β-Myrcene

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Normal alkane RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxInnowaxHP-InnowaxAT-WaxHP-Innowax
Column length (m) 60.30.60.60.30.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.220.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.60.60.50.
Tend (C) 230.250.220.280.250.
Heat rate (K/min) 2.8.5.4.5.
Initial hold (min)  1.1. 5.
Final hold (min) 5.2.755. 10.
I 1152.1162.1170.1130.1174.
ReferenceBendiabdellah, El Amine Dib, et al., 2012Siristova, Prinosilova, et al., 2012Feng, Cui, et al., 2011Kiss, Csoka, et al., 2011Menichini, Tundis, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxBP-20DB-WaxSupelcowax-10DB-Wax
Column length (m) 60. 15.30.30.
Carrier gas HeliumNitrogenHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.22 0.250.200.25
Phase thickness (μm) 0.25 0.250.200.25
Tstart (C) 60.60.40.70.80.
Tend (C) 230.200.260.220.240.
Heat rate (K/min) 2.5.4.3.3.
Initial hold (min)      
Final hold (min) 30. 5.15.2.
I 1141.1155.1178.1160.1157.
ReferenceDib, Djabou, et al., 2010Mishra, Chaudhary, et al., 2010Miyazawa, Kawauchi, et al., 2010Neves, Rosa, et al., 2010Vahirua-Lechat, Mitermite, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10SupelcowaxDB-WaxRTX-WaxInnowax
Column length (m) 30.60.30.60.30.
Carrier gas HeliumNitrogenHydrogenHeliumHelium
Substrate      
Column diameter (mm) 0.250.350.250.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.60.30.60.40.
Tend (C) 220.230.230.230.250.
Heat rate (K/min) 2.4.8.2.6.
Initial hold (min)   5. 1.
Final hold (min)  40.10.30.4.
I 1157.1156.1160.1143.1165.
ReferenceBenites, Moiteiro, et al., 2009Gauvin-Bialecki and Marodon, 2009Karlsson, Birgersson, et al., 2009Museli, Pau, et al., 2009Seo, Kim, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-InnowaxDB-WaxDB-WaxHP-FFAP
Column length (m) 60.30.60.60.30.
Carrier gas HeliumNitrogenHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.320.320.25
Phase thickness (μm) 0.250.520.250.250.25
Tstart (C) 50.35.30.30.40.
Tend (C) 220.205.200.200.120.
Heat rate (K/min) 3.3.2.2.3.
Initial hold (min) 2.10.4.4.3.
Final hold (min) 70.10.30.30.5.
I 1164.1174.1157.1160.1169.
ReferenceShimizu, Imayoshi, et al., 2009Wannes, Mhamdi, et al., 2009Beck, Higbee, et al., 2008Beck, Higbee, et al., 2008Guzman-Geronimo, Lopez, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP InnowaxHP-InnowaxCP-Wax 52CBCarbowaxHP-Wax
Column length (m) 30.30.60.60.30.
Carrier gas HeliumN2HeHeN2
Substrate      
Column diameter (mm) 0.320.250.250.20.25
Phase thickness (μm) 0.500.250.250.250.25
Tstart (C) 60.50.40.60.50.
Tend (C) 260.240.220.250.250.
Heat rate (K/min) 3.5.3.2.5.
Initial hold (min)  1. 8. 
Final hold (min)  4. 15.10.
I 1160.1152.1173.1165.1161.
ReferenceCapetanos, Saroglou, et al., 2007Cheraif, Ben Jannet, et al., 2007Chyau, Tsai, et al., 2007Ferhat, Meklati, et al., 2007Fredj, Marzouk, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxTC-FFAPTC-FFAPCarbowax 20MFFAP
Column length (m) 30.  30.30.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.5
Tstart (C) 60.60.60.60.35.
Tend (C) 240.220.220.230.320.
Heat rate (K/min) 2.3.3.3.4.
Initial hold (min)     5.
Final hold (min) 20.30.30. 45.
