH5OSi- + H+ = CH6OSi

Quantity Value Units Method Reference Comment
Deltar1502. ± 17.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Deltar1475. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

C7H6I- + Hydrogen cation = Benzene, 1-iodo-2-methyl-

By formula: C7H6I- + H+ = C7H7I

Quantity Value Units Method Reference Comment
Deltar1557. ± 13.kJ/molG+TSWenthold, Wierschke, et al., 1994gas phase; Between MeCN and FCH2CH2OH
Quantity Value Units Method Reference Comment
Deltar1527. ± 13.kJ/molIMRBWenthold, Wierschke, et al., 1994gas phase; Between MeCN and FCH2CH2OH

C7H6I- + Hydrogen cation = Benzene, 1-iodo-3-methyl-

By formula: C7H6I- + H+ = C7H7I

Quantity Value Units Method Reference Comment
Deltar1557. ± 13.kJ/molG+TSWenthold, Wierschke, et al., 1994gas phase; Between MeCN and FCH2CH2OH
Quantity Value Units Method Reference Comment
Deltar1527. ± 13.kJ/molIMRBWenthold, Wierschke, et al., 1994gas phase; Between MeCN and FCH2CH2OH

C7H6I- + Hydrogen cation = Benzene, 1-iodo-4-methyl-

By formula: C7H6I- + H+ = C7H7I

Quantity Value Units Method Reference Comment
Deltar1558. ± 13.kJ/molG+TSWenthold, Wierschke, et al., 1994gas phase; Between MeCN and FCH2CH2OH
Quantity Value Units Method Reference Comment
Deltar1527. ± 13.kJ/molIMRBWenthold, Wierschke, et al., 1994gas phase; Between MeCN and FCH2CH2OH

N-diazirinide anion + Hydrogen cation = 3H-Diazirine

By formula: CH3N2- + H+ = CH2N2

Quantity Value Units Method Reference Comment
Deltar1633. ± 13.kJ/molG+TSBroadus and Kass, 1999gas phase; Betweeen D2O, fluorobenzene
Quantity Value Units Method Reference Comment
Deltar1598. ± 13.kJ/molIMRBBroadus and Kass, 1999gas phase; Betweeen D2O, fluorobenzene

Aluminum anion + Hydrogen cation = Aluminum hydride

By formula: Al- + H+ = HAl

Quantity Value Units Method Reference Comment
Deltar1555.2 ± 2.9kJ/molD-EAScheer, Bilodeau, et al., 1998, 2gas phase; Given: 432.83(5) meV
Quantity Value Units Method Reference Comment
Deltar1528.7 ± 3.3kJ/molH-TSScheer, Bilodeau, et al., 1998, 2gas phase; Given: 432.83(5) meV

C2H7OSi- + Hydrogen cation = Silanol, dimethyl-

By formula: C2H7OSi- + H+ = C2H8OSi

Quantity Value Units Method Reference Comment
Deltar1502. ± 17.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Deltar1475. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

C4H11OSi- + Hydrogen cation = Silanol, ethyldimethyl-

By formula: C4H11OSi- + H+ = C4H12OSi

Quantity Value Units Method Reference Comment
Deltar1502. ± 17.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Deltar1475. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

C8H11OSi- + Hydrogen cation = C8H12OSi

By formula: C8H11OSi- + H+ = C8H12OSi

Quantity Value Units Method Reference Comment
Deltar1502. ± 17.kJ/molG+TSDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH
Quantity Value Units Method Reference Comment
Deltar1475. ± 17.kJ/molIMRBDamrauer, Simon, et al., 1991gas phase; between pyrrole, CF3CH2OH

C23H31OSi- + Hydrogen cation = C23H32OSi

By formula: C23H31OSi- + H+ = C23H32OSi

Quantity Value Units Method Reference Comment
Deltar1427. ± 10.kJ/molG+TSMishima, Mustanir, et al., 2000gas phase; Keto acidity: 323 K
Quantity Value Units Method Reference Comment
Deltar1397. ± 8.4kJ/molIMREMishima, Mustanir, et al., 2000gas phase; Keto acidity: 323 K

