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Iron, tricarbonyliodo(«eta»3-2-propenyl)-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-337. ± 10.kJ/molReviewMartinho Simões 
Deltafgas-344. ± 11.kJ/molHAL-HFCConnor, Demain, et al., 1979Value corrected based on a set of ancillary data by J.A. Martinho Simões; Selected data. The enthalpy of formation is a recommended Connor, Demain, et al., 1979 weighed average from thermal decomposition and iodination results

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-421.5 ± 9.3kJ/molReviewMartinho Simões 
Deltafsolid-428. ± 10.kJ/molHAL-HFCConnor, Demain, et al., 1979Value corrected based on a set of ancillary data by J.A. Martinho Simões; Selected data. The enthalpy of formation is a recommended Connor, Demain, et al., 1979 weighed average from thermal decomposition and iodination results

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub84.5 ± 4.0kJ/molN/APilcher and Skinner, 1983See also Connor, Demain, et al., 1979, 2.; AC
Deltasub84.5 ± 4.0kJ/molTD-HFCConnor, Demain, et al., 1979MS

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
8.2PELouwen, Hart, et al., 1982LBLHLM
8.36PELouwen, Hart, et al., 1982Vertical value; LBLHLM

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Connor, Demain, et al., 1979
Connor, J.A.; Demain, C.P.; Skinner, H.A.; Zafarani-Moattar, M.T., J. Orgnometal. Chem., 1979, 170, 117. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Connor, Demain, et al., 1979, 2
Connor, Joseph A.; Demain, Christopher P.; Skinner, Henry A.; Zafarani-Moattar, Mohammad T., Thermochemistry of «eta»3-Allyltricarbonyliodoiron, Tricarbonyl («eta»4-cyclooctatetraene)iron and Tetracarbonyldiiodoiron. The Enthalpy Contributions of Allyliron and Cyclooctatetraene-iron Bonds, Journal of Organometallic Chemistry, 1979, 170, 1, 117-130, https://doi.org/10.1016/S0022-328X(00)83195-2 . [all data]

Louwen, Hart, et al., 1982
Louwen, J.N.; Hart, J.; Stufkens, D.J.; Oskam, A., The HeI and HeII photoelectron spectra of [Fe «eta»3-C3H5(CO)3X] and [Fe «eta»3-C4H7(CO)3X] (X = Cl, Br, I) and [CoC3H5(CO)3], Z. Naturforsch. B:, 1982, 37, 179. [all data]


Notes

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