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Azide cation


Reaction thermochemistry data

Go To: Top, Ion clustering data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(N3+ bullet 10Nitrogen) + Nitrogen = (N3+ bullet 11Nitrogen)

By formula: (N3+ bullet 10N2) + N2 = (N3+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar70.7J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 9Nitrogen) + Nitrogen = (N3+ bullet 10Nitrogen)

By formula: (N3+ bullet 9N2) + N2 = (N3+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar69.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 3Nitrogen) + Nitrogen = (N3+ bullet 4Nitrogen)

By formula: (N3+ bullet 3N2) + N2 = (N3+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar15. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 4Nitrogen) + Nitrogen = (N3+ bullet 5Nitrogen)

By formula: (N3+ bullet 4N2) + N2 = (N3+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 5Nitrogen) + Nitrogen = (N3+ bullet 6Nitrogen)

By formula: (N3+ bullet 5N2) + N2 = (N3+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar10. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 6Nitrogen) + Nitrogen = (N3+ bullet 7Nitrogen)

By formula: (N3+ bullet 6N2) + N2 = (N3+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar80.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 7Nitrogen) + Nitrogen = (N3+ bullet 8Nitrogen)

By formula: (N3+ bullet 7N2) + N2 = (N3+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar69.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 8Nitrogen) + Nitrogen = (N3+ bullet 9Nitrogen)

By formula: (N3+ bullet 8N2) + N2 = (N3+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar68.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 2Nitrogen) + Nitrogen = (N3+ bullet 3Nitrogen)

By formula: (N3+ bullet 2N2) + N2 = (N3+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet Nitrogen) + Nitrogen = (N3+ bullet 2Nitrogen)

By formula: (N3+ bullet N2) + N2 = (N3+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

N3+ + Nitrogen = (N3+ bullet Nitrogen)

By formula: N3+ + N2 = (N3+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

N3+ + Nitrogen = (N3+ bullet Nitrogen)

By formula: N3+ + N2 = (N3+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet Nitrogen) + Nitrogen = (N3+ bullet 2Nitrogen)

By formula: (N3+ bullet N2) + N2 = (N3+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 2Nitrogen) + Nitrogen = (N3+ bullet 3Nitrogen)

By formula: (N3+ bullet 2N2) + N2 = (N3+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 3Nitrogen) + Nitrogen = (N3+ bullet 4Nitrogen)

By formula: (N3+ bullet 3N2) + N2 = (N3+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar15. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 4Nitrogen) + Nitrogen = (N3+ bullet 5Nitrogen)

By formula: (N3+ bullet 4N2) + N2 = (N3+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 5Nitrogen) + Nitrogen = (N3+ bullet 6Nitrogen)

By formula: (N3+ bullet 5N2) + N2 = (N3+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar10. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 6Nitrogen) + Nitrogen = (N3+ bullet 7Nitrogen)

By formula: (N3+ bullet 6N2) + N2 = (N3+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar80.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 7Nitrogen) + Nitrogen = (N3+ bullet 8Nitrogen)

By formula: (N3+ bullet 7N2) + N2 = (N3+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar69.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 8Nitrogen) + Nitrogen = (N3+ bullet 9Nitrogen)

By formula: (N3+ bullet 8N2) + N2 = (N3+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar68.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 9Nitrogen) + Nitrogen = (N3+ bullet 10Nitrogen)

By formula: (N3+ bullet 9N2) + N2 = (N3+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar69.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ bullet 10Nitrogen) + Nitrogen = (N3+ bullet 11Nitrogen)

By formula: (N3+ bullet 10N2) + N2 = (N3+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Deltar70.7J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

Vibrational and/or electronic energy levels

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 35370 T gas A-X 245 283 Friedmann, Soliva, et al., 1994


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 1300 T gas PF Friedmann, Soliva, et al., 1994
Piu 2 Bend 440 T gas PF Friedmann, Soliva, et al., 1994
Sigmau+ 3 Asym. stretch 1700 T gas PF Friedmann, Soliva, et al., 1994

State:   b


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 14520 ± 160 gas Dyke, Jonathan, et al., 1982

State:   a


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 9120 ± 160 gas Dyke, Jonathan, et al., 1982

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 Sym. stretch 1170 ± 30 gas PE Dyke, Jonathan, et al., 1982

Additional references: Jacox, 1994, page 72; Jacox, 1998, page 181

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., Stabilities of the N3+(N2)n Cluster Ions with n = 1 - 11, Chem. Phys. Lett., 1989, 154, 2, 139, https://doi.org/10.1016/S0009-2614(89)87275-6 . [all data]

Friedmann, Soliva, et al., 1994
Friedmann, A.; Soliva, A.M.; Nizkorodov, S.A.; Bieske, E.J.; Maier, J.P., A 3.PI.u .rarw. X 3.SIGMA.g- Electronic Spectrum of N3+, J. Phys. Chem., 1994, 98, 36, 8896, https://doi.org/10.1021/j100087a013 . [all data]

Dyke, Jonathan, et al., 1982
Dyke, J.M.; Jonathan, N.B.H.; Lewis, A.E.; Morris, A., Vacuum ultraviolet photoelectron spectroscopy oftransient species. Part 15. The N3(X2«pi») radical, Mol. Phys., 1982, 47, 1231. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, References