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Nitrogen(1+), hydrodi-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(HN2+ bullet 4Nitrogen) + Nitrogen = (HN2+ bullet 5Nitrogen)

By formula: (HN2+ bullet 4N2) + N2 = (HN2+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar3.0 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Deltar3.2kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar20.cal/mol*KN/AHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
1.492.PHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated

(HN2+ bullet 2Nitrogen) + Nitrogen = (HN2+ bullet 3Nitrogen)

By formula: (HN2+ bullet 2N2) + N2 = (HN2+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar3.4 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Deltar3.8kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar20.1cal/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar20.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(HN2+ bullet 3Nitrogen) + Nitrogen = (HN2+ bullet 4Nitrogen)

By formula: (HN2+ bullet 3N2) + N2 = (HN2+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar3.3 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Deltar3.5kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar21.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar20.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

(HN2+ bullet Nitrogen) + Nitrogen = (HN2+ bullet 2Nitrogen)

By formula: (HN2+ bullet N2) + N2 = (HN2+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar3.6 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Deltar4.0kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar19.2cal/mol*KPHPMSHiraoka and Mori, 1989gas phase
Deltar18.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

HN2+ + Nitrogen = (HN2+ bullet Nitrogen)

By formula: HN2+ + N2 = (HN2+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar16.0kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Deltar14.5kcal/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase
Deltar20.4cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase

(HN2+ bullet 10Nitrogen) + Nitrogen = (HN2+ bullet 11Nitrogen)

By formula: (HN2+ bullet 10N2) + N2 = (HN2+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar1.72kcal/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated

(HN2+ bullet 9Nitrogen) + Nitrogen = (HN2+ bullet 10Nitrogen)

By formula: (HN2+ bullet 9N2) + N2 = (HN2+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ bullet 5Nitrogen) + Nitrogen = (HN2+ bullet 6Nitrogen)

By formula: (HN2+ bullet 5N2) + N2 = (HN2+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar2.2 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar20.9cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ bullet 6Nitrogen) + Nitrogen = (HN2+ bullet 7Nitrogen)

By formula: (HN2+ bullet 6N2) + N2 = (HN2+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar2.0 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar21.4cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ bullet 7Nitrogen) + Nitrogen = (HN2+ bullet 8Nitrogen)

By formula: (HN2+ bullet 7N2) + N2 = (HN2+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar1.9 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar21.5cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ bullet 8Nitrogen) + Nitrogen = (HN2+ bullet 9Nitrogen)

By formula: (HN2+ bullet 8N2) + N2 = (HN2+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 0.3kcal/molPHPMSHiraoka and Mori, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka and Mori, 1989gas phase

(HN2+ bullet Hydrogen) + Hydrogen = (HN2+ bullet 2Hydrogen)

By formula: (HN2+ bullet H2) + H2 = (HN2+ bullet 2H2)

Quantity Value Units Method Reference Comment
Deltar1.8kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

HN2+ + Hydrogen = (HN2+ bullet Hydrogen)

By formula: HN2+ + H2 = (HN2+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar7.2kcal/molPHPMSHiraoka, Saluja, et al., 1979gas phase
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase

HN2+ + helium = (HN2+ bullet helium)

By formula: HN2+ + He = (HN2+ bullet He)

Quantity Value Units Method Reference Comment
Deltar1.2kcal/molSCATTERINGMeuwly, Nizkorodov, et al., 1996gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T., Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Chem. Phys., 1989, 137, 1-3, 345, https://doi.org/10.1016/0301-0104(89)87119-8 . [all data]

Hiraoka, Saluja, et al., 1979
Hiraoka, K.; Saluja, P.P.S.; Kebarle, P., Stabilities of Complexes (N2)nH+, (CO)nH+ and (O2)nH+ for n = 1 to 7 Based on Gas Phase Ion Equilibrium Measurements, Can. J. Chem., 1979, 57, 16, 2159, https://doi.org/10.1139/v79-346 . [all data]

Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

Meuwly, Nizkorodov, et al., 1996
Meuwly, M.; Nizkorodov, S.A.; Maier, J.P.; Bieske, E.J., Mid-Infrared Spectra of He-HN2+ and He2-HN2+, J. Chem. Phys., 1996, 104, 11, 3876, https://doi.org/10.1063/1.471244 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References