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Triethylamine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltafgas-32.05kcal/molN/ABaroody and Carpenter, 1972Value computed using «DELTA»fHliquid° value of -169 kj/mol from Baroody and Carpenter, 1972 and «DELTA»vapH° value of 34.94±0.06 kj/mol from missing citation.
Deltafgas-22.2 ± 0.1kcal/molN/ALebedeva, 1966Value computed using «DELTA»fHliquid° value of -127.8±0.54 kj/mol from Lebedeva, 1966 and «DELTA»vapH° value of 34.94±0.06 kj/mol from missing citation.
Deltafgas-34.20kcal/molN/ALemoult, 1907Value computed using «DELTA»fHliquid° value of -178 kj/mol from Lemoult, 1907 and «DELTA»vapH° value of 34.94±0.06 kj/mol from missing citation.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-40.5kcal/molCcbBaroody and Carpenter, 1972ALS
Deltafliquid-30.54 ± 0.13kcal/molCcbLebedeva, 1966ALS
Deltafliquid-42.6kcal/molCcbLemoult, 1907ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1046.15 ± 0.13kcal/molCcbLebedeva, 1966ALS
Deltacliquid-1040.7kcal/molCcbLemoult, 1907ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
51.728298.15Grolier, Roux-Desgranges, et al., 1993DH
52.127298.15Hepler, Kooner, et al., 1985DH
42.30298.von Reis, 1881T = 293 to 378 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H9Sn+ + Triethylamine = (C3H9Sn+ bullet Triethylamine)

By formula: C3H9Sn+ + C6H15N = (C3H9Sn+ bullet C6H15N)

Quantity Value Units Method Reference Comment
Deltar45.7kcal/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar33.9cal/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
27.9525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated

C6H16N+ + Triethylamine = (C6H16N+ bullet Triethylamine)

By formula: C6H16N+ + C6H15N = (C6H16N+ bullet C6H15N)

Quantity Value Units Method Reference Comment
Deltar23.8kcal/molPHPMSMeot-Ner M. and Sieck, 1983gas phase
Quantity Value Units Method Reference Comment
Deltar41.0cal/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baroody and Carpenter, 1972
Baroody, E.E.; Carpenter, G.A., Heats of formation of propellant compounds (U), Rpt. Naval Ordnance Systems Command Task No. 331-003/067-1/UR2402-001 for Naval Ordance Station, Indian Head, MD, 1972, 1-9. [all data]

Lebedeva, 1966
Lebedeva, N.D., Heats of combustion and formation of aliphatic tertiary amine homologues, Russ. J. Phys. Chem. (Engl. Transl.), 1966, 40, 1465-1467. [all data]

Lemoult, 1907
Lemoult, M.P., Recherches theoriques et experimentales sur les chaleurs de combustion et de formation des composes organiques, Ann. Chim. Phys., 1907, 12, 395-432. [all data]

Grolier, Roux-Desgranges, et al., 1993
Grolier, J.-P.E.; Roux-Desgranges, G.; Berkane, M.; Jimenez, E.; Wilhelm, E., Heat capacities and densities of mixtures of very polar substances 2. Mixtures containing N,N-dimethylformamide, J. Chem. Thermodynam., 1993, 25(1), 41-50. [all data]

Hepler, Kooner, et al., 1985
Hepler, L.G.; Kooner, Z.S.; Roux-Desgranges, G.; Grolier, J.-P.E., Thermal and volumetric properties of chloroform + triethylamine mixtures and the ideal associated solution model of complex formation, J. Solution Chem., 1985, 14(8), 579-594. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]

Stone and Splinter, 1984
Stone, J.A.; Splinter, D.E., A high-pressure mass spectrometric study of the binding of (CH3)3Sn+ to lewis bases in the gas phase, Int. J. Mass Spectrom. Ion Processes, 1984, 59, 169. [all data]

Meot-Ner M. and Sieck, 1983
Meot-Ner M.; Sieck, L.W., The Ionic Hydrogen Bond. 1. Sterically Hindered Bonds. Solvation and Clustering of Sterically Hindered Amines and Pyridines, J. Am. Chem. Soc., 1983, 105, 10, 2956, https://doi.org/10.1021/ja00348a005 . [all data]


Notes

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