Arsenic tetramer


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.3 ± 0.3EIHirayama, Straw, et al., 1985LBLHLM
10.1 ± 0.4EIDeMaria, Malaspina, et al., 1970RDSH
9.07 ± 0.07EIWestmore, Mann, et al., 1964RDSH
9.9 ± 0.2EIGutbier, 1961RDSH
8.92PEEbel, Dieck, et al., 1981Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
As3+12.0 ± 0.6AsEIHirayama, Straw, et al., 1985LBLHLM
As3+13.5 ± 0.4AsEIDeMaria, Malaspina, et al., 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hirayama, Straw, et al., 1985
Hirayama, C.; Straw, R.D.; Hobgood, H.M., Equilibria over gas in the Knudsen cell range, J. Less-Common Met., 1985, 109, 331. [all data]

DeMaria, Malaspina, et al., 1970
DeMaria, G.; Malaspina, L.; Piacente, V., Mass spectrometric study of the GaAs system, J. Chem. Phys., 1970, 52, 1019. [all data]

Westmore, Mann, et al., 1964
Westmore, J.B.; Mann, K.H.; Tickner, A.W., Mass spectrometric study of the nonstoichiometric vaporization of cadmium arsenide, J. Phys. Chem., 1964, 68, 606. [all data]

Gutbier, 1961
Gutbier, H., Massenspektrometrische Untersuchungen der Verdampfungsvorgange bei einigen Verbindungen mit Zinkblende-Gitter im Temperaturbereich um 1000 degree K, Z. Naturforsch. A:, 1961, 16, 268. [all data]

Ebel, Dieck, et al., 1981
Ebel, S.; Dieck, T.; Walther, H., Photoelectron spectra of group V compounds, As4 and As2, Inorg. Chim. Acta, 1981, 53, 101. [all data]


Notes

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