I 1163.1174.1172.1149.1192.
ReferenceHachicha, Skanji, et al., 2007Kurose, Okamura, et al., 2007Kurose, Okamura, et al., 2007Limberger, Scopel, et al., 2007Nebesny, Budryn, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSupelcowax-10CP-Wax 52CBSupelcowax-10Supelcowax-10
Column length (m) 60.30.60.30.30.
Carrier gas HeHeHe  
Substrate      
Column diameter (mm) 0.320.20.320.250.25
Phase thickness (μm) 0.250.20.50.250.25
Tstart (C) 70.70.40.40.40.
Tend (C) 220.220.220.210.250.
Heat rate (K/min) 4.3.4.2.2.
Initial hold (min)   8.  
Final hold (min)  15.20.33.33.
I 1160.1164.1172.1174.1172.
ReferencePala-Paul, Brophy, et al., 2007Pinto, Salgueiro, et al., 2007Povolo, Contarini, et al., 2007Sylvestre, Longtin, et al., 2007Sylvestre, Pichette, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10DB-WaxInnowaxInnowaxDB-Wax
Column length (m) 30.60.30.30.30.
Carrier gas HeHeN2N2Helium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.50.50.40.
Tend (C) 250.180.280.280.250.
Heat rate (K/min) 3.3.9.9.3.
Initial hold (min) 5.8.3.3. 
Final hold (min) 10.80.3.3.20.
I 1172.1153.1156.1167.1148.
ReferenceVichi, Riu-Aumatell, et al., 2007Wei A. and Shibamoto T., 2007Abdelwahed, Hayder, et al., 2006Abdelwahed, Hayder, et al., 2006Berlinet, Brat, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase AT-WaxBP-20BP-20DB-WaxSupelcowax 10
Column length (m) 60.50.50.60.30.
Carrier gas HeHe HeHelium
Substrate      
Column diameter (mm) 0.250.220.220.250.20
Phase thickness (μm) 0.250.250.250.50.20
Tstart (C) 60.60.60.50.70.
Tend (C) 200.220.220.230.220.
Heat rate (K/min) 4.2.2.3.3.
Initial hold (min)    2. 
Final hold (min) 20.20.20.20.15.
I 1159.1157.1162.1162.1161.
ReferenceBorges, Rojas, et al., 2006Boti, Muselli, et al., 2006Boti, Yao, et al., 2006Cai, Lin, et al., 2006Cavaleiro, Pinto, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxBP-20BP-20CP-Wax 52CB
Column length (m) 60.60.50.50.30.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.220.220.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.70.60.60.60.
Tend (C) 230.230.220.220.220.
Heat rate (K/min) 2.2.2.2.3.3
Initial hold (min) 2.2.  7.
Final hold (min) 20.20.20.20.3.
I 1168.1176.1159.1159.1145.
ReferenceChoi H.S., 2006Choi, 2006Fanciullino, Tomi, et al., 2006Fanciullino, Tomi, et al., 2006Hymete, Rohloff, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase FFAPDB-WaxSupelcowaxHP-WaxHP-20M
Column length (m) 20.60.30.30.30.
Carrier gas He N2NitrogenN2
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 90.70.50.50.50.
Tend (C) 250.230.200.280.250.
Heat rate (K/min) 6.2.5.5.5.
Initial hold (min)  2.   
Final hold (min)  20. 5.10.
I 1182.1164.1165.1152.1152.
ReferenceKitchlu, Bakshi, et al., 2006Lan Phi N.T., Nishiyama C., et al., 2006Martin, Joseph, et al., 2006Marzouk, Mansour, et al., 2006Marzouk, Neffati, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-InnowaxNB-20MDB-WaxSupelcowax-10Supelcowax-10
Column length (m) 60.30.60.30.30.
Carrier gas HeliumHe HeHe
Substrate      
Column diameter (mm) 0.250.20.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.50.70.50.50.
Tend (C) 240.250.230.220.250.
Heat rate (K/min) 3.2.2.4.4.
