Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Hydrogen anion


Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Hydrogen anion = C7H13O-

By formula: H- = C7H13O-

Quantity Value Units Method Reference Comment
Deltar154. ± 9.6kJ/molN/AHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.; B

Hydrogen anion = C7H15O-

By formula: H- = C7H15O-

Quantity Value Units Method Reference Comment
Deltar181. ± 14.kJ/molN/ABoand, Houriet, et al., 1983gas phase; value altered from reference due to change in acidity scale; B

Hydrogen anion + CH2BN = (Hydrogen anion bullet CH2BN)

By formula: H- + CH2BN = (H- bullet CH2BN)

Quantity Value Units Method Reference Comment
Deltar112.5kJ/molN/AWorkman and Squires, 1988gas phase; Calculated from data on BH3..CN-; B

Hydrogen anion + Trimethylaluminum = (Hydrogen anion bullet Trimethylaluminum)

By formula: H- + C3H9Al = (H- bullet C3H9Al)

Quantity Value Units Method Reference Comment
Deltar>354.8 ± 2.1kJ/molIMRBden Berg, Ingemann, et al., 1992gas phase; Hydride affinity > (CF3)2CO. Computations indicate HOF(A-) ca. -46 kcal/mol, dHaff ca. 74 kcal/mol; B

Hydrogen anion + Diethylsilane = (Hydrogen anion bullet Diethylsilane)

By formula: H- + C4H12Si = (H- bullet C4H12Si)

Quantity Value Units Method Reference Comment
Deltar84. ± 17.kJ/molIMRBHajdasz, Ho, et al., 1994gas phase; Hydride affinity order: Et3SiH<=Et2SiH2<=nPnSiH3<=SiH4. dHf(Et2SiH2) in 77Ped/Ryl is 10 kcal/mol too negative, relative to Me2SiH2.Group Additivity imples ca. -25 kcal/mol.; B

Hydrogen anion + Iron pentacarbonyl = (Hydrogen anion bullet Iron pentacarbonyl)

By formula: H- + C5FeO5 = (H- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar235. ± 13.kJ/molIMRBLane, Sallans, et al., 1985gas phase; B

Hydrogen anion + Trifluorophenylsilane = C6H6F3Si-

By formula: H- + C6H5F3Si = C6H6F3Si-

Quantity Value Units Method Reference Comment
Deltar268. ± 13.kJ/molCIDTKrouse, Lardin, et al., 2003gas phase; B

Hydrogen anion + Borane, triethyl- = (Hydrogen anion bullet Borane, triethyl-)

By formula: H- + C6H15B = (H- bullet C6H15B)

Quantity Value Units Method Reference Comment
Deltar290. ± 10.kJ/molEndoWorkman and Squires, 1988gas phase; From Endo threshold for hydride transfer to CO2; B

Hydrogen anion + Silane, triethyl- = (Hydrogen anion bullet Silane, triethyl-)

By formula: H- + C6H16Si = (H- bullet C6H16Si)

Quantity Value Units Method Reference Comment
Deltar84. ± 17.kJ/molIMRBHajdasz, Ho, et al., 1994gas phase; affinity order: Et3SiH<=Et2SiH2<=nPnSiH3<=SiH4. nPnSiH3 is 0.4±0.2 kcal/mol > Et3SiH in «DELTA»G. Et3SiH dHf(77PR) is wrong.; B
Deltar43. ± 23.kJ/molIMRBHajdasz and Squires, 1986gas phase; B

Hydrogen anion + Molybdenum hexacarbonyl = (Hydrogen anion bullet Molybdenum hexacarbonyl)

By formula: H- + C6MoO6 = (H- bullet C6MoO6)

Quantity Value Units Method Reference Comment
Deltar184. ± 17.kJ/molN/ALane and Squires, 1988gas phase; Hydride affinity between CH2=O and PhCH=O; B

Hydrogen anion + Tungsten hexacarbonyl = (Hydrogen anion bullet Tungsten hexacarbonyl)

By formula: H- + C6O6W = (H- bullet C6O6W)

Quantity Value Units Method Reference Comment
Deltar184. ± 17.kJ/molN/ALane and Squires, 1988gas phase; Hydride affinity between CH2=O and PhCH=O; B

Hydrogen anion + Hydroxyl radical = (Hydrogen anion bullet Hydroxyl radical)

By formula: H- + HO = (H- bullet HO)

Quantity Value Units Method Reference Comment
Deltar217. ± 17.kJ/molTherde Koening and Nibbering, 1984gas phase; B

Hydrogen anion + Water = (Hydrogen anion bullet Water)

By formula: H- + H2O = (H- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar74.1 ± 8.4kJ/molN/AMiller, Leopold, et al., 1985gas phase; EA given is Vertical Detachment Energy. Est. Adiabatic: 1.40 eV, 32.3 kcal/mol; B
Deltar72. ± 15.kJ/molTherPaulson and Henchman, 1984gas phase; HOH..HO- + H2 ->. See also Griffiths and Harris, 1989; B,M
Deltar57.74kJ/molCIDTPaulson and Henchman, 1982gas phase; B

