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Carbon monoxide, ion(1+)


Reaction thermochemistry data

Go To: Top, Ion clustering data, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CO+ + Carbon monoxide = (CO+ bullet Carbon monoxide)

By formula: CO+ + CO = (CO+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar67.kJ/molPIPECONorwood, Guo, et al., 1988gas phase; CO+ in state B, «DELTA»rH>
Deltar93.7kJ/molPILinn, Ono, et al., 1981gas phase
Deltar120. ± 30.kJ/molEIMunson and Franlin, 1962gas phase; from IP'switching reaction and heats of formation
Deltar106.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.340.HPMSChong and Franklin, 1971gas phase; equilibrium uncertain
48.1695.PHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>

(CO+ bullet 2Carbon monoxide) + Carbon monoxide = (CO+ bullet 3Carbon monoxide)

By formula: (CO+ bullet 2CO) + CO = (CO+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar30.2kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures

(CO+ bullet 5Carbon monoxide) + Carbon monoxide = (CO+ bullet 6Carbon monoxide)

By formula: (CO+ bullet 5CO) + CO = (CO+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar11.3kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures

(CO+ bullet 6Carbon monoxide) + Carbon monoxide = (CO+ bullet 7Carbon monoxide)

By formula: (CO+ bullet 6CO) + CO = (CO+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar9.41kJ/molPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot
Quantity Value Units Method Reference Comment
Deltar88.3J/mol*KPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot

(CO+ bullet 7Carbon monoxide) + Carbon monoxide = (CO+ bullet 8Carbon monoxide)

By formula: (CO+ bullet 7CO) + CO = (CO+ bullet 8CO)

Quantity Value Units Method Reference Comment
Deltar6.61kJ/molPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot
Quantity Value Units Method Reference Comment
Deltar51.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot

(CO+ bullet Carbon monoxide) + Carbon monoxide = (CO+ bullet 2Carbon monoxide)

By formula: (CO+ bullet CO) + CO = (CO+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSHiraoka and Mori, 1991gas phase
Deltar15.kJ/molPILinn, Ono, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Deltar149.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 3Carbon monoxide) + Carbon monoxide = (CO+ bullet 4Carbon monoxide)

By formula: (CO+ bullet 3CO) + CO = (CO+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar18.4kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers

(CO+ bullet 4Carbon monoxide) + Carbon monoxide = (CO+ bullet 5Carbon monoxide)

By formula: (CO+ bullet 4CO) + CO = (CO+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar17.8kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers

(CO+ bullet 11Carbon monoxide) + Carbon monoxide = (CