Hydrogen cation


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1251 to 1300

C14H6F4N- + Hydrogen cation = C14H7F4N

By formula: C14H6F4N- + H+ = C14H7F4N

Quantity Value Units Method Reference Comment
Δr1363. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C15H5F7N- + Hydrogen cation = C15H6F7N

By formula: C15H5F7N- + H+ = C15H6F7N

Quantity Value Units Method Reference Comment
Δr1321. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C14ClF9N- + Hydrogen cation = C14HClF9N

By formula: C14ClF9N- + H+ = C14HClF9N

Quantity Value Units Method Reference Comment
Δr1305. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C17H5F9NO2- + Hydrogen cation = C17H6F9NO2

By formula: C17H5F9NO2- + H+ = C17H6F9NO2

Quantity Value Units Method Reference Comment
Δr1299. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C15H3F9N- + Hydrogen cation = C15H4F9N

By formula: C15H3F9N- + H+ = C15H4F9N

Quantity Value Units Method Reference Comment
Δr1323. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C13F9N2- + Hydrogen cation = C13HF9N2

By formula: C13F9N2- + H+ = C13HF9N2

Quantity Value Units Method Reference Comment
Δr1279. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C14BrF9N- + Hydrogen cation = C14HBrF9N

By formula: C14BrF9N- + H+ = C14HBrF9N

Quantity Value Units Method Reference Comment
Δr1309. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C14HF10O- + Hydrogen cation = C14H2F10O

By formula: C14HF10O- + H+ = C14H2F10O

Quantity Value Units Method Reference Comment
Δr1323. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C15HF12O- + Hydrogen cation = C15H2F12O

By formula: C15HF12O- + H+ = C15H2F12O

Quantity Value Units Method Reference Comment
Δr1301. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C11H6F4NO2- + Hydrogen cation = C11H7F4NO2

By formula: C11H6F4NO2- + H+ = C11H7F4NO2

Quantity Value Units Method Reference Comment
Δr1320. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C12H8F4NO2- + Hydrogen cation = C12H9F4NO2

By formula: C12H8F4NO2- + H+ = C12H9F4NO2

Quantity Value Units Method Reference Comment
Δr1323. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C12H5F7NO2- + Hydrogen cation = C12H6F7NO2

By formula: C12H5F7NO2- + H+ = C12H6F7NO2

Quantity Value Units Method Reference Comment
Δr1288. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C11H5ClF4NO2- + Hydrogen cation = C11H6ClF4NO2

By formula: C11H5ClF4NO2- + H+ = C11H6ClF4NO2

Quantity Value Units Method Reference Comment
Δr1308. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C11H5BrF4NO2- + Hydrogen cation = C11H6BrF4NO2

By formula: C11H5BrF4NO2- + H+ = C11H6BrF4NO2

Quantity Value Units Method Reference Comment
Δr1307. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C12H5F4N2O2- + Hydrogen cation = C12H6F4N2O2

By formula: C12H5F4N2O2- + H+ = C12H6F4N2O2

Quantity Value Units Method Reference Comment
Δr1283. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C17F16N- + Hydrogen cation = C17HF16N

By formula: C17F16N- + H+ = C17HF16N

Quantity Value Units Method Reference Comment
Δr1282. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C2H5Sn- + Hydrogen cation = C2H6Sn

By formula: C2H5Sn- + H+ = C2H6Sn

Quantity Value Units Method Reference Comment
Δr1431. ± 8.4kJ/molIMREGal, Decouzon, et al., 2001gas phase

C2H3Sn- + Hydrogen cation = C2H4Sn

By formula: C2H3Sn- + H+ = C2H4Sn

Quantity Value Units Method Reference Comment
Δr1386. ± 12.kJ/molIMREGal, Decouzon, et al., 2001gas phase

