Hydroquinone

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-88.70 ± 0.31kcal/molCcrSabbah and Buluku, 1991ΔHfusion =21.09±0.4 kJ/mol; ALS
Δfsolid-87.51 ± 0.28kcal/molCcbPilcher and Sutton, 1956ALS
Δfsolid-86.75 ± 0.25kcal/molCcbParks, Manchester, et al., 1954ALS
Δfsolid-86.2kcal/molCcbPushin, 1954Author's hf298_condensed=-87.8 kcal/mol; ALS
Δfsolid-86.65kcal/molCcbSchreiner, 1925ALS
Quantity Value Units Method Reference Comment
Δcsolid-682. ± 5.kcal/molAVGN/AAverage of 8 values; Individual data points

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
31.525298.15Bret-Dibat and Lichanot, 1989T = 200 to 500 K. Cp(c) = 125.328 + 0.2791t - 1.0329x10-3t2 + 1.5075x10-5t3 J/mol*K (t/°C). Cp value caluculated from equation.; DH
32.60298.15Ueberreiter and Orthmann, 1950T = 293 to 368 K. Equation only.; DH
35.90323.Satoh and Sogabe, 1941T = 0 to 100°C. Mean value.; DH
33.39298.Andrews, Lynn, et al., 1926T = 22 to 200°C.; DH
31.91297.9Andrews, 1926T = 110 to 344 K. Value is unsmoothed experimental datum.; DH
31.19274.3Lange, 1924T = 28 to 275 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sabbah and Buluku, 1991
Sabbah, R.; Buluku, E.N.L.E., Thermodynamic study of three isomers of dihydroxybenzene, Can. J. Chem., 1991, 69, 481-488. [all data]

Pilcher and Sutton, 1956
Pilcher, G.; Sutton, L.E., The heats of combustion of quinol and p-benzoquinone and the thermodynamic quantities of the oxidation-reduction reaction, J. Chem. Soc., 1956, 2695-2700. [all data]

Parks, Manchester, et al., 1954
Parks, G.S.; Manchester, K.E.; Vaughan, L.M., Heats of combustion and formation of some alcohols, phenols, and ketones, J. Chem. Phys., 1954, 22, 2089-2090. [all data]

Pushin, 1954
Pushin, N.A., Heats of combustion and heats of formation of isomeric organic compounds, Bull. Soc. Chim. Belgrade, 1954, 19, 531-547. [all data]

Schreiner, 1925
Schreiner, E., Thermodynamics of the quinhydrone electrode and the chemical constant of hydrogen, Z. Phys. Chem., 1925, 117, 57-87. [all data]

Bret-Dibat and Lichanot, 1989
Bret-Dibat, P.; Lichanot, A., Thermodynamic properties of positional isomers of disubstituted benzene in condensed phase, Thermochim. Acta, 1989, 147(2), 261-271. [all data]

Ueberreiter and Orthmann, 1950
Ueberreiter, K.; Orthmann, H.-J., Specifische Wärme, spezifisches Volumen, Temperatur- und Wärme-leittähigkeit einiger disubstituierter Benzole und polycyclischer Systeme, Z. Natursforsch. 5a, 1950, 101-108. [all data]

Satoh and Sogabe, 1941
Satoh, S.; Sogabe, T., The heat capacities of some organic compounds containing nitrogen and the atomic heat of nitrogen. (3), Sci., Pap. Inst. Phys. Chem. Res. (Tokyo), 1941, 38, 238-245. [all data]

Andrews, Lynn, et al., 1926
Andrews, D.H.; Lynn, G.; Johnston, J., The heat capacities and heat of crystallization of some isomeric aromatic compounds, J. Am. Chem. Soc., 1926, 48, 1274-1287. [all data]

Andrews, 1926
Andrews, D.H., The specific heats of some isomers of the type ortho, meta and para C6H4XY from 110 to 340K, J. Am. Chem. Soc., 1926, 48, 1287-1298. [all data]

Lange, 1924
Lange, F., Untersuchungen über die spezifische Wärme bei tiefen Temperaturen, Z. Phys. Chem., 1924, 110, 343-362. [all data]


Notes

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