Lithium fluoride
- Formula: F2Li2
- Molecular weight: 51.879
- CAS Registry Number: 12265-82-6
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -942.78 | kJ/mol | Review | Chase, 1998 | Data last reviewed in December, 1968 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 258.52 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1968 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. - 6000. |
|---|---|
| A | 80.14410 |
| B | 2.547382 |
| C | -0.688335 |
| D | 0.058638 |
| E | -1.617435 |
| F | -972.2068 |
| G | 345.6821 |
| H | -942.7807 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in December, 1968 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Li2F+ | 11.91 | F | EI | Veljkovic, Neskovic, et al., 1993 | LL |
| Li2F+ | 11.5 | F | EI | Berkowitz, Tasman, et al., 1962 | RDSH |
| LiF2+ | 13.88 | Li | EI | Veljkovic, Neskovic, et al., 1993 | LL |
| Li+ | 13.75 | LiF+F | EI | Veljkovic, Neskovic, et al., 1993 | LL |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Veljkovic, Neskovic, et al., 1993
Veljkovic, M.V.; Neskovic, O.M.; Miletic, M.B.; Zmbov, K.F.,
Mass spectrometric study of ionization and fragmentation of lithium fluoride vapor by electron impact,
J. Serb. Chem. Soc., 1993, 58, 101. [all data]
Berkowitz, Tasman, et al., 1962
Berkowitz, J.; Tasman, H.A.; Chupka, W.A.,
Double-oven experiments with lithium halide vapors,
J. Chem. Phys., 1962, 36, 2170. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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