1,4-Dioxane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil374.3 ± 0.8KAVGN/AAverage of 20 out of 21 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus285. ± 1.KAVGN/AAverage of 17 out of 18 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple284.1KN/AJacobs and Parks, 1934Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc587.3KN/ACristou, Young, et al., 1991Uncertainty assigned by TRC = 1. K; TRC
Tc588.15KN/AGlaser and Ruland, 1957Uncertainty assigned by TRC = 2. K; TRC
Tc588.KN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 2. K; TRC
Tc585.15KN/AHojendahl, 1946Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc54.0000atmN/AGlaser and Ruland, 1957Uncertainty assigned by TRC = 3.0000 atm; TRC
Pc51.42atmN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 0.6804 atm; TRC
Pc49.35atmN/AHojendahl, 1946Uncertainty assigned by TRC = 0.69 atm; by extrapolation of vapor pressure to critical temperature; TRC
Quantity Value Units Method Reference Comment
Vc0.239l/molN/ACristou, Young, et al., 1991Uncertainty assigned by TRC = 0.008 l/mol; TRC
Vc0.239l/molN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 0.004 l/mol; TRC
Quantity Value Units Method Reference Comment
ρc4.09mol/lN/AHojendahl, 1946Uncertainty assigned by TRC = 0.11 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap9.0 ± 0.9kcal/molAVGN/AAverage of 7 values; Individual data points

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
8.164374.5N/AMajer and Svoboda, 1985 
9.1300.AStephenson and Malanowski, 1987Based on data from 285. - 375. K.; AC
8.72350.N/ACastellari, Comelli, et al., 1984Based on data from 329. - 372. K.; AC
8.91308.N/AVinson and Martin, 1963Based on data from 293. - 398. K. See also Boublik, Fried, et al., 1984.; AC
8.56273.VGallaugher and Hibbert, 1937ALS
8.8318.N/AHovorka, Schaefer, et al., 1936Based on data from 283. - 353. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
293. - 378.4.575641570.093-31.297Crenshaw, Cope, et al., 1938Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
8.51255.AStull, 1947Based on data from 237. - 272. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
3.069284.1Domalski and Hearing, 1996AC
2.8394283.2Roth and Meyer, 1933DH

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
10.0283.2Roth and Meyer, 1933DH

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
2.10272.9Domalski and Hearing, 1996CAL
10.80284.1

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.5619272.9crystaline, IIcrystaline, IJacobs and Parks, 1934, 2DH
3.0700284.1crystaline, IliquidJacobs and Parks, 1934, 2DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
2.1272.9crystaline, IIcrystaline, IJacobs and Parks, 1934, 2DH
10.8284.1crystaline, IliquidJacobs and Parks, 1934, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jacobs and Parks, 1934
Jacobs, C.J.; Parks, G.S., Thermal data on organic compounds. XIV. Some heat capacity, entropy and free energy data for cyclic substances, J. Am. Chem. Soc., 1934, 56, 1513-17. [all data]

Cristou, Young, et al., 1991
Cristou, G.; Young, C.L.; Svejda, P., Fluid Phase Equilibria, 1991, 67, 45-53. [all data]

Glaser and Ruland, 1957
Glaser, F.; Ruland, H., Untersuchungsen über dampfdruckkurven und kritische daten einiger technisch wichtiger organischer substanzen, Chem. Ing. Techn., 1957, 29, 772. [all data]

Kobe, Ravicz, et al., 1956
Kobe, K.A.; Ravicz, A.E.; Vohra, S.P., Critical Properties and Vapor Pressures of Some Ethers and Heterocyclic Compounds, J. Chem. Eng. Data, 1956, 1, 50. [all data]

Hojendahl, 1946
Hojendahl, K., Dielectric Constant, Viscosity, Surface Tension, and Critical Data of Boron Tribromide, Dioxane, and Ethylene Dichloride, Mat.-Fys. Medd. - K. Dan. Vidensk. Selsk., 1946, 24, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Castellari, Comelli, et al., 1984
Castellari, Carlo; Comelli, Fabio; Francesconi, Romolo, Vapor-liquid equilibria in binary systems containing 1,3-dioxolane at isobaric conditions. 4. Binary mixtures of 1,3-dioxolane with 1,4-dioxane and 1,1,2,2-tetrachloroethane, J. Chem. Eng. Data, 1984, 29, 2, 126-128, https://doi.org/10.1021/je00036a008 . [all data]

Vinson and Martin, 1963
Vinson, Carl G.; Martin, Joseph J., Heat of Vaporization and Vapor Pressure of 1,4-Dioxane., J. Chem. Eng. Data, 1963, 8, 1, 74-75, https://doi.org/10.1021/je60016a021 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Gallaugher and Hibbert, 1937
Gallaugher, A.F.; Hibbert, H., Studies on reactions relating to carbohydrates and polysaccharides. LV. Vapor pressures of the polyethylene glycols and their derivatives, J. Am. Chem. Soc., 1937, 59, 2521-2525. [all data]

Hovorka, Schaefer, et al., 1936
Hovorka, Frank; Schaefer, Ralph A.; Dreisbach, Dale, The System Dioxane and Water, J. Am. Chem. Soc., 1936, 58, 11, 2264-2267, https://doi.org/10.1021/ja01302a051 . [all data]

Crenshaw, Cope, et al., 1938
Crenshaw, J.L.; Cope, A.C.; Finkelstein, N.; Rogan, R., The Dioxanates of the Mercuric Halides, J. Am. Chem. Soc., 1938, 60, 10, 2308-2311, https://doi.org/10.1021/ja01277a010 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Roth and Meyer, 1933
Roth, W.A.; Meyer, I., Einige physikalisch-chemische konstanten des dioxans, Z. Electrochem., 1933, 39, 35-37. [all data]

Jacobs and Parks, 1934, 2
Jacobs, C.J.; Parks, G.S., Thermal data on organic compounds. XIV. Some heat capacity, entropy and free energy data for cyclic substances, J. Am. Chem. Soc., 1934, 56, 1513-1517. [all data]


Notes

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