Initial hold (min)   2.1.1.
Final hold (min) 20. 20.10.10.
I 1156.1152.1165.1161.1154.
ReferenceMendivil, Rodrigues, et al., 2006Orav, Raal, et al., 2006Sawamura, Onishi, et al., 2006Wong, Lim, et al., 2006Wong, Sivasothy, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MInnowaxHP-20MHP-InnowaxSupelcowax
Column length (m) 60.50.50.30.60.
Carrier gas N2HeHeliumHeHe
Substrate      
Column diameter (mm) 0.250.20.200.250.2
Phase thickness (μm) 0.250.50.200.170.2
Tstart (C) 40.60.70.60.60.
Tend (C) 190.250.250.210.230.
Heat rate (K/min) 10.2.4.4.4.
Initial hold (min) 2. 4.3.30.
Final hold (min) 15.60.10.15. 
I 1156.1140.1149.1168.1136.
ReferenceBabu and Kaul, 2005Bendimerad and Bendiab, 2005Bezic, Skocibusic, et al., 2005Ferretti, Maggi, et al., 2005Gauvin and Smadja, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase StabilwaxStabilwaxHP-20MHP-20MDB-Wax
Column length (m) 30.30.50.50.60.
Carrier gas H2 HeliumHeliumN2
Substrate      
Column diameter (mm) 0.320.320.200.200.25
Phase thickness (μm) 0.50.50.200.200.25
Tstart (C) 40.40.70.70.70.
Tend (C) 280.280.180.180.230.
Heat rate (K/min) 6.6.4.4.2.
Initial hold (min) 5.5.4.4.2.
Final hold (min) 5.5.10.10.20.
I 1143.1143.1148.1149.1161.
ReferenceJirovetz, Buchbauer, et al., 2005Jirovetz, Buchbauer, et al., 2005, 2Kulisic, Radonic, et al., 2005Kulisic, Radonic, et al., 2005Njoroge, Koaze, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxStabilwax DADB-WaxCP-Wax 52CBCP-Wax 52CB
Column length (m) 60.60.60.30.30.
Carrier gas N2 HeHeHe
Substrate      
Column diameter (mm) 0.250.250.320.320.32
Phase thickness (μm) 0.250.50.250.250.25
Tstart (C) 70.40.35.40.40.
Tend (C) 230.180.220.220.220.
Heat rate (K/min) 2.5.3.4.4.
Initial hold (min) 2.5. 1.1.
Final hold (min) 20.    
I 1161.1128.1160.1161.1161.
ReferenceNjoroge, Koaze, et al., 2005, 2Nogueira, Lubachevsky, et al., 2005Palá-Paúl, Pérez-Alonso, et al., 2005Rohloff and Bones, 2005Rohloff and Bones, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSupelcowax-10Supelcowax-10Supelcowax-10DB-Wax
Column length (m) 30.30.30.30.30.
Carrier gas He  HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.40.50.90.
Tend (C) 250.210.220.220.220.
Heat rate (K/min) 4.2.3.4.7.
Initial hold (min)  2.5.3.2.
Final hold (min) 10.33.10.30.5.
I 1154.1157.1172.1165.1181.
ReferenceSalehi, Sonboli, et al., 2005Stevanovic, Garneau, et al., 2005Vichi, Riu-Aumatell, et al., 2005Wong, Lee, et al., 2005Agnihotri, Thappa, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20DB-WaxDB-WaxSupelcowax-10Supelcowax-10
Column length (m) 50.60.60.60.30.
Carrier gas  N2N2HeN2
Substrate      
Column diameter (mm) 0.220.250.250.20.25
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 60.70.70.60.40.
Tend (C) 220.230.230.200.230.
Heat rate (K/min) 2.2.2.4.2.
Initial hold (min)  2.2.  
Final hold (min) 20.20.20.40. 
I 1156.1170.1165.1134.1161.
