Hydroquinone

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-277.0 ± 1.4kJ/molCcrSabbah and Buluku, 1991ΔHfusion =21.09±0.4 kJ/mol; ALS
Δfgas-272.0kJ/molN/APilcher and Sutton, 1956Value computed using ΔfHsolid° value of -366.1±1.2 kj/mol from Pilcher and Sutton, 1956 and ΔsubH° value of 94.1 kj/mol from Sabbah and Buluku, 1991.; DRB
Δfgas-268.9kJ/molN/AParks, Manchester, et al., 1954Value computed using ΔfHsolid° value of -363.0±1.0 kj/mol from Parks, Manchester, et al., 1954 and ΔsubH° value of 94.1 kj/mol from Sabbah and Buluku, 1991.; DRB
Δfgas-266.9kJ/molN/APushin, 1954Value computed using ΔfHsolid° value of -361.0 kj/mol from Pushin, 1954 and ΔsubH° value of 94.1 kj/mol from Sabbah and Buluku, 1991.; DRB
Δfgas-268.4kJ/molN/ASchreiner, 1925Value computed using ΔfHsolid° value of -362.5 kj/mol from Schreiner, 1925 and ΔsubH° value of 94.1 kj/mol from Sabbah and Buluku, 1991.; DRB
Quantity Value Units Method Reference Comment
gas343.1 ± 5.0J/mol*KN/AKudchadker S.A., 1979GT

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
34.5250.Kudchadker S.A., 1979GT
47.69100.
66.48150.
86.13200.
114.40273.15
123.60298.15
124.27300.
157.14400.
183.26500.
203.62600.
219.74700.
232.82800.
243.67900.
252.831000.
260.641100.
267.361200.
273.171300.
278.221400.
282.611500.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sabbah and Buluku, 1991
Sabbah, R.; Buluku, E.N.L.E., Thermodynamic study of three isomers of dihydroxybenzene, Can. J. Chem., 1991, 69, 481-488. [all data]

Pilcher and Sutton, 1956
Pilcher, G.; Sutton, L.E., The heats of combustion of quinol and p-benzoquinone and the thermodynamic quantities of the oxidation-reduction reaction, J. Chem. Soc., 1956, 2695-2700. [all data]

Parks, Manchester, et al., 1954
Parks, G.S.; Manchester, K.E.; Vaughan, L.M., Heats of combustion and formation of some alcohols, phenols, and ketones, J. Chem. Phys., 1954, 22, 2089-2090. [all data]

Pushin, 1954
Pushin, N.A., Heats of combustion and heats of formation of isomeric organic compounds, Bull. Soc. Chim. Belgrade, 1954, 19, 531-547. [all data]

Schreiner, 1925
Schreiner, E., Thermodynamics of the quinhydrone electrode and the chemical constant of hydrogen, Z. Phys. Chem., 1925, 117, 57-87. [all data]

Kudchadker S.A., 1979
Kudchadker S.A., Ideal gas thermodynamic properties of benzene diols: pyrocatechol, resorcinol, and hydroquinone, Thermochim. Acta, 1979, 30, 319-326. [all data]


Notes

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