Nitrogen(1+), hydrodi-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(HN2+ • 4Nitrogen) + Nitrogen = (HN2+ • 5Nitrogen)

By formula: (HN2+ • 4N2) + N2 = (HN2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr12. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Δr13.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mori, 1989gas phase
Δr84.J/mol*KN/AHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
5.992.PHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated

(HN2+ • 2Nitrogen) + Nitrogen = (HN2+ • 3Nitrogen)

By formula: (HN2+ • 2N2) + N2 = (HN2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Δr16.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Δr84.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase
Δr84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(HN2+ • 3Nitrogen) + Nitrogen = (HN2+ • 4Nitrogen)

By formula: (HN2+ • 3N2) + N2 = (HN2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Δr15.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSHiraoka and Mori, 1989gas phase
Δr84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(HN2+ • Nitrogen) + Nitrogen = (HN2+ • 2Nitrogen)

By formula: (HN2+ • N2) + N2 = (HN2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr15. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Δr17.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Δr80.3J/mol*KPHPMSHiraoka and Mori, 1989gas phase
Δr75.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

HN2+ + Nitrogen = (HN2+ • Nitrogen)

By formula: HN2+ + N2 = (HN2+ • N2)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Δr60.7kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase
Δr85.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase

(HN2+ • 10Nitrogen) + Nitrogen = (HN2+ • 11Nitrogen)

By formula: (HN2+ • 10N2) + N2 = (HN2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr7.20kJ/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated

(HN2+ • 9Nitrogen) + Nitrogen = (HN2+ • 10Nitrogen)

By formula: (HN2+ • 9N2) + N2 = (HN2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ • 5Nitrogen) + Nitrogen = (HN2+ • 6Nitrogen)

By formula: (HN2+ • 5N2) + N2 = (HN2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr9. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ • 6Nitrogen) + Nitrogen = (HN2+ • 7Nitrogen)

By formula: (HN2+ • 6N2) + N2 = (HN2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ • 7Nitrogen) + Nitrogen = (HN2+ • 8Nitrogen)

By formula: (HN2+ • 7N2) + N2 = (HN2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ • 8Nitrogen) + Nitrogen = (HN2+ • 9Nitrogen)

By formula: (HN2+ • 8N2) + N2 = (HN2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ • Hydrogen) + Hydrogen = (HN2+ • 2Hydrogen)

By formula: (HN2+ • H2) + H2 = (HN2+ • 2H2)

Quantity Value Units Method Reference Comment
Δr7.5kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Δr71.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

HN2+ + Hydrogen = (HN2+ • Hydrogen)

By formula: HN2+ + H2 = (HN2+ • H2)

Quantity Value Units Method Reference Comment
Δr30.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

HN2+ + helium = (HN2+ • helium)

By formula: HN2+ + He = (HN2+ • He)

Quantity Value Units Method Reference Comment
Δr5.0kJ/molSCATTERINGMeuwly, Nizkorodov, et al., 1996gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Chem. Phys., 1989, 137, 1-3, 345, https://doi.org/10.1016/0301-0104(89)87119-8 . [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]

Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

Meuwly, Nizkorodov, et al., 1996
Meuwly, M.; Nizkorodov, S.A.; Maier, J.P.; Bieske, E.J., Mid-Infrared Spectra of He-HN2+ and He2-HN2+, J. Chem. Phys., 1996, 104, 11, 3876, https://doi.org/10.1063/1.471244 . [all data]


Notes

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