C6H11O2- + Hydrogen cation = 1,4-Cyclohexanediol, cis-

By formula: C6H11O2- + H+ = C6H12O2

Quantity Value Units Method Reference Comment
Δr1490. ± 8.4kJ/molIMREChen, Walthall, et al., 2004gas phase

C2H5Te- + Hydrogen cation = C2H6Te

By formula: C2H5Te- + H+ = C2H6Te

Quantity Value Units Method Reference Comment
Δr1403. ± 12.kJ/molIMRBGuillemin, Riague, et al., 2005gas phase

C12H8ClN2O6S2- + Hydrogen cation = C12H9ClN2O6S2

By formula: C12H8ClN2O6S2- + H+ = C12H9ClN2O6S2

Quantity Value Units Method Reference Comment
Δr1243. ± 8.4kJ/molIMRELeito, Raamat, et al., 2009gas phase

C12H7ClN3O8S2- + Hydrogen cation = C12H8ClN3O8S2

By formula: C12H7ClN3O8S2- + H+ = C12H8ClN3O8S2

Quantity Value Units Method Reference Comment
Δr1218. ± 8.4kJ/molIMRELeito, Raamat, et al., 2009gas phase

C11H10NO2- + Hydrogen cation = Benzeneacetic acid, α-cyano-, ethyl ester

By formula: C11H10NO2- + H+ = C11H11NO2

Quantity Value Units Method Reference Comment
Δr1351. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C14H8N- + Hydrogen cation = 9H-Fluorene-9-carbonitrile

By formula: C14H8N- + H+ = C14H9N

Quantity Value Units Method Reference Comment
Δr1345. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C8H8F3N2O3S2- + Hydrogen cation = C8H9F3N2O3S2

By formula: C8H8F3N2O3S2- + H+ = C8H9F3N2O3S2

Quantity Value Units Method Reference Comment
Δr1299. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2001gas phase

C6H7Ge- + Hydrogen cation = C6H8Ge

By formula: C6H7Ge- + H+ = C6H8Ge

Quantity Value Units Method Reference Comment
Δr1448. ± 5.0kJ/molIMREGal, Decouzon, et al., 2001gas phase

C2H7Sn- + Hydrogen cation = C2H8Sn

By formula: C2H7Sn- + H+ = C2H8Sn

Quantity Value Units Method Reference Comment
Δr1433. ± 8.4kJ/molIMREGal, Decouzon, et al., 2001gas phase

C6H7Sn- + Hydrogen cation = C6H8Sn

By formula: C6H7Sn- + H+ = C6H8Sn

Quantity Value Units Method Reference Comment
Δr1400. ± 16.kJ/molIMREGal, Decouzon, et al., 2001gas phase

FS- + Hydrogen cation = HFS

By formula: FS- + H+ = HFS

Quantity Value Units Method Reference Comment
Δr1449. ± 15.kJ/molD-EAPolak, Gilles, et al., 1992gas phase

Pb- + Hydrogen cation = HPb

By formula: Pb- + H+ = HPb

Quantity Value Units Method Reference Comment
Δr1454. ± 8.4kJ/molD-EAFeigerle, Corderman, et al., 1981gas phase

C8H12O4-2 + Hydrogen cation = C8H13O4-2

By formula: C8H12O4-2 + H+ = C8H13O4-2

Quantity Value Units Method Reference Comment
Δr1636. ± 13.kJ/molD-EAYang, Fu, et al., 2004gas phase

Rh- + Hydrogen cation = HRh

By formula: Rh- + H+ = HRh

Quantity Value Units Method Reference Comment
Δr1449. ± 21.kJ/molD-EAScheer, Brodie, et al., 1998gas phase

Pd- + Hydrogen cation = HPd

By formula: Pd- + H+ = HPd

Quantity Value Units Method Reference Comment
Δr1492. ± 25.kJ/molD-EAScheer, Brodie, et al., 1998gas phase

Ag- + Hydrogen cation = HAg

By formula: Ag- + H+ = HAg

Quantity Value Units Method Reference Comment
Δr1406. ± 7.9kJ/molD-EABilodeau, Scheer, et al., 1998gas phase