ReferenceBlanc, Muselli, et al., 2004Choi, 2004Choi, 2004, 2Gauvin, Ravaomanarivo, et al., 2004González, Guerra, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxSupelcowax-10HP-FFAPInnowax FSC
Column length (m) 60.60.30.30.60.
Carrier gas HeHe HeHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)   0.250.25 
Tstart (C) 60.60.40.40.60.
Tend (C) 220.220.210.120.220.
Heat rate (K/min) 2.2.2.5.4.
Initial hold (min) 4.4.2.5.10.
Final hold (min)   33.3. 
I 1163.1163.1174.1160.1174.
ReferenceJiang and Kubota, 2004Jiang and Kubota, 2004Lopez Arze, Collin, et al., 2004López, Guzmán, et al., 2004Lourens, Reddy, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20PEG-20MPEG-20MSupelcowax-10Supelcowax-10
Column length (m) 25.50.50.50.50.
Carrier gas N2  HeHe
Substrate      
Column diameter (mm) 0.250.200.200.20.2
Phase thickness (μm) 0.250.200.200.250.25
Tstart (C) 60.40.40.70.70.
Tend (C) 220.180.180.230.230.
Heat rate (K/min) 5.3.3.2.2.
Initial hold (min)  5.5.  
Final hold (min)  30.30.  
I 1165.1162.1170.1160.1161.
ReferenceMallavarapu, Kulkarni, et al., 2004Narain, Almeida, et al., 2004Narain, Almeida, et al., 2004Orav, Stulova, et al., 2004Orav, Stulova, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxInnowaxNB-20MSW-10DB-Wax
Column length (m) 60.50.50.50.60.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.320.20.20.200.25
Phase thickness (μm) 0.250.20.250.250.25
Tstart (C) 35.70.50.50.70.
Tend (C) 220.220.250.230.230.
Heat rate (K/min) 3.4.2.2.2.
Initial hold (min)     2.
Final hold (min)     20.
I 1162.1171.1160.1162.1174.
ReferencePalá-Paúl, Brophy, et al., 2004Palá-Paúl, García-Jiménez, et al., 2004Raal, Arak, et al., 2004Raal, Paaver, et al., 2004Sawamura, Son, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-WaxSupelcowax-10HP-20MHP-20M
Column length (m) 60.30.30.50.50.
Carrier gas NitrogenN2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.20.2
Phase thickness (μm) 0.250.250.250.20.2
Tstart (C) 70.60.60.70.70.
Tend (C) 230.220.240.180.180.
Heat rate (K/min) 2.5.4.4.4.
Initial hold (min) 2.10. 4.4.
Final hold (min)    10.10.
I 1174.1170.1160.1148.1148.
ReferenceSawamura, Sou, et al., 2004Bertoli, Menichini, et al., 2003Cabanillas, Lopez, et al., 2003Juteau, Jerkovic, et al., 2003Mastelic and Jerkovic, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase TC-WaxDB-WaxSupelcowax-10Carbowax 20MSW-10
Column length (m) 60.60.50.50.50.
Carrier gas HeHeliumHeN2He
Substrate      
Column diameter (mm) 0.250.250.20.250.20
Phase thickness (μm)   0.250.250.25
Tstart (C) 80.70.70.90.50.
Tend (C) 240.210.230.220.250.
Heat rate (K/min) 3.2.2.3.2.
Initial hold (min)      
Final hold (min)  60.   
I 1166.1166.1161.1153.1161.
ReferenceMiyazawa, Teranishi, et al., 2003Mookdasanit, Tamura, et al., 2003Orav, Kailas, et al., 2003Priestap, van Baren, et al., 2003Raal, Arak, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxHP-InnowaxInnowaxDB-WaxDB-Wax
Column length (m) 50.50.60.60.60.
Carrier gas   HeN2N2
Substrate      
Column diameter (mm) 0.20.20.250.250.25
Phase thickness (μm) 0.20.2 0.250.25
Tstart (C) 50.50.60.70.70.
Tend (C) 220.220.220.230.230.
Heat rate (K/min) 4.4.4.2.2.
