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Reaction data

Oxygen cation + Carbon dioxide = (Oxygen cation bullet Carbon dioxide)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

DeltarH° (kJ/mol) Method Reference Comment
41. ± 2.PHPMSHiraoka, Nakajima, et al., 1988gas phase; M
40. ± 1.DTIllies, 1988gas phase; «DELTA»rH(0 K)=41.0 kJ/mol; M
38. ± 5.0PDissKim, Kuo, et al., 1987gas phase; M
43.9FADotan, Davidson, et al., 1978gas phase; switching reaction(O2+)O2, Entropy change calculated or estimated; Conway and Janik, 1970; M
89.5PHPMSMeot-Ner (Mautner) and Field, 1977gas phase; Entropy change calculated or estimated, DG>, «DELTA»rH>; M; Data excluded from overall average
44.4PDissBeyer and Vanderhoff, 1976gas phase; «DELTA»rH<; M; Data excluded from overall average

References

Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Nakajima, et al., 1988
Hiraoka, K.; Nakajima, G.; Shoda, S., Determination of the Stabilities of CO2+(CO2)n and O2+(CO2)n Clusters with n = 1 - 6, Chem. Phys. Lett., 1988, 146, 6, 535, https://doi.org/10.1016/0009-2614(88)87495-5 . [all data]

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Kim, Kuo, et al., 1987
Kim, H.S.; Kuo, C.H.; Bowers, M.T., Photon Driven Charge Transfer Half-Collisions: The Photodissociation of CO2.O2+ Cluster Ions with Resolution of the O2 Product Vibrational States, J. Chem. Phys., 1987, 87, 5, 2667, https://doi.org/10.1063/1.453105 . [all data]

Dotan, Davidson, et al., 1978
Dotan, I.; Davidson, J.A.; Fehsenfeld, F.C.; Albritton, D.L., Reactions of O2+.O2 with CO2, O3 and CH4 and O2+.O3 with H2O and CH4 and their Role in Stratospheric Ion Chemistry, J. Geophys. Res., 1978, 83, C8, 4036, https://doi.org/10.1029/JC083iC08p04036 . [all data]

Conway and Janik, 1970
Conway, D.C.; Janik, G.S., Determination of the Bond Energies for the Series O2 - O2+ through O2 - O10+, J. Chem. Phys., 1970, 53, 5, 1859, https://doi.org/10.1063/1.1674262 . [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry, J. Chem. Phys., 1977, 66, 10, 4527, https://doi.org/10.1063/1.433706 . [all data]

Beyer and Vanderhoff, 1976
Beyer, R.A.; Vanderhoff, J.A., Cross Section Measurements for Photodetachment or Photodissociation of Ions Produced in Gaseous Mixtures of O2, CO2 and H2O, J. Chem. Phys., 1976, 65, 6, 2313, https://doi.org/10.1063/1.433342 . [all data]


Notes

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