Hydrogen anion + aluminium trihydride = H4Al-

By formula: H- + H3Al = H4Al-

Quantity Value Units Method Reference Comment
Deltar314. ± 17.kJ/molCIDTGoebbert, Hernandez, et al., 2005gas phase; B

Hydrogen anion + Borane = (Hydrogen anion bullet Borane)

By formula: H- + H3B = (H- bullet H3B)

Quantity Value Units Method Reference Comment
Deltar310. ± 12.kJ/molEndoWorkman and Squires, 1988gas phase; From Endo threshold for hydride transfer to CO2; B
Deltar322. ± 8.4kJ/molTherKrivtsov, Titova, et al., 1977gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar341.4kJ/molTherAltschuller, 1955gas phase; B

Hydrogen anion + Ammonia = (Hydrogen anion bullet Ammonia)

By formula: H- + H3N = (H- bullet H3N)

Quantity Value Units Method Reference Comment
Deltar29.7kJ/molEstSnodgrass, Coe, et al., 1995gas phase; Stated electron affinity is the Vertical Detachment Energy; B
Deltar35.kJ/molPESCoe, Snodgrass, et al., 1985gas phase; «DELTA»rH<; M

(Hydrogen anion bullet Ammonia) + Ammonia = (Hydrogen anion bullet 2Ammonia)

By formula: (H- bullet H3N) + H3N = (H- bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar33.9kJ/molEstSnodgrass, Coe, et al., 1995gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B

Hydrogen anion + Silane = (Hydrogen anion bullet Silane)

By formula: H- + H4Si = (H- bullet H4Si)

Quantity Value Units Method Reference Comment
Deltar79. ± 17.kJ/molIMRBHajdasz, Ho, et al., 1994gas phase; B
Deltar94. ± 19.kJ/molIMREHajdasz and Squires, 1986gas phase; QCISD Calculation: H-A = 20.2, 99MOC; B
Quantity Value Units Method Reference Comment
Deltar49. ± 17.kJ/molIMRBHajdasz, Ho, et al., 1994gas phase; B

Hydrogen anion + H6Al2 = H7Al2-

By formula: H- + H6Al2 = H7Al2-

Quantity Value Units Method Reference Comment
Deltar322. ± 17.kJ/molCIDTGoebbert, Hernandez, et al., 2005gas phase; B

Hydrogen anion + Diborane = (Hydrogen anion bullet Diborane)

By formula: H- + H6B2 = (H- bullet H6B2)

Quantity Value Units Method Reference Comment
Deltar309.6kJ/molTherWorkman and Squires, 1988gas phase; Calculated from data on BH3..BH4-; B

Hydrogen anion + Sulfur dioxide = (Hydrogen anion bullet Sulfur dioxide)

By formula: H- + O2S = (H- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar260. ± 67.kJ/molIMRBSheldon, Currie, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar240. ± 67.kJ/molIMRBSheldon, Currie, et al., 1985gas phase; B

Hydrogen anion + CAS Reg. No. 10177-98-7 = (Hydrogen anion bullet CAS Reg. No. 10177-98-7)

By formula: H- + CAS Reg. No. 10177-98-7 = (H- bullet CAS Reg. No. 10177-98-7)

Quantity Value Units Method Reference Comment
Deltar84. ± 17.kJ/molIMRBHajdasz, Ho, et al., 1994gas phase; affinity order: Et3SiH<=Et2SiH2<=nPnSiH3<=SiH4. nPnSiH3 is 0.4±0.2 kcal/mol > Et3SiH in «DELTA»G. Et3SiH dHf(77PR) is wrong.; B
Deltar45. ± 23.kJ/molIMRBHajdasz and Squires, 1986gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Haas and Harrison, 1993
Haas, M.J.; Harrison, A.G., The Fragmentation of Proton-Bound Cluster Ions and the Gas-Phase Acidities of Alcohols, Int. J. Mass Spectrom. Ion Proc., 1993, 124, 2, 115, https://doi.org/10.1016/0168-1176(93)80003-W . [all data]

Boand, Houriet, et al., 1983
Boand, G.; Houriet, R.; Baumann, T., The gas phase acidity of aliphatic alcohols, J. Am. Chem. Soc., 1983, 105, 2203. [all data]

Workman and Squires, 1988
Workman, D.B.; Squires, R.R., Hydride Binding Energies of Boranes, Inorg. Chem., 1988, 27, 11, 1846, https://doi.org/10.1021/ic00284a003 . [all data]

den Berg, Ingemann, et al., 1992
den Berg, K.J. van; Ingemann, S.; Nibbering, N.M.M., Gas Phase Reactions of Negative Ions with Trimethylaluminum: Formation and Reactivity of the Me3AlH- Ion., Org. Mass Spectrom., 1992, 27, 4, 523, https://doi.org/10.1002/oms.1210270427 . [all data]