Initial hold (min) 5.5.10.2.2.
Final hold (min)   10.20.20.
I 1157.1157.1174.1155.1168.
ReferenceStashenko, Jaramillo, et al., 2003Stashenko, Jaramillo, et al., 2003Suleimenov, Atazharova, et al., 2003Tu, Onishi, et al., 2003Tu, Onishi, et al., 2003, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxCarbowax 20MRTX-WaxDB-WaxCarbowax 20M
Column length (m) 50.25.60.60.30.
Carrier gas HeN2HeH2He
Substrate      
Column diameter (mm) 0.20.250.250.320.25
Phase thickness (μm) 0.20.250.50.250.325
Tstart (C) 70.50.40.40.50.
Tend (C) 190.250.180.245.215.
Heat rate (K/min) 5.4.5.1.54.
Initial hold (min)   5.  
Final hold (min)  10.20.20.20.
I 1167.1150.1178.1156.1156.
ReferenceVelasco-Negueruela, Pérez-Alonso, et al., 2003Zrira, Elamrani, et al., 2003Galindo-Cuspinera, Lubran, et al., 2002Gancel, Ollé, et al., 2002Kasali, Winterhalter, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10HP-WaxDB-WaxDB-WaxDB-Wax
Column length (m) 60.50.60.60.60.
Carrier gas HeN2N2N2He
Substrate      
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (μm) 0.50.250.250.250.25
Tstart (C) 70.75.70.70.40.
Tend (C) 220.220.230.230.200.
Heat rate (K/min) 2.3.2.2.2.
Initial hold (min)  4.2. 2.
Final hold (min)   20.  
I 1161.1153.1162.1169.1150.
ReferenceOrav, Kailas, et al., 2002Priestap, van Baren, et al., 2002Tu, Onishi, et al., 2002Tu, Thanh, et al., 2002Umano, Hagi, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxStabilwaxCarbowax 20MBP-20
Column length (m) 60.60.30.30.50.
Carrier gas HeHeH2HeHe
Substrate      
Column diameter (mm) 0.250.250.320.250.22
Phase thickness (μm) 0.25 0.250.250.25
Tstart (C) 45.40.60.50.60.
Tend (C) 240.220.280.215.230.
Heat rate (K/min) 3.2.10.4.2.
Initial hold (min)   5.  
Final hold (min)   5. 35.
I 1164.1184.1158.1156.1157.
ReferenceChristoph, 2001Jiang and Kubota, 2001Jirovetz L., Buchbauer G., et al., 2001Kasali, Oyedeji, et al., 2001Lota, de Rocca Serra, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase TC-WaxPEG-20MPEG-20MPEG-20MCarbowax 20M
Column length (m) 60.50.50.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.20.20.20.22
Phase thickness (μm)     0.25
Tstart (C) 80.70.70.70.60.
Tend (C) 250.250.220.220.220.
Heat rate (K/min) 4.2.2.2.2.
Initial hold (min)      
Final hold (min) 47.    
I 1170.1158.1161.1161.1155.
ReferenceMiyazawa, Kurose, et al., 2001Orav, Kailas, et al., 2001Orav and Kann, 2001Orav and Kann, 2001Vernin, Lageot, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxDB-WaxCP-Wax 52CBCP-Wax 52CBDB-Wax
Column length (m) 60.60.50.50.30.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.250.250.300.300.2
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 60.30.40.40.50.
Tend (C) 220.170.220.220.180.
Heat rate (K/min) 4.2.3.3.3.
Initial hold (min) 10.4.5.5.8.
Final hold (min) 10.30.   
I 1174.1157.1164.1164.1154.
ReferenceBaser, Özek, et al., 2000Buttery, Light, et al., 2000Chagonda, Makanda, et al., 2000Chagonda, Makanda, et al., 2000Franco and Shibamoto, 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxSupelcowax-10Supelcowax-10BP-20
Column length (m) 30.30.30.60.25.