Se- + Hydrogen cation = Selenium monohydride

By formula: Se- + H+ = HSe

Quantity Value Units Method Reference Comment
Deltar1422. ± 4.6kJ/molD-EAVandevraye, Drag, et al., 2012gas phase; Given: 2.0206046(11) eV
Quantity Value Units Method Reference Comment
Deltar1397. ± 5.0kJ/molH-TSVandevraye, Drag, et al., 2012gas phase; Given: 2.0206046(11) eV

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P., Summary of gas phase measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A-H) and electron affinities EA(A), Can. J. Chem., 1978, 56, 1. [all data]

Cooper and Compton, 1973
Cooper, C.D.; Compton, R.N., Electron attachment and cesium collisional ionization studies of tetrafluorosuccinic and hexafluoroglutaric anhydrides: Molecular electron affinities, J. Chem. Phys., 1973, 59, 3550. [all data]

Scheer, Bilodeau, et al., 1998
Scheer, M.; Bilodeau, R.C.; Brodie, C.A.; Haugen, H.K., Systematic study of the stable states of C-, Si-, Ge-, and Sn- via infrared laser spectroscopy, Phys. Rev. A, 1998, 58, 4, 2844-2856, https://doi.org/10.1103/PhysRevA.58.2844 . [all data]

Haeffler, Hanstorp, et al., 1996
Haeffler, G.; Hanstorp, G.; Kiyan, I.; Klinkm|ller, A.E.; Ljungblad, U.; Pegg, D.J., Electron affinity of Li: A state-selective measurement, Phys. Rev. A, 1996, 53, 6, 4127-4131, https://doi.org/10.1103/PhysRevA.53.4127 . [all data]

Graul, Schnute, et al., 1990
Graul, S.T.; Schnute, M.E.; Squires, R.R., Gas-Phase Acidities of Carboxylic Acids and Alcohols from Collision-Induced Dissociation of Dimer Cluster Ions, Int. J. Mass Spectrom. Ion Proc., 1990, 96, 2, 181, https://doi.org/10.1016/0168-1176(90)87028-F . [all data]

Zimmerman, Reed, et al., 1977
Zimmerman, A.H.; Reed, K.J.; Brauman, J.I., Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals, J. Am. Chem. Soc., 1977, 99, 7203. [all data]

Damrauer, Kass, et al., 1988
Damrauer, R.; Kass, S.R.; DePuy, C.H., Gas-Phase Acidities of Methylsilanes: C-H versus Si-H, Organomet., 1988, 7, 3, 637, https://doi.org/10.1021/om00093a011 . [all data]

Damrauer, Krempp, et al., 1991
Damrauer, R.; Krempp, M.; Schmidt, M.W.; Gordon, M.S., Gas-Phase Chemistry of the Dimethylaluminum Oxide Ion and Related Aluminum Oxide Ions - Comparison of Reactivity with Siloxide Ions, J. Am. Chem. Soc., 1991, 113, 7, 2393, https://doi.org/10.1021/ja00007a007 . [all data]

Breuker, Knochenmuss, et al., 1999
Breuker, K.; Knochenmuss, R.; Zenobi, R., Gas-phase basicities of deprotonated matrix-assisted laser desorption/ionization matrix molecules, Int. J. Mass Spectrom., 1999, 184, 1, 25-38, https://doi.org/10.1016/S1387-3806(98)14200-8 . [all data]

Taft, Koppel, et al., 1990
Taft, R.W.; Koppel, I.J.; Topsom, R.D.; Anvia, F., Acidities of OH Compounds, including Alcohols, Phenols, Carboxylic Acids, and Mineral Acids, J. Am. Chem. Soc., 1990, 112, 6, 2047, https://doi.org/10.1021/ja00162a001 . [all data]

Koppel, Pikver, et al., 1981
Koppel, I.; Pikver, R.; Sugis, A.; Suurmaa, E.; Lippmaa, E., FTICR Study of Structure and Solvent Effects on Basicity of Some Anions in the Gas Phase, Org. Reac., 1981, 18, 3. [all data]