Sb- + Hydrogen cation = HSb

By formula: Sb- + H+ = HSb

Quantity Value Units Method Reference Comment
Δr1444. ± 4.6kJ/molD-EAScheer, Haugen, et al., 1997gas phase

C6H2F3- + Hydrogen cation = 1,3,5-Trifluorobenzene

By formula: C6H2F3- + H+ = C6H3F3

Quantity Value Units Method Reference Comment
Δr1512. ± 8.4kJ/molIMREBuker, Nibbering, et al., 1997gas phase

C6H5Se- + Hydrogen cation = Benzeneselenol

By formula: C6H5Se- + H+ = C6H6Se

Quantity Value Units Method Reference Comment
Δr1386. ± 10.kJ/molIMRBGuillemin, Riague, et al., 2005gas phase

C10H17NO3- + Hydrogen cation = C10H18NO3

By formula: C10H17NO3- + H+ = C10H18NO3

Quantity Value Units Method Reference Comment
Δr1411. ± 8.8kJ/molCIDCGryn'ova, Marshall, et al., 2013gas phase

Ti- + Hydrogen cation = Titanium monohydride

By formula: Ti- + H+ = HTi

Quantity Value Units Method Reference Comment
Δr1508. ± 8.8kJ/molD-EAIlin, Sakharov, et al., 1987gas phase

H2Si- + Hydrogen cation = Silyl radical

By formula: H2Si- + H+ = H3Si

Quantity Value Units Method Reference Comment
Δr1495. ± 5.9kJ/molD-EAKasdan, Herbst, et al., 1975gas phase

As- + Hydrogen cation = Arsenic monohydride

By formula: As- + H+ = HAs

Quantity Value Units Method Reference Comment
Δr1508.1 ± 2.9kJ/molD-EAWalter, Gibson, et al., 2009gas phase

C8H3F5NO- + Hydrogen cation = C8H4F5NO

By formula: C8H3F5NO- + H+ = C8H4F5NO

Quantity Value Units Method Reference Comment
Δr1364. ± 8.4kJ/molIMREKoppel, Koppel, et al., 1998gas phase

C14H10N- + Hydrogen cation = Benzeneacetonitrile, α-phenyl-

By formula: C14H10N- + H+ = C14H11N

Quantity Value Units Method Reference Comment
Δr1395. ± 8.4kJ/molIMREKoppel, Koppel, et al., 2000gas phase

C3H7S2- + Hydrogen cation = 1,3-Propanedithiol

By formula: C3H7S2- + H+ = C3H8S2

Quantity Value Units Method Reference Comment
Δr1429. ± 8.8kJ/molIMREKarty, Wu, et al., 2001gas phase

C8H4O4-2 + Hydrogen cation = C8H5O4-2

By formula: C8H4O4-2 + H+ = C8H5O4-2

Quantity Value Units Method Reference Comment
Δr1679. ± 13.kJ/molD-EAYang, Fu, et al., 2004gas phase

C8H4O4-2 + Hydrogen cation = C8H5O4-2

By formula: C8H4O4-2 + H+ = C8H5O4-2

Quantity Value Units Method Reference Comment
Δr1765. ± 13.kJ/molD-EAYang, Fu, et al., 2004gas phase

C6H3F3NO6S3- + Hydrogen cation = C6H4F3NO6S3

By formula: C6H3F3NO6S3- + H+ = C6H4F3NO6S3

Quantity Value Units Method Reference Comment
Δr1287. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase

C7H5F2O4S2- + Hydrogen cation = C7H6F2O4S2

By formula: C7H5F2O4S2- + H+ = C7H6F2O4S2

Quantity Value Units Method Reference Comment
Δr1284. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase

