Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Titanium,bis(«eta»5-2,4-cyclopentadien-1-yl)diiodo-


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C10H10I2Ti (solution) + Titanocene dichloride (solution) = 2C10H10ClITi (solution)

By formula: C10H10I2Ti (solution) + C10H10Cl2Ti (solution) = 2C10H10ClITi (solution)

Quantity Value Units Method Reference Comment
Deltar-3.4kJ/molEqSBruce and Tyler, 1985solvent: Perdeuterated benzene; The reaction enthalpy relies on a single value for the equilibrium constant. It assumes a negligible reaction entropy

Titanium, dicarbonylbis(η5-2,4-cyclopentadien-1-yl)- (cr) + Iodine (cr) = C10H10I2Ti (cr) + 2Carbon monoxide (g)

By formula: C12H10O2Ti (cr) + I2 (cr) = C10H10I2Ti (cr) + 2CO (g)

Quantity Value Units Method Reference Comment
Deltar-74.1 ± 2.1kJ/molRSCDias, Dias, et al., 1987 

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bruce and Tyler, 1985
Bruce, M.R.M.; Tyler, D.R., Organometallics, 1985, 4, 528. [all data]

Dias, Dias, et al., 1987
Dias, A.R.; Dias, P.B.; Diogo, H.P.; Galvão, A.M.; Minas da Piedade, M.E.; Martinho Simões, J.A., Organometallics, 1987, 6, 1427. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References