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1-Butanol, 3-methyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-85.07 ± 0.38kcal/molCcbMarkovnik, Shvarko, et al., 1987Uc =-3320.42 kJ/mol; ALS
Deltafliquid-85.18 ± 0.14kcal/molCcbChao and Rossini, 1965ALS
Quantity Value Units Method Reference Comment
Deltacliquid-795.08 ± 0.38kcal/molCcbMarkovnik, Shvarko, et al., 1987Uc =-3320.42 kJ/mol; Corresponding «DELTA»fliquid = -85.067 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-794.98 ± 0.12kcal/molCcbChao and Rossini, 1965Corresponding «DELTA»fliquid = -85.17 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
61.59347.Swietoslawski and Zielenkiewicz, 1958Mean value 22 to 126°C.; DH
50.076295.52Zhdanov, 1945T = 7 to 47°C. Value is unsmoothed experimental datum.; DH
50.19303.Willams and Daniels, 1924T = 303 to 343 K. Equation only; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Markovnik, Shvarko, et al., 1987
Markovnik, V.S.; Shvarko, O.V.; Al'khimovich, V.M.; Sachek, A.I., Temperature dependence of vapor pressure, of heats of formation, combustion, and vaporization of 3-methyl-1-butanol, Termodin. Org. Soedin., 1987, 68-70. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Swietoslawski and Zielenkiewicz, 1958
Swietoslawski, W.; Zielenkiewicz, A., Mean specific heats of binary positive azeotropes, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1958, 6, 367-369. [all data]

Zhdanov, 1945
Zhdanov, A.K., On the thermal capacity of some pure liquids and azeotropic mixtures, Zhur. Obshch. Khim., 1945, 15, 895-902. [all data]

Willams and Daniels, 1924
Willams, J.W.; Daniels, F., The specific heats of certain organic liquids at elevated temperatures, J. Am. Chem. Soc., 1924, 46, 903-917. [all data]


Notes

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