C11H4F9O7S3- + Hydrogen cation = C11H5F9O7S3

By formula: C11H4F9O7S3- + H+ = C11H5F9O7S3

Quantity Value Units Method Reference Comment
Δr1283. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase

C12H4F5N2O2- + Hydrogen cation = C12H5F5N2O2

By formula: C12H4F5N2O2- + H+ = C12H5F5N2O2

Quantity Value Units Method Reference Comment
Δr1320. ± 8.4kJ/molIMREKoppel, Koppel, et al., 1998gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Koppel, Koppel, et al., 2000
Koppel, I.A.; Koppel, J.; Pihl, V.; Leito, I.; Mishima, M.; Vlasov, V.M.; Yagupolskii, L.M.; Taft, R.W., Comparison of Bronsted acidities of neutral CH acids in gas phase and dimethyl sulfoxide, J. Chem. Soc. Perkin Trans., 2000, 2, 6, 1125-1133, https://doi.org/10.1039/b001792m . [all data]

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]

Chen, Walthall, et al., 2004
Chen, X.; Walthall, D.A.; Brauman, J.I., Acidities in cyclohexanediols enhanced by intramolecular hydrogen bonds, J. Am. Chem. Soc., 2004, 126, 39, 12614-12620, https://doi.org/10.1021/ja049780s . [all data]

Guillemin, Riague, et al., 2005
Guillemin, J.C.; Riague, E.H.; Gal, J.F.; Maria, P.C.; Mo, O.; Yanez, M., Acidity trends in alpha,beta-unsaturated sulfur, selenium, and tellurium derivatives: Comparison with C-, Si-, Ge-, Sn-, N-, P-, As-, and Sb-containing analogues, Chem. Eur. J., 2005, 11, 7, 2145-2153, https://doi.org/10.1002/chem.200400989 . [all data]

Leito, Raamat, et al., 2009
Leito, I.; Raamat, E.; Kutt, A.; Saame, J.; Kipper, K.; Koppel, I.A.; Koppel, I.; Zhang, M.; Mishima, M.; Yagupolskii, L.M.; Garlyauskayte, R.Y.; Filatov, A.A., Revision of the Gas-Phase Acidity Scale below 300 kcal mol(-1), J. Phys. Chem. A, 2009, 113, 29, 8421-8424, https://doi.org/10.1021/jp903780k . [all data]

Koppel, Koppel, et al., 2001
Koppel, I.A.; Koppel, J.; Leito, I.; Koppel, I.; Mishima, M.; Yagupolskii, L.M., The enormous acidifying effect of the supersubstituent =NSO2CF3 on the acidity of derivatives of benzenesulfonamide and toluene-p-sulfonamide in the gas phase and in dimethyl sulfoxide, J. Chem. Soc. Perkin Trans., 2001, 2, 2, 229-232, https://doi.org/10.1039/b005765g . [all data]

Polak, Gilles, et al., 1992
Polak, M.L.; Gilles, M.K.; Lineberger, W.C., Photoelectron Spectroscopy of SF-, J. Chem. Phys., 1992, 96, 9, 7191, https://doi.org/10.1063/1.462526 . [all data]

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Lineberger, W.C., Electron affinities of B, Al, Bi, and Pb, J. Chem. Phys., 1981, 74, 2, 1513, https://doi.org/10.1063/1.441174 . [all data]

Yang, Fu, et al., 2004
Yang, X.; Fu, Y.J.; Wang, X.B.; Slavicek, P.; Mucha, M.; Jungwirth, P.; Wang, L.S., Solvent-mediated folding of a doubly charged anion, J. Am. Chem. Soc., 2004, 126, 3, 876-883, https://doi.org/10.1021/ja038108c . [all data]

Scheer, Brodie, et al., 1998
Scheer, M.; Brodie, C.A.; Bilodeau, R.C.; Haugen, H.K., Laser spectroscopic measurements of binding energies and fine-structure splittings of Co-, Ni-, Rh-, and Pd-, Phys. Rev. A, 1998, 58, 3, 2051-2062, https://doi.org/10.1103/PhysRevA.58.2051 . [all data]

