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1,4-Dioxane

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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director

Tboil (K) Reference Comment
374.2Aldrich Chemical Company Inc., 1990BS
374.Rao and Reddy, 1988Uncertainty assigned by TRC = 0.4 K; TRC
374.5Majer and Svoboda, 1985 
374.55Rao and Naidu, 1973Uncertainty assigned by TRC = 0.25 K; TRC
374.45Anonymous, 1968TRC
374.7Fort and Moore, 1965Uncertainty assigned by TRC = 0.3 K; TRC
374.4Amaya, 1961Uncertainty assigned by TRC = 0.4 K; TRC
374.55Schott, 1961Uncertainty assigned by TRC = 0.3 K; TRC
374.25McCormack, Walkup, et al., 1956Uncertainty assigned by TRC = 0.2 K; TRC
372.Wotiz, Hollingsworth, et al., 1956Uncertainty assigned by TRC = 3. K; TRC; Data excluded from overall average
374.15Hammond and Stokes, 1955Uncertainty assigned by TRC = 0.5 K; TRC
373.15Jung, Miller, et al., 1953Uncertainty assigned by TRC = 1. K; TRC
375.Griffiths, 1952Uncertainty assigned by TRC = 0.2 K; TRC
374.65Kortuem, Moegling, et al., 1950Uncertainty assigned by TRC = 0.5 K; TRC
374.5Lecat, 1947Uncertainty assigned by TRC = 0.3 K; TRC
374.5Lecat, 1943Uncertainty assigned by TRC = 0.3 K; TRC
374.15Ewell and Welch, 1941Uncertainty assigned by TRC = 1. K; TRC
374.41Crenshaw, Cope, et al., 1938Uncertainty assigned by TRC = 0.1 K; TRC
374.45Earp and Glasstone, 1935Uncertainty assigned by TRC = 0.3 K; TRC
373.4Sutton and Brockway, 1935Uncertainty assigned by TRC = 0.3 K; TRC
374.6Gillis and Delaunois, 1934Uncertainty assigned by TRC = 0.5 K; TRC
373.8Smyth and Walls, 1931Uncertainty assigned by TRC = 0.5 K; TRC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Rao and Reddy, 1988
Rao, K.P.C.; Reddy, K.S. (see subram k), Viscosities of Trichloroethylene with Ketones and 1,4-Dioxane at 298.15, 308.15, and 318.15 K, J. Chem. Eng. Data, 1988, 33, 130. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Rao and Naidu, 1973
Rao, M.V.P.; Naidu, P.R., Excess volumes and viscosities of dioxane-pyridine mixture, Proc. - Indian Acad. Sci., Sect. A, 1973, 78, 65. [all data]

Anonymous, 1968
Anonymous, X., Chemicals and Plastics Physical Properties, 1968, Union Carbide Corp., product bulletin, 1968. [all data]

Fort and Moore, 1965
Fort, R.J.; Moore, W.R., Adiabatic compressibilities of binary liquid mixtures, Trans. Faraday Soc., 1965, 61, 2102. [all data]

Amaya, 1961
Amaya, K., Thermodynamical studies on bionary systems consisting of polar and non-polar liquids. II. the measurement of the heats of mixing for binary systems of polar and non-polar liquids, Bull. Chem. Soc. Jpn., 1961, 34, 1278. [all data]

Schott, 1961
Schott, H., Densities, Refractive Indices, and Molar Refractions of the System Water-Dioxane at 25 C, J. Chem. Eng. Data, 1961, 6, 19-20. [all data]

McCormack, Walkup, et al., 1956
McCormack, J.B.; Walkup, J.H.; Rush, R.I., Boiling Point Comp. Diagram for the Sys. 1,4-Dioxane-n-Butyl Alcohol alcohol, J. Phys. Chem., 1956, 60, 826. [all data]

Wotiz, Hollingsworth, et al., 1956
Wotiz, J.H.; Hollingsworth, C.A.; Dessy, R.E., The reaction of 1-Alkynes with Organometallic Compounds IV. Reactions in the Presence of Dioxane, J. Am. Chem. Soc., 1956, 78, 1221-3. [all data]

Hammond and Stokes, 1955
Hammond, B.R.; Stokes, R.H., Diffusion in Binary Liqu8id Mixtures. Part 2 The Diffusion of Carbon Tetrachloride in SOme Organic Solvents at 25 deg, Trans. Faraday Soc., 1955, 51, 1641. [all data]

Jung, Miller, et al., 1953
Jung, S.L.; Miller, J.G.; Day, A.R., Effect of Structue on Reactivity. VIII. Aminolysis of Methyl Acetate with Some «beta»-Phenylethylamines, J. Am. Chem. Soc., 1953, 75, 4664. [all data]

Griffiths, 1952
Griffiths, V.S., Densities of SOme Binary Liquid Mixtures, Part I., J. Chem. Soc., 1952, 1952, 1326. [all data]

Kortuem, Moegling, et al., 1950
Kortuem, G.; Moegling, D.; Woerner, F., The Efficiency of Circulation Apparatuses for Determining Boiling and Vapor Pressure Diagrams of Binary Liquids., Chem.-Ing.-Tech., 1950, 22, 453. [all data]

Lecat, 1947
Lecat, M., Some azeotropes of which one constituant is heterocyclic nitrogen, Ann. Soc. Sci. Bruxelles, Ser. 1, 1947, 61, 73. [all data]

Lecat, 1943
Lecat, M., Negative and other Azeotropes, C. R. Hebd. Seances Acad. Sci., 1943, 217, 242. [all data]

Ewell and Welch, 1941
Ewell, R.H.; Welch, L.M., Maximum Boiling Mixtures of chloroparaffins with Donor Liquids, J. Am. Chem. Soc., 1941, 63, 2475. [all data]

Crenshaw, Cope, et al., 1938
Crenshaw, J.L.; Cope, A.C.; Finkelstein, N.; Rogan, R., The Dioxanates of the Mercuric Halides, J. Am. Chem. Soc., 1938, 60, 2308. [all data]

Earp and Glasstone, 1935
Earp, D.P.; Glasstone, S., Dielectric polarisation and molecular-compound formation in solution, J. Chem. Soc., 1935, 1935, 1709. [all data]

Sutton and Brockway, 1935
Sutton, L.E.; Brockway, L.O., The Electron Diffraction Investigation of the Molecular Structures of (1) Chlorine Monoxide, Oxygen Fluoride, Dimethyl Ether, and 1,4-Dioxane and of (2) Methyl Chloride, Methylene CHloride, and Chlor, J. Am. Chem. Soc., 1935, 57, 473. [all data]

Gillis and Delaunois, 1934
Gillis, J.; Delaunois, A., Melting point, boiling point, refractive indices and densities of the system water - 1,4 dioxane, Recl. Trav. Chim. Pays-Bas, 1934, 53, 186-90. [all data]

Smyth and Walls, 1931
Smyth, C.P.; Walls, W.S., Electric moment and molecular structure: IV the glycols, J. Am. Chem. Soc., 1931, 53, 2115-22. [all data]


Notes

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