Carrier gas HeHeHeHeNitrogen
Substrate      
Column diameter (mm) 0.20.20.320.250.50
Phase thickness (μm)   0.250.250.25
Tstart (C) 50.50.70.60.60.
Tend (C) 180.180.240.280.200.
Heat rate (K/min) 3.3.5.4.5.
Initial hold (min) 8.8.8.  
Final hold (min)   20.  
I 1155.1158.1139.1149.1155.
ReferenceFranco and Shibamoto, 2000Franco and Shibamoto, 2000Kim, Kim, et al., 2000Korány, Mednyánszky, et al., 2000Mallavarapu, Rao, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxDB-WaxCW 20MCW 20M
Column length (m) 60.60.60.25.25.
Carrier gas HeliumNitrogenHeHydrogenHydrogen
Substrate      
Column diameter (mm) 0.320.250.250.320.32
Phase thickness (μm) 0.25 0.250.250.25
Tstart (C) 50.40.40.50.50.
Tend (C) 230.200.200.220.220.
Heat rate (K/min) 5.2.2.3.3.
Initial hold (min) 2.10.2.1.1.
Final hold (min)    10.10.
I 1164.1173.1161.1157.1159.
ReferencePaniandy, Chane-Ming, et al., 2000Tamura, Boonbumrung, et al., 2000Umano, Hagi, et al., 2000Bicchi, Binello, et al., 1999Bicchi, Binello, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CW 20MCW 20MCW 20MSupelcowax-10BP-20
Column length (m) 25.25.25.30.25.
Carrier gas HydrogenHydrogenHydrogen  
Substrate      
Column diameter (mm) 0.320.320.320.250.33
Phase thickness (μm) 0.250.250.250.250.5
Tstart (C) 50.50.50.60.80.
Tend (C) 220.220.220.220.220.
Heat rate (K/min) 3.3.3.4.5.
Initial hold (min) 1.1.1.  
Final hold (min) 10.10.10.  
I 1159.1159.1159.1165.1175.
ReferenceBicchi, Binello, et al., 1999Bicchi, Binello, et al., 1999Bicchi, Binello, et al., 1999Choo, Wong, et al., 1999Dunlop, Bignell, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxHP-InnowaxHP-InnowaxSupelcowax-10DB-Wax
Column length (m) 60.60.60.30.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.25 0.25
Tstart (C) 60.60.60.60.60.
Tend (C) 220.220.220.240.240.
Heat rate (K/min)    4.4.
Initial hold (min) 10.10.10.  
Final hold (min)      
I 1174.1174.1174.1161.1160.
ReferenceKaya, Baser, et al., 1999Kaya, Baser, et al., 1999, 2Kaya, Baser, et al., 1999, 2Labuckas, Zygadlo, et al., 1999Ngassoum, Yonkeu, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase NB-351HP-20MBP-20BP-20CP-Wax 52CB
Column length (m) 25.25.25.25.25.
Carrier gas H2HeliumN2H2He
Substrate      
Column diameter (mm) 0.30.200.50.330.32
Phase thickness (μm) 0.50.25 0.50.2
Tstart (C) 70.60.60.80.60.
Tend (C) 250.200.200.220.240.
Heat rate (K/min) 5.3.5.5.6.
Initial hold (min) 2.4.  2.
Final hold (min)     10.
I 1182.1156.1155.1175.1161.
ReferenceOnocha, Ekundayo, et al., 1999Prikhod'ko, Klyuev, et al., 1999Rao, Bhattacharya, et al., 1999Bignell, Dunlop, et al., 1998Chisowa, Hall, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-20MDB-WaxDB-WaxHP-InnowaxHP-Innowax FSC
Column length (m) 50.30.30.60.60.
Carrier gas HeN2N2HeHe
Substrate      
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (μm) 0.20.250.250.250.25
Tstart (C) 70.45.45.50.60.
Tend (C) 180.220.220.220.220.
Heat rate (K/min) 4.3.3.5.4.
Initial hold (min) 4.  5.10.
Final hold (min) 10.   10.