Poutsma, Nash, et al., 1997
Poutsma, J.C.; Nash, J.J.; Paulino, J.A.; Squires, R.R., Absolute Heats of Formation of Phenylcarbene and Vinylcarbene, J. Am. Chem. Soc., 1997, 119, 20, 4686, https://doi.org/10.1021/ja963918s . [all data]

Bartmess and McIver Jr., 1979
Bartmess, J.E.; McIver Jr., The Gas Phase Acidity Scale in Gas Phase Ion Chemistry, Gas Phase Ion Chemistry, V. 2, M.T. Bowers, Ed., Academic Press, NY, 1979, Ch. 11, Elsevier, 1979. [all data]

Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B., Reinvestigation of the Electron Affinities of O2 and NO, Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6 . [all data]

Broadus and Kass, 2000
Broadus, K.M.; Kass, S.R., Benzocyclobutadienyl anion: Formation and energetics of an antiaromatic molecule, J. Org. Chem., 2000, 65, 20, 6566-6571, https://doi.org/10.1021/jo000709o . [all data]

Grabowski and Zhang, 1989
Grabowski, J.J.; Zhang, L., Dimethyl Disulfide: Anion-Molecule Reactions in the Gas Phase at 300 K, J. Am. Chem. Soc., 1989, 111, 4, 1193, https://doi.org/10.1021/ja00186a005 . [all data]

Gronert, O'Hair, et al., 1990
Gronert, S.; O'Hair, R.A.J.; Prodnuk, S.; Suzle, D.; Damrauer, R.; DePuy, C.H., Gas-Phase Chemistry of the Silaformyl Anion, HSiO-, J. Am. Chem. Soc., 1990, 112, 3, 997, https://doi.org/10.1021/ja00159a016 . [all data]

O'Hair, Krempp, et al., 1992
O'Hair, R.A.J.; Krempp, M.; Damrauer, R.; Depuy, C.H., Gas-Phase Ion Chemistry of HP2(-), FP2(-), and HP2(+), Inorg. Chem., 1992, 31, 11, 2092, https://doi.org/10.1021/ic00037a021 . [all data]

Schlosser, Marzi, et al., 2001
Schlosser, M.; Marzi, E.; Cottet, F.; Buker, H.H.; Nibbering, N.M.M., The acidity of chloro-substituted benzenes: A comparison of gas phase, ab initio, and kinetic data, Chem. Eur. J., 2001, 7, 16, 3511-3516, https://doi.org/10.1002/1521-3765(20010817)7:16<3511::AID-CHEM3511>3.0.CO;2-U . [all data]

Andersson, Sandstrom, et al., 2000
Andersson, K.T.; Sandstrom, J.; Kiyan, I.Y.; Hanstorp, D.; Pegg, D.J., Measurement of the electron affinity of potassium - art. no. 022503, Phys. Rev. A, 2000, 62, 2, 22503, https://doi.org/10.1103/PhysRevA.62.022503 . [all data]

Brickhouse and Squires, 1988
Brickhouse, M.D.; Squires, R.R., Gas Phase Bronsted vs. Lewis Acid-Base Reactions of 6,6-Dimethylfulvene. A Sensitive Probe of the Electronic Structures of Organic Anions, J. Am. Chem. Soc., 1988, 110, 9, 2706, https://doi.org/10.1021/ja00217a002 . [all data]

Koppel, Taft, et al., 1994
Koppel, I.A.; Taft, R.W.; Anvia, F.; Zhu, S.Z.; Hu, L.Q.; Sung, K.S.; Desmarteau, D.D.; Yagupolskii, L.M., The Gas-Phase Acidities of Very Strong Neutral Bronsted Acids, J. Am. Chem. Soc., 1994, 116, 7, 3047, https://doi.org/10.1021/ja00086a038 . [all data]

