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Formamide, N-methyl-

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C2H4NO- + Formamide, N-methyl- = (C2H4NO- bullet Formamide, N-methyl-)

By formula: C2H4NO- + C2H5NO = (C2H4NO- bullet C2H5NO)

Quantity Value Units Method Reference Comment
Deltar120. ± 8.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

pyrrolide anion + Formamide, N-methyl- = (pyrrolide anion bullet Formamide, N-methyl-)

By formula: C4H4N- + C2H5NO = (C4H4N- bullet C2H5NO)

Quantity Value Units Method Reference Comment
Deltar110. ± 8.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

Lithium ion (1+) + Formamide, N-methyl- = (Lithium ion (1+) bullet Formamide, N-methyl-)

By formula: Li+ + C2H5NO = (Li+ bullet C2H5NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
166.373.CIDCHerreros, Gal, et al., 1999RCD

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1988
Meot-Ner (Mautner), M., Models for Strong Interactions in Proteins and Enzymes. 2. Interactions of Ions with the Peptide Link and Imidazole, J. Am. Chem. Soc., 1988, 110, 10, 3075, https://doi.org/10.1021/ja00218a014 . [all data]

Herreros, Gal, et al., 1999
Herreros, M.; Gal, J.-F.; Maria, P.-C.; Decouzon, M., Gas-Phase Basicity of Simple Amides Toward Proton and Lithium Cation: An Experimental and Theoretical Study, Eur. J. Mass Spectrom., 1999, 5, 1, 259, https://doi.org/10.1255/ejms.282 . [all data]


Notes

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