I 1148.1150.1166.1160.1174.
ReferenceMilso, Mastelic, et al., 1998Molleken U., Sinnwell V., et al., 1998Mölleken, Sinnwell, et al., 1998Stashenko, Cervantes, et al., 1998Tümen, Baser, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase PEG-20MHP-Innowax FSCBP-20BP-20BP-20
Column length (m) 60.60.25.25.25.
Carrier gas  HeH2H2H2
Substrate      
Column diameter (mm) 0.250.250.330.330.33
Phase thickness (μm)   0.50.50.5
Tstart (C) 70.60.80.80.80.
Tend (C) 220.240.220.220.220.
Heat rate (K/min) 3.4.5.5.5.
Initial hold (min)  10.   
Final hold (min)  10.   
I 1168.1174.1175.1175.1175.
ReferenceAwano, Ichikawa, et al., 1997Baser, Kirimer, et al., 1997Bignell, Dunlop, et al., 1997Bignell, Dunlop, et al., 1997, 2Bignell, Dunlop, et al., 1997, 3
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20BP-20BP-20Supelcowax-10SP-1000
Column length (m) 25.25.25.0.85.
Carrier gas H2 H2HeHe
Substrate      
Column diameter (mm) 0.330.330.330.250.50
Phase thickness (μm) 0.50.50.5  
Tstart (C) 80.80.80.40.65.
Tend (C) 220.220.220.240.225.
Heat rate (K/min) 5.5.5.3.3.
Initial hold (min)      
Final hold (min)      
I 1175.1175.1175.1161.1150.
ReferenceBignell, Dunlop, et al., 1997, 4Bignell, Dunlop, et al., 1997, 5Bignell, Dunlop, et al., 1997, 6Zygadlo, Ariza-Espinar, et al., 1997Brophy, Goldsack, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxPEG-20MDB-WaxDB-WaxDB-Wax
Column length (m) 30.50.30.60.60.
Carrier gas N2HeHeHeHe
Substrate      
Column diameter (mm) 0.3190.250.320.320.25
Phase thickness (μm) 0.25 0.50.500.25
Tstart (C) 60.70.40.50.50.
Tend (C) 300.250.210.250.180.
Heat rate (K/min) 8.2.3.8.2.5
Initial hold (min)   1.1.5.
Final hold (min) 15. 25.6. 
I 1161.1158.1163.1167.1164.
ReferenceMalizia, Molli, et al., 1996Orav, Kailas, et al., 1996Pollak and Berger, 1996Sagrero-Nieves and Bartley, 1996Stashenko, Puertas, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10PEG-20MDB-WaxCarbowax 20MDB-Wax
Column length (m) 60.60.60.60.60.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.320.250.250.32
Phase thickness (μm) 0.250.250.250.250.5
Tstart (C) 40.70.50.50.50.
Tend (C) 200.180.180.150.225.
Heat rate (K/min) 3.2.2.52.2.
Initial hold (min) 3.7.5.10. 
Final hold (min) 30.  20. 
I 1161.1167.1166.1162.1171.
ReferenceWong and Lai, 1996Orav, Kuningas, et al., 1995Stashenko, Torres, et al., 1995Tirado, Stashenko, et al., 1995Sagrero-Nieves, Bartley, et al., 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxCarbowax 20MCarbowax 20MDB-WaxSupelcowax-10
Column length (m) 60.45.50.60.60.
Carrier gas HeHydrogenHe He
Substrate      
Column diameter (mm) 0.250.320.250.320.32
Phase thickness (μm) 0.251.0   
Tstart (C) 50.60.60.50.60.
Tend (C) 230.200.180.230.220.
Heat rate (K/min) 2.2.2.4.2.
Initial hold (min) 4.5.4. 1.
Final hold (min)    10. 
I 1160.1169.1149.1160.1176.
