Titanium,bis(η5-2,4-cyclopentadien-1-yl)diiodo-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C10H10I2Ti (solution) + Titanocene dichloride (solution) = 2C10H10ClITi (solution)

By formula: C10H10I2Ti (solution) + C10H10Cl2Ti (solution) = 2C10H10ClITi (solution)

Quantity Value Units Method Reference Comment
Δr-0.81kcal/molEqSBruce and Tyler, 1985solvent: Perdeuterated benzene; The reaction enthalpy relies on a single value for the equilibrium constant. It assumes a negligible reaction entropy

Titanium, dicarbonylbis(η5-2,4-cyclopentadien-1-yl)- (cr) + Iodine (cr) = C10H10I2Ti (cr) + 2Carbon monoxide (g)

By formula: C12H10O2Ti (cr) + I2 (cr) = C10H10I2Ti (cr) + 2CO (g)

Quantity Value Units Method Reference Comment
Δr-17.7 ± 0.50kcal/molRSCDias, Dias, et al., 1987 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.0 ± 0.1PECauletti, Clark, et al., 1980Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bruce and Tyler, 1985
Bruce, M.R.M.; Tyler, D.R., Organometallics, 1985, 4, 528. [all data]

Dias, Dias, et al., 1987
Dias, A.R.; Dias, P.B.; Diogo, H.P.; Galvão, A.M.; Minas da Piedade, M.E.; Martinho Simões, J.A., Organometallics, 1987, 6, 1427. [all data]

Cauletti, Clark, et al., 1980
Cauletti, C.; Clark, J.P.; Green, J.C.; Jackson, S.E.; Fragala, I.L.; Ciliberto, E.; Coleman, A.W., Photoelectron spectra of bis-cyclopentadienyl metal dihalides, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 61. [all data]


Notes

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