Hajdasz, Ho, et al., 1994
Hajdasz, D.J.; Ho, Y.; Squires, R.R., Gas-Phase Chemistry of Pentacoordinate Silicon Hydrides, J. Am. Chem. Soc., 1994, 116, 23, 10751, https://doi.org/10.1021/ja00102a045 . [all data]

Lane, Sallans, et al., 1985
Lane, K.R.; Sallans, L.; Squires, R.R., Anion affinities of transition metal carbonyls. A thermochemical correlation for iron tetracarbonyl acyl negative ions, J. Am. Chem. Soc., 1985, 107, 5369. [all data]

Krouse, Lardin, et al., 2003
Krouse, I.H.; Lardin, H.A.; Wenthold, P.G., Gas-phase ion chemistry and ion thermochemistry of phenyltrifluorosilane, Int. J. Mass Spectrom., 2003, 227, 3, 303-314, https://doi.org/10.1016/S1387-3806(03)00080-0 . [all data]

Hajdasz and Squires, 1986
Hajdasz, D.J.; Squires, R.R., Hypervalent silicon hydrides: SiH5-, J. Am. Chem. Soc., 1986, 108, 3139. [all data]

Lane and Squires, 1988
Lane, K.R.; Squires, R.R., Hydride Transfer to Transition Metal Carbonyls in the Gas Phase. Formation and Relative Stabilities of Anionic Formyl Complexes, Polyhedron, 1988, 7, 16-17, 1609, https://doi.org/10.1016/S0277-5387(00)81786-6 . [all data]

de Koening and Nibbering, 1984
de Koening, L.J.; Nibbering, N.M.M., Formation of the Long-Lived H2O-. Ion in the Gas Phase, J. Am. Chem. Soc., 1984, 106, 25, 7971, https://doi.org/10.1021/ja00337a054 . [all data]

Miller, Leopold, et al., 1985
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., The Photoelectron Spectrum of H3O-, Bull. Am. Phys. Soc., 1985, 30, 880. [all data]

Paulson and Henchman, 1984
Paulson, J.F.; Henchman, M.J., On the Formation of H3O- in an Ion-Molecule Reaction in Ionic Processes in the Gas Phase,, M.A. Almoster Ferreira, Ed., Reidel, Dordrecht,, 1984, 331. [all data]

Griffiths and Harris, 1989
Griffiths, W.J.; Harris, F.M., Amended Interpretation of the Results Obtained in an Experimental Investigation of the Structure of the H3O- Ion, Int. J. Mass Spectrom. Ion Proc., 1989, 87, 1, R25, https://doi.org/10.1016/0168-1176(89)80017-5 . [all data]

Paulson and Henchman, 1982
Paulson, J.F.; Henchman, M.J., The Hydrated Negative Hydrogen Ion, Bull. Am. Phys. Soc., 1982, 27, 108. [all data]

Goebbert, Hernandez, et al., 2005
Goebbert, D.J.; Hernandez, H.; Francisco, J.S.; Wenthold, P.G., The binding energy and bonding in dialane, J. Am. Chem. Soc., 2005, 127, 33, 11684-11689, https://doi.org/10.1021/ja0424070 . [all data]

Krivtsov, Titova, et al., 1977
Krivtsov, N.V.; Titova, K.V.; Rosolovskii, V.Ya., Thermochemical study of complex borates, Russ. J. Inorg. Chem., 1977, 22, 374. [all data]

Altschuller, 1955
Altschuller, A.P., Lattice Energies and Related Thermodynamic Properties of the Alkali Metal Borohydrides and of the Borohydride Ion, J. Am. Chem. Soc., 1955, 77, 21, 5455, https://doi.org/10.1021/ja01626a001 . [all data]

Snodgrass, Coe, et al., 1995
Snodgrass, J.T.; Coe, J.V.; Freidhoff, C.B.; Mchugh, K.M.; Arnold, S.T.; Bowen, K.H., Negative ion photoelectron spectroscopy of NH2-(NH3)1 and NH2-(NH3)2: Gas phase basicities of partially solvated anions, J. Phys. Chem., 1995, 99, 24, 9675, https://doi.org/10.1021/j100024a006 . [all data]

Coe, Snodgrass, et al., 1985
Coe, J.V.; Snodgrass, J.T.; Friedhoff, C.B.; McHugh, K.M.; Bowen, K.H., Negative ion photoelectron spectroscopy of the negative ion H-(NH3), J. Chem. Phys., 1985, 83, 3169. [all data]

Sheldon, Currie, et al., 1985
Sheldon, J.C.; Currie, G.J.; Lahnstein, J.; Hayes, R.N.; Bowie, J.H., Gas Phase Ion Chemistry of Ambident Nucleophiles. Reactions of Alkoxide and Thiomethoxide Negative Ions with Hydrogen Free Molecules., Nouv. J. Chem., 1985, 9, 205. [all data]


Notes

Go To: Top, Ion clustering data, References