ReferenceShimoda, Shiratsuchi, et al., 1993Kollmannsberger, Nitz, et al., 1992Kawakami and Kobayashi, 1991Binder, Turner, et al., 1990Loughrin, Hamilton-Kemp, et al., 1990
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxFFAPDB-WaxDB-Wax
Column length (m) 30.60.50.60.60.
Carrier gas    HeHe
Substrate      
Column diameter (mm) 0.320.32 0.320.32
Phase thickness (μm)    0.250.25
Tstart (C) 70.50.50.30.30.
Tend (C) 200.250.180.180.180.
Heat rate (K/min) 4.4.10.2.2.
Initial hold (min) 2.0.11.4.4.
Final hold (min)  5.   
I 1174.1157.1172.1160.1160.
ReferenceWyllie, Brophy, et al., 1990Binder and Flath, 1989Brophy, Davies, et al., 1989Takeoka and Butter, 1989Takeoka and Butter, 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MCarbowax 20MCarbowax 20MCarbowax 20MDB-Wax
Column length (m) 150.50.150.25.30.
Carrier gas   He H2
Substrate      
Column diameter (mm) 0.660.250.660.300.25
Phase thickness (μm)     0.25
Tstart (C) 60.80.60.40.50.
Tend (C) 170.200.170.220.250.
Heat rate (K/min) 1.2.1.2.5.
Initial hold (min) 40. 40.5. 
Final hold (min)      
I 1145.1174.1160.1166.1146.
ReferenceButtery, Ling, et al., 1987Shibamoto, 1987Buttery, Maddox, et al., 1986Nykanen, 1986Perry, Baxter, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20Carbowax 20MCarbowax 20MCarbowax 20MCarbowax 20M
Column length (m) 25.150.50.150.150.
Carrier gas      
Substrate      
Column diameter (mm) 0.20.660.320.640.64
Phase thickness (μm)      
Tstart (C) 70.60.70.50.50.
Tend (C) 180.170.180.170.170.
Heat rate (K/min) 3.1.2.1.1.
Initial hold (min) 5.40. 30.30.
Final hold (min)      
I 1173.1160.1159.1160.1150.
ReferenceMacLeod and Snyder, 1985Buttery and Ling, 1984Engel and Tressl, 1983Buttery, Parker, et al., 1981Buttery and Kamm, 1980
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryPacked
Active phase Carbowax 20MCarbowax 20MCarbowax 20MCarbowax 20MCarbowax 20M
Column length (m) 50.50.100.100.2.
Carrier gas N2N2  Hydrogen
Substrate     Gas-Chrom Z (80-100 mesh)
Column diameter (mm) 0.280.280.250.25 
Phase thickness (μm)      
Tstart (C) 80.80.70.70.65.
Tend (C) 170.170.170.170.220.
Heat rate (K/min) 1.1.1.1.4.
Initial hold (min)      
Final hold (min)      
I 1137.1137.1170.1171.1154.
ReferenceYamaguchi and Shibamoto, 1980Yamaguchi and Shibamoto, 1980Shibamoto and Jennings, 1977Shibamoto and Jennings, 1977Stancher and Pertoldi, 1967
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Carbowax 20MCarbowax 20MCarbowax 20MCarbowax 20MCarbowax 20M
Column length (m) 2.2.2.2.2.
Carrier gas HydrogenHydrogenHydrogenHydrogenHydrogen
Substrate Gas-Chrom Z (80-100 mesh)Gas-Chrom Z (80-100 mesh)Gas-Chrom Z (80-100 mesh)Gas-Chrom Z (80-100 mesh)Gas-Chrom Z (80-100 mesh)
Column diameter (mm)      
Phase thickness (μm)      
Tstart (C) 65.65.65.65.65.
Tend (C) 220.220.220.220.220.
Heat rate (K/min) 4.4.4.4.4.
Initial hold (min)      
Final hold (min)      
I 1154.1154.1155.1156.1158.
ReferenceStancher and Pertoldi, 1967Stancher and Pertoldi, 1967Stancher and Pertoldi, 1967Stancher and Pertoldi, 1967Stancher and Pertoldi, 1967
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

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