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Bismuth dimer


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.22 ± 0.10LPESSun, Sun, et al., 2009B
1.2710 ± 0.0080LPESPolak, Ho, et al., 1991B
1.20 ± 0.10LPESSobhy, Reveles, et al., 2009B

Ionization energy determinations

IE (eV) Method Reference Comment
<=7.34PIYoo, Ruscic, et al., 1993LL
7.6 ± 0.5EIWagner and Grimley, 1974LLK
7.3 ± 0.5EIGingerich, Cocke, et al., 1974LLK
7.2 ± 0.5EIUy and Drowart, 1969RDSH
7.1 ± 0.3EIKohl, Uy, et al., 1967RDSH
7.4 ± 0.1EIKohl, Uy, et al., 1967RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Bi+9.6 ± 0.5?EIWagner and Grimley, 1974LLK
Bi+9.7 ± 0.1BiEIKohl, Uy, et al., 1967RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sun, Sun, et al., 2009
Sun, Z.; Sun, S.T.; Liu, H.T.; Zhu, Q.H.; Gao, Z.; Tang, Z.C., Photoelectron Spectroscopic and Theoretical Studies of MmC6F5 Anionic Complexes (M = Ph and Bi; m=1-4), J. Phys. Chem. A, 2009, 113, 28, 8045-8054, https://doi.org/10.1021/jp8099626 . [all data]

Polak, Ho, et al., 1991
Polak, M.L.; Ho, J.; Gerber, G.; Lineberger, W.C., Photoelectron Spectroscopy of Negatively Charged Bismuth Clusters: Bi2-, Bi3-, and Bi4-, J. Chem. Phys., 1991, 95, 5, 3053, https://doi.org/10.1063/1.460862 . [all data]

Sobhy, Reveles, et al., 2009
Sobhy, M.A.; Reveles, J.U.; Gupta, U.; Khanna, S.N.; Castleman, A.W., Photoelectron imaging and theoretical investigation of bimetallic Bi1-2Ga0-2- and Pb-1-4(-) cluster anions, J. Chem. Phys., 2009, 130, 5, 054304, https://doi.org/10.1063/1.3069295 . [all data]

Yoo, Ruscic, et al., 1993
Yoo, R.K.; Ruscic, B.; Berkowitz, J., Photoionization mass spectrometric studies of Sb2 and Bi2, J. Chem. Phys., 1993, 99, 8445. [all data]

Wagner and Grimley, 1974
Wagner, L.C.; Grimley, R.T., A mass spectrometric study of the bismuth vapor system by the angular distribution technique, Chem. Phys. Lett., 1974, 29, 594. [all data]

Gingerich, Cocke, et al., 1974
Gingerich, K.A.; Cocke, D.L.; Kordis, J., Gaseous phosphorus compounds. X. Mass spectrometric determination of the dissociation energies of arsenic and bismuth monophosphides, J. Phys. Chem., 1974, 78, 603. [all data]

Uy and Drowart, 1969
Uy, O.M.; Drowart, J., Mass spectrometric determination of the dissociation energies of the molecules BiO, BiS, BiSe and BiTe, J. Chem. Soc. Faraday Trans., 1969, 65, 3221. [all data]

Kohl, Uy, et al., 1967
Kohl, F.J.; Uy, O.M.; Carlson, K.D., Cross sections for electron-impact fragmentation and dissociation energies of the dimer and tetramer of bismuth, J. Chem. Phys., 1967, 47, 2667. [all data]


Notes

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