Leito, Raamat, et al., 2009
Leito, I.; Raamat, E.; Kutt, A.; Saame, J.; Kipper, K.; Koppel, I.A.; Koppel, I.; Zhang, M.; Mishima, M.; Yagupolskii, L.M.; Garlyauskayte, R.Y.; Filatov, A.A., Revision of the Gas-Phase Acidity Scale below 300 kcal mol(-1), J. Phys. Chem. A, 2009, 113, 29, 8421-8424, https://doi.org/10.1021/jp903780k . [all data]

Schmitt, Krempp, et al., 1992
Schmitt, R.J.; Krempp, M.; Bierbaum, V.M., Gas Phase Chemistry of Dinitramide and Nitroacetylide Ions, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 621, https://doi.org/10.1016/0168-1176(92)80116-I . [all data]

Krempp and Damrauer, 1995
Krempp, M.; Damrauer, R., The Gas-phase Chemistry of Silamide Ions, Organomet., 1995, 14, 1, 170, https://doi.org/10.1021/om00001a027 . [all data]

Frey, Breyer, et al., 1978
Frey, P.; Breyer, F.; Hotop, H., High Resolutions Photodetachment from the Rubidium Negative Ion around the Rb(5p1/2) Threshold, J. Phys. B: Atom. Mol. Phys., 1978, 11, 19, L589, https://doi.org/10.1088/0022-3700/11/19/005 . [all data]

Damrauer, Simon, et al., 1991
Damrauer, R.; Simon, R.; Krempp, M., Effect of Substituents on the Gas-Phase Acidity of Silanols, J. Am. Chem. Soc., 1991, 113, 12, 4431, https://doi.org/10.1021/ja00012a009 . [all data]

Decouzon, Exner, et al., 1990
Decouzon, M.; Exner, O.; Gal, J.-F.; Maria, P.-C., The Gas-Phase Acidity and the Acidic Site of Acetohydroxamic Acid: an FT-ICR Study, J. Org. Chem., 1990, 55, 13, 3980, https://doi.org/10.1021/jo00300a007 . [all data]

Thomas, Bloor, et al., 1990
Thomas, D.A.; Bloor, J.E.; Bartmess, J.E., The Structures of the (M-H) Anions of the CH3NO2 Isomers Nitromethane and Methyl Nitrite, J. Am. Soc. Mass Spectrom., 1990, 1, 4, 295, https://doi.org/10.1016/1044-0305(90)85004-6 . [all data]

Wenthold, Wierschke, et al., 1994
Wenthold, P.G.; Wierschke, S.G.; Nash, J.J.; Squires, R.R., Biradical thermochemistry from collision-induced dissociation threshold energy measurements .2. Experimental and theoretical studies of the Mechanism and Thermochemistry of Formation of alph, J. Am. Chem. Soc., 1994, 116, 16, 7378, https://doi.org/10.1021/ja00095a048 . [all data]

Broadus and Kass, 1999
Broadus, K.M.; Kass, S.R., Conjugate Base of a Cyclic Hydrazine: Formation and Energetics of N-Diaziridyl Anion, Int. J. Mass Spectrom., 1999, 185, 179, https://doi.org/10.1016/S1387-3806(98)14164-7 . [all data]

Scheer, Bilodeau, et al., 1998, 2
Scheer, M.; Bilodeau, RC; Thogresen, J.; Haugen, HK, Threshold Photodetachment of Al-: Electron Affinity and Fine Structure, Phys. Rev. A, 1998, 57, 3, R1493-, https://doi.org/10.1103/PhysRevA.57.R1493 . [all data]

Mishima, Mustanir, et al., 2000
Mishima, M.; Mustanir; Eventova, I.; Rappoport, Z., Acidities and pK(Enol) values of stable simple enols in the gas phase, J. Chem. Soc. Perkin Trans., 2000, 2, 7, 1505-1512, https://doi.org/10.1039/b001155j . [all data]

Vandevraye, Drag, et al., 2012
Vandevraye, M.; Drag, C.; Blondel, C., Electron affinity of selenium measured by photodetachment microscopy, Phys. Rev. A, 2012, 85, 1, 015401, https://doi.org/10.1103/PhysRevA.85.015401 . [all data]


Notes

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