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Nitrogen oxide cation


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 58243 ± 17 gas Brundle and Turner, 1969
Berkowitz and Eland, 1977
Dehmer, Dehmer, et al., 1980
Chen, Liu, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 Sym. stretch 1251 ± 10 gas PE Brundle and Turner, 1969
Dehmer, Dehmer, et al., 1980
Chiang and -I Ma, 2000
Chen, Liu, et al., 2003
Pi 2 Bend 482 ± 10 gas PE Dehmer, Dehmer, et al., 1980
Chen, Liu, et al., 2003
Sigma+ 3 Asym. stretch 2300 ± 10 gas PE Brundle and Turner, 1969
Dehmer, Dehmer, et al., 1980
Chiang and -I Ma, 2000
Chen, Liu, et al., 2003

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 38440 ± 100 gas Brundle and Turner, 1969
Chen, Liu, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 Sym. stretch 960 gas PE Brundle and Turner, 1969
Cvitas, Klasinc, et al., 1983
Pi 2 Bend 368 gas PE Cvitas, Klasinc, et al., 1983

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

gas B-A 538 866 Danis, Wyttenbach, et al., 1988

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 28162.33 gas A-X 317 421 Callomon and Creutzberg, 1974
Larzilliere, Carre, et al., 1980
Frey, Kakoschke, et al., 1982
Abed, Broyer, et al., 1983
Aarts and Callomon, 1987
Larzilliere, 1989
el Idrissi, Larzilliere, et al., 1994
Chen, Liu, et al., 2003
Xu, Guo, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 Sym. stretch 1345.38 gas EM PF Callomon and Creutzberg, 1974
Frey, Kakoschke, et al., 1982
Fellows and Vervloet, 2001
1 Sym. stretch 1345.38 gas PE Chen, Liu, et al., 2003
Pi 2 Bend 614.45 gas EM PE Callomon and Creutzberg, 1974
Aarts and Callomon, 1987
Chen, Liu, et al., 2003
Sigma+ 3 Asym. stretch 2451.7 gas EM PE Callomon and Creutzberg, 1974

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 Sym. stretch 1126.28 gas EM Callomon and Creutzberg, 1974
Fellows and Vervloet, 2001
1 Sym. stretch 1135.5 Ne IR Jacox, 1990
Pi 2 Bend 452.42 gas EM PF Callomon and Creutzberg, 1974
Abed, Broyer, et al., 1983
Aarts and Callomon, 1987
Sigma+ 3 Asym. stretch 1737.37 gas EM Callomon and Creutzberg, 1974
Fellows and Vervloet, 2001
3 Asym. stretch 1741.4 w m Ne IR Jacox, 1990

Additional references: Jacox, 1994, page 83; Jacox, 1998, page 187; Jacox, 2003, page 127; Smith, 1969; Eland, Devoret, et al., 1976; Maier and Thommen, 1980; Dunbar and Turner, 1981; Klapstein and Maier, 1981; Ibuki and Sugita, 1984; Kindvall, Larsson, et al., 1986; Kong, Rodgers, et al., 1994

Notes

wWeak
mMedium
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brundle and Turner, 1969
Brundle, C.R.; Turner, D.W., Studies on the photoionisation of the linear triatomic molecules: N2O, COS, CS2 and CO2 using high-resolution photoelectron spectroscopy, Intern. J. Mass Spectrom. Ion Phys., 1969, 2, 195. [all data]

Berkowitz and Eland, 1977
Berkowitz, J.; Eland, J.H.D., Photoionization of N2O: Mechanisms of photoionization and ion dissociation, J. Chem. Phys., 1977, 67, 2740. [all data]

Dehmer, Dehmer, et al., 1980
Dehmer, P.M.; Dehmer, J.L.; Chupka, W.A., Effects of vibronic interaction and autoionization on the photoelectron spectrum of N2O, J. Chem. Phys., 1980, 73, 1, 126, https://doi.org/10.1063/1.439906 . [all data]

Chen, Liu, et al., 2003
Chen, W.; Liu, J.; Ng, C.Y., Vacuum Ultraviolet Pulsed Field Ionization-Photoelectron Study for N, J. Phys. Chem. A, 2003, 107, 40, 8086, https://doi.org/10.1021/jp022389d . [all data]

Chiang and -I Ma, 2000
Chiang, S.-Y.; -I Ma, C., Fragmentation of Vibrationally Selected N, J. Phys. Chem. A, 2000, 104, 10, 1991, https://doi.org/10.1021/jp9935081 . [all data]

Cvitas, Klasinc, et al., 1983
Cvitas, T.; Klasinc, L.; Kovac, B.; McDiarmid, R., The high-resolution photoelectron spectrum of N2O. The B(2«PI»i) state, J. Chem. Phys., 1983, 79, 4, 1565, https://doi.org/10.1063/1.446028 . [all data]

Danis, Wyttenbach, et al., 1988
Danis, P.O.; Wyttenbach, T.; Maier, J.P., Two-photon absorption spectroscopy of mass-selected ions: N2O+ and CS+2, J. Chem. Phys., 1988, 88, 6, 3451, https://doi.org/10.1063/1.453893 . [all data]

Callomon and Creutzberg, 1974
Callomon, J.H.; Creutzberg, F., The Electronic Emission Spectrum of Ionized Nitrous Oxide, FormulaOFormula, Phil. Trans. Roy. Soc. (London) A277, 1974, 277, 1266, 157, https://doi.org/10.1098/rsta.1974.0048 . [all data]

