Magnesium carbide


Solid Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 2500.
A 28.36661
B 2.579561
C -0.013452
D 0.002940
E -0.597694
F 8.412689
G 54.17001
H 19.00000
ReferenceChase, 1998
Comment Data last reviewed in December, 1960
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
298.22.4023.9624.01-0.01
300.22.5024.1124.010.03
400.25.6631.0824.932.46
500.27.2636.9926.765.11
600.28.2542.0628.907.89
700.28.9546.4631.1010.75
800.29.4950.3733.2713.68
900.29.9453.8735.3716.65
1000.30.3457.0437.3819.66
1100.30.7059.9539.3022.72
1200.31.0362.6441.1425.80
1300.31.3565.1342.8928.92
1400.31.6567.4744.5632.07
1500.31.9569.6646.1635.25
1600.32.2471.7347.7038.46
1700.32.5273.7049.1741.70
1800.32.8075.5650.5844.97
1900.33.0777.3451.9448.26
2000.33.3579.0553.2651.58
2100.33.6280.6854.5254.93
2200.33.8882.2555.7558.30
2300.34.1583.7656.9361.70
2400.34.4285.2258.0865.13
2500.34.6886.6359.2068.59

References

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), References