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Acetic acid, phenyl ester

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C8H8O2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference
8.6 ± 0.05PEBouchoux, 1978
8.8 ± 0.2EIGamble, Gilbert, et al., 1971
8.75 ± 0.03EIBenezra and Bursey, 1971

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H3O+12.8 ± 0.2cyclo-C6H5EIGamble, Gilbert, et al., 1971 
C2H3O+12.83 ± 0.03C6H5OEIBenezra and Bursey, 1971 
C6H6O+9.9 ± 0.2CH2=C=OEIGamble, Gilbert, et al., 1971 
C6H6O+9.57 ± 0.03CH2=C=OEIBenezra and Bursey, 1971 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bouchoux, 1978
Bouchoux, G., Ionisation et fragmentation en spectrometrie de masse VIII. Energies d'activation de deux fragmentations competitives, dissociation de l'acetate de phenyle et de l'acetanilide sous impact electronique, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 379. [all data]

Gamble, Gilbert, et al., 1971
Gamble, A.A.; Gilbert, J.R.; Tillett, J.G., Substituent effects on the mass spectra of substituted phenyl acetates, Org. Mass Spectrom., 1971, 5, 1093. [all data]

Benezra and Bursey, 1971
Benezra, S.A.; Bursey, M.M., ortho-Effects on ordering factors in mass spectral rearrangements. Loss of keten from halogenated phenyl acetates and acetanilides, J. Chem. Soc. B, 1971, 1515. [all data]


Notes

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