Larzilliere, Carre, et al., 1980
Larzilliere, M.; Carre, M.; Gaillard, M.L.; Rostas, J.; Horani, M.; Velghe, M., J. Chim. Phys., 1980, 77, 689. [all data]

Frey, Kakoschke, et al., 1982
Frey, R.; Kakoschke, R.; Schlag, E.W., Spectroscopy of molecular ions: Laser-induced fragmentation spectra of N2O+, A 2«SIGMA»+-X2«PI», Chem. Phys. Lett., 1982, 93, 3, 227, https://doi.org/10.1016/0009-2614(82)80128-0 . [all data]

Abed, Broyer, et al., 1983
Abed, S.; Broyer, M.; Carre, M.; Gaillard, M.L.; Larzilliere, M., High-resolution spectroscopy of N2O+ in the near ultraviolet using fiblas (fast-ion-beam laser spectroscopy), Chem. Phys., 1983, 74, 1, 97, https://doi.org/10.1016/0301-0104(83)80012-3 . [all data]

Aarts and Callomon, 1987
Aarts, J.F.M.; Callomon, J.H., Analysis of the v´´, Mol. Phys., 1987, 62, 3, 637, https://doi.org/10.1080/00268978700102451 . [all data]

Larzilliere, 1989
Larzilliere, M., and Ch. Jungen, 1989, Mol. Phys. 67, 807. [all data]

el Idrissi, Larzilliere, et al., 1994
el Idrissi, M.C.; Larzilliere, M.; Carre, M., Fast ion beam laser spectroscopy of N2O+: Observation and interpretation of the Fermi resonance in the 100 2«PI» vibronic level of the ground state, J. Chem. Phys., 1994, 100, 1, 204, https://doi.org/10.1063/1.467269 . [all data]

Xu, Guo, et al., 2003
Xu, H.; Guo, Y.; Li, Q.; Liu, S.; Ma, X.; Liang, J.; Li, H., Spectroscopic study of N[sub 2]O[sup +](A [sup 2]«SIGMA»[sup +]) by photofragment excitation spectrum, J. Chem. Phys., 2003, 119, 22, 11609, https://doi.org/10.1063/1.1624596 . [all data]

Fellows and Vervloet, 2001
Fellows, C.E.; Vervloet, M., Fourier transform emission spectra of the electronic transition A of N2O+, Chem. Phys., 2001, 264, 2, 203, https://doi.org/10.1016/S0301-0104(00)00401-8 . [all data]

Jacox, 1990
Jacox, M.E., The vibrational spectra of molecular ions isolated in solid neon. V. N2O+ and NNO-2, J. Chem. Phys., 1990, 93, 11, 7622, https://doi.org/10.1063/1.459393 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Smith, 1969
Smith, W.H., Radiative Lifetimes and Total Transition Probabilities for Some Polyatomic Species, J. Chem. Phys., 1969, 51, 8, 3410, https://doi.org/10.1063/1.1672528 . [all data]

Eland, Devoret, et al., 1976
Eland, J.H.D.; Devoret, M.; Leach, S., Quantum yields and lifetimes of molecular ion fluorescence, Chem. Phys. Lett., 1976, 43, 1, 97, https://doi.org/10.1016/0009-2614(76)80765-8 . [all data]

Maier and Thommen, 1980
Maier, J.P.; Thommen, F., Fluorescence quantum yields and cascade-free lifetimes of state selected CO+2, COS+, CS+2 and N2O+ determined by photoelectron---photon coincidence spectroscopy, Chem. Phys., 1980, 51, 3, 319, https://doi.org/10.1016/0301-0104(80)80106-6 . [all data]

Dunbar and Turner, 1981
Dunbar, R.C.; Turner, D.W., Wavelength-resolved fluorescence lifetimes of gas-phase ions: CO2+ and CS2+, Chem. Phys., 1981, 57, 3, 377, https://doi.org/10.1016/0301-0104(81)80216-9 . [all data]

Klapstein and Maier, 1981
Klapstein, D.; Maier, J.P., Lifetimes of N2O+(Ã2«SIGMA»+) and COS+(Ã2«PI») in selected vibronic levels, Chem. Phys. Lett., 1981, 83, 3, 590, https://doi.org/10.1016/0009-2614(81)85529-7 . [all data]

Ibuki and Sugita, 1984
Ibuki, T.; Sugita, N., Lifetimes of N2O+(A), CS+2(A), and CS+2(B) states produced by pulsed EUV photons, J. Chem. Phys., 1984, 80, 10, 4625, https://doi.org/10.1063/1.446547 . [all data]

Kindvall, Larsson, et al., 1986
Kindvall, G.; Larsson, M.; Olsson, B.; Sigray, P., Fluorescence Lifetimes of N, Phys. Scripta, 1986, 33, 5, 412, https://doi.org/10.1088/0031-8949/33/5/005 . [all data]

Kong, Rodgers, et al., 1994
Kong, W.; Rodgers, D.; Hepburn, J.W., Pulsed field ionization threshold photelectron spectroscopy of the fluorescing N2O+ (A 2«SIGMA»+) state, Chem. Phys. Lett., 1994, 221, 3-4, 301, https://doi.org/10.1016/0009-2614(94)00260-6 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References