1,4-Dioxane

• Formula: C₄H₈O₂
• Molecular weight: 88.1051
• IUPAC Standard InChI: InChI=1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2 Copy

  
• IUPAC Standard InChIKey: RYHBNJHYFVUHQT-UHFFFAOYSA-N Copy
• CAS Registry Number: 123-91-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: p-Dioxane; p-Dioxan; Di(ethylene oxide); Diethylene dioxide; Diethylene ether; Dioxan; Dioxane; Dioxyethylene ether; 1,4-Diethylene dioxide; 1,4-Dioxan; 1,4-Dioxacyclohexane; Glycol ethylene ether; Tetrahydro-p-dioxin; Diokan; Dioksan; Diossano-1,4; Dioxaan-1,4; Dioxan-1,4; Dioxane-1,4; Dioxanne; NCI-C03689; Tetrahydro-1,4-dioxin; p-Dioxin, tetrahydro-; Rcra waste number U108; UN 1165; 1,4-Dioxin, tetrahydro-; 1,4-Diethyleneoxide; Glycol ethylene ether 8; NE 220; NSC 8728
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• Information on this page:
  • Normal boiling point
  • References
  • Notes
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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Rao and Reddy, 1988
Rao, K.P.C.; Reddy, K.S. (see subram k), Viscosities of Trichloroethylene with Ketones and 1,4-Dioxane at 298.15, 308.15, and 318.15 K, J. Chem. Eng. Data, 1988, 33, 130. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Rao and Naidu, 1973
Rao, M.V.P.; Naidu, P.R., Excess volumes and viscosities of dioxane-pyridine mixture, Proc. - Indian Acad. Sci., Sect. A, 1973, 78, 65. [all data]

Fort and Moore, 1965
Fort, R.J.; Moore, W.R., Adiabatic compressibilities of binary liquid mixtures, Trans. Faraday Soc., 1965, 61, 2102. [all data]

Amaya, 1961
Amaya, K., Thermodynamical studies on bionary systems consisting of polar and non-polar liquids. II. the measurement of the heats of mixing for binary systems of polar and non-polar liquids, Bull. Chem. Soc. Jpn., 1961, 34, 1278. [all data]

Schott, 1961
Schott, H., Densities, Refractive Indices, and Molar Refractions of the System Water-Dioxane at 25 C, J. Chem. Eng. Data, 1961, 6, 19-20. [all data]

McCormack, Walkup, et al., 1956
McCormack, J.B.; Walkup, J.H.; Rush, R.I., Boiling Point Comp. Diagram for the Sys. 1,4-Dioxane-n-Butyl Alcohol alcohol, J. Phys. Chem., 1956, 60, 826. [all data]

Wotiz, Hollingsworth, et al., 1956
Wotiz, J.H.; Hollingsworth, C.A.; Dessy, R.E., The reaction of 1-Alkynes with Organometallic Compounds IV. Reactions in the Presence of Dioxane, J. Am. Chem. Soc., 1956, 78, 1221-3. [all data]

Hammond and Stokes, 1955
Hammond, B.R.; Stokes, R.H., Diffusion in Binary Liqu8id Mixtures. Part 2 The Diffusion of Carbon Tetrachloride in SOme Organic Solvents at 25 deg, Trans. Faraday Soc., 1955, 51, 1641. [all data]

Jung, Miller, et al., 1953
Jung, S.L.; Miller, J.G.; Day, A.R., Effect of Structue on Reactivity. VIII. Aminolysis of Methyl Acetate with Some β-Phenylethylamines, J. Am. Chem. Soc., 1953, 75, 4664. [all data]

Griffiths, 1952
Griffiths, V.S., Densities of SOme Binary Liquid Mixtures, Part I., J. Chem. Soc., 1952, 1952, 1326. [all data]

Kortuem, Moegling, et al., 1950
Kortuem, G.; Moegling, D.; Woerner, F., The Efficiency of Circulation Apparatuses for Determining Boiling and Vapor Pressure Diagrams of Binary Liquids., Chem.-Ing.-Tech., 1950, 22, 453. [all data]

Lecat, 1947
Lecat, M., Some azeotropes of which one constituant is heterocyclic nitrogen, Ann. Soc. Sci. Bruxelles, Ser. 1, 1947, 61, 73. [all data]

Lecat, 1943
Lecat, M., Negative and other Azeotropes, C. R. Hebd. Seances Acad. Sci., 1943, 217, 242. [all data]

Ewell and Welch, 1941
Ewell, R.H.; Welch, L.M., Maximum Boiling Mixtures of chloroparaffins with Donor Liquids, J. Am. Chem. Soc., 1941, 63, 2475. [all data]

Crenshaw, Cope, et al., 1938
Crenshaw, J.L.; Cope, A.C.; Finkelstein, N.; Rogan, R., The Dioxanates of the Mercuric Halides, J. Am. Chem. Soc., 1938, 60, 2308. [all data]

Earp and Glasstone, 1935
Earp, D.P.; Glasstone, S., Dielectric polarisation and molecular-compound formation in solution, J. Chem. Soc., 1935, 1935, 1709. [all data]

Sutton and Brockway, 1935
Sutton, L.E.; Brockway, L.O., The Electron Diffraction Investigation of the Molecular Structures of (1) Chlorine Monoxide, Oxygen Fluoride, Dimethyl Ether, and 1,4-Dioxane and of (2) Methyl Chloride, Methylene CHloride, and Chlor, J. Am. Chem. Soc., 1935, 57, 473. [all data]

Gillis and Delaunois, 1934
Gillis, J.; Delaunois, A., Melting point, boiling point, refractive indices and densities of the system water - 1,4 dioxane, Recl. Trav. Chim. Pays-Bas, 1934, 53, 186-90. [all data]

Smyth and Walls, 1931
Smyth, C.P.; Walls, W.S., Electric moment and molecular structure: IV the glycols, J. Am. Chem. Soc., 1931, 53, 2115-22. [all data]

Notes

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• Symbols used in this document:
  

  Tboil

  Boiling point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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