Reaction data

Oxygen cation + Oxygen = (Oxygen cation • Oxygen)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

ΔrH° (kJ/mol) Method Reference Comment
38. ± 2.PHPMSHiraoka, 1988gas phase; M
41.PILinn, Ono, et al., 1981gas phase; M
45.2 ± 0.2PHPMSConway and Janik, 1970gas phase; M
40.PHPMSDurden, Kebarle, et al., 1969gas phase; M
40.PHPMSYang and Conway, 1964gas phase; M
25.PIAnderson, Hirooka, et al., 1980gas phase; M; Data excluded from overall average

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, 1988
Hiraoka, K., A Determination of the Stabilities of O2+(O2)n and O2-(O2)n with n = 1 - 8 from Measurements of the Gas-Phase Ion Equilibria, J. Chem. Phys., 1988, 89, 5, 3190, https://doi.org/10.1063/1.454976 . [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., A Study of the Ion - Molecule Half Reactions O2+(a4piu, v)...(O2)m ---> O2m+1 + O, m=1, 2, 3, Using the Molecular Beam Photoionization Method, J. Chem. Phys., 1981, 74, 6, 3348, https://doi.org/10.1063/1.441487 . [all data]

Conway and Janik, 1970
Conway, D.C.; Janik, G.S., Determination of the Bond Energies for the Series O2 - O2+ through O2 - O10+, J. Chem. Phys., 1970, 53, 5, 1859, https://doi.org/10.1063/1.1674262 . [all data]

Durden, Kebarle, et al., 1969
Durden, D.A.; Kebarle, P.; Good, A., Thermal Ion-Molecule Reaction Rate Constants at Pressures up to 10 torr with a Pulsed Mass Spectrometer. Reactions in Methane, Krypton, and Oxygen, J. Chem. Phys., 1969, 50, 2, 805, https://doi.org/10.1063/1.1671133 . [all data]

Yang and Conway, 1964
Yang, J.H.; Conway, D.C., Bonding in Ion Clusters. I. O4+, J. Chem. Phys., 1964, 40, 6, 1729, https://doi.org/10.1063/1.1725389 . [all data]

Anderson, Hirooka, et al., 1980
Anderson, S.L.; Hirooka, T.; Tiedeman, P.W.; Mahan, B.H.; Lee, Y.T., Photoionization of (H2)2 and Clusters of O2 Molecules, J. Chem. Phys., 1980, 73, 10, 4779, https://doi.org/10.1063/1.440010 . [all data]


Notes

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