Holmium monoxide


Constants of diatomic molecules

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through February, 1975

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for 165Ho16O
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
R shaded emission bands from 21700 to 23000 cm-1.
Mavrodineanu and Boiteux, 1965
            (18795)
missing citation; missing citation
            (17881)
missing citation; missing citation

Notes

1Thermochemical value (mass-spectrom. Ames, Walsh, et al., 1967), recalculated Smoes, Coppens, et al., 1969.

References

Go To: Top, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mavrodineanu and Boiteux, 1965
Mavrodineanu, R.; Boiteux, H., Flame Spectroscopy, John Wiley & Sons, Inc., New York, 1965, 721. [all data]

Ames, Walsh, et al., 1967
Ames, L.L.; Walsh, P.N.; White, D., Rare earths. IV. Dissocaition energies of the gaseous monoxides of the rare earths, J. Phys. Chem., 1967, 71, 2707. [all data]

Smoes, Coppens, et al., 1969
Smoes, S.; Coppens, P.; Bergman, C.; Drowart, J., Mass spectrometric determination of the dissociation energies of the gaseous rare earth monosulphides, Trans. Faraday Soc., 1969, 65, 682. [all data]


Notes

Go To: Top, Constants of diatomic molecules, References