Bilodeau, Scheer, et al., 1998
Bilodeau, R.C.; Scheer, M.; Haugen, H.K., Infrared Laser Photodetachment of Transition Metal Negative Ions: Studies on Cr-, Mo-, Cu-, and Ag-, J. Phys. B: Atom. Mol. Opt. Phys., 1998, 31, 17, 3885-3891, https://doi.org/10.1088/0953-4075/31/17/013 . [all data]

Scheer, Haugen, et al., 1997
Scheer, M.; Haugen, H.K.; Beck, D.R., Single- and Multiphoton Infrared Laser Spectroscopy of Sb-: A Case Study, Phys. Rev. Lett., 1997, 79, 21, 4104-4107, https://doi.org/10.1103/PhysRevLett.79.4104 . [all data]

Buker, Nibbering, et al., 1997
Buker, H.H.; Nibbering, N.M.M.; Espinosa, D.; Mongin, F.; Schlosser, M., Additivity of substituent effects in the fluoroarene series: Equilibrium acidity in the gas phase and deprotonation rates in ethereal solution, Tetrahed. Lett., 1997, 38, 49, 8519-8522, https://doi.org/10.1016/S0040-4039(97)10303-3 . [all data]

Gryn'ova, Marshall, et al., 2013
Gryn'ova, G.; Marshall, D.L.; Blanksby, S.J.; Coote, M.L., Switching Radical Stability by pH-Induced Orbital Conversion, Nat. Chem., 2013, 5, 6, 474-481, https://doi.org/10.1038/nchem.1625 . [all data]

Ilin, Sakharov, et al., 1987
Ilin, R.N.; Sakharov, V.I.; Serenkov, I.T., Study of Titanium Negative Ion Using Method of Electron Detachment by an Electric Field, Opt. Spectros. (USSR), 1987, 62, 578. [all data]

Kasdan, Herbst, et al., 1975
Kasdan, A.; Herbst, E.; Lineberger, W.C., Laser photoelectron spectrometry of the negative ions of silicon and its hydrides, J. Chem. Phys., 1975, 62, 541. [all data]

Walter, Gibson, et al., 2009
Walter, C.W.; Gibson, N.D.; Field, R.L.; Snedden, A.P.; Shapiro, J.Z.; Janczak, C.M.; Hanstorp, D., Electron affinity of arsenic and the fine structure of As- measured using infrared photodetachment threshold spectroscopy, Phys. Rev. A, 2009, 80, 1, 014501, https://doi.org/10.1103/PhysRevA.80.014501 . [all data]

Koppel, Koppel, et al., 1998
Koppel, I.; Koppel, J.; Maria, P.C.; Gal, J.F.; Notario, R.; Vlasov, V.M.; Taft, R.W., Comparison of Bronsted acidities of neutral NH-acids in gas phase, dimethyl sulfoxide and water, Int. J. Mass Spectrom., 1998, 175, 1-2, 61-69, https://doi.org/10.1016/S0168-1176(98)00113-X . [all data]

Karty, Wu, et al., 2001
Karty, J.M.; Wu, Y.S.; Brauman, J.I., The RS-center dot HSR hydrogen bond: Acidities of alpha,omega- dithiols and electron affinities of their monoradicals, J. Am. Chem. Soc., 2001, 123, 40, 9800-9805, https://doi.org/10.1021/ja0039684 . [all data]

Koppel, Taft, et al., 1994
Koppel, I.A.; Taft, R.W.; Anvia, F.; Zhu, S.Z.; Hu, L.Q.; Sung, K.S.; Desmarteau, D.D.; Yagupolskii, L.M., The Gas-Phase Acidities of Very Strong Neutral Bronsted Acids, J. Am. Chem. Soc., 1994, 116, 7, 3047, https://doi.org/10.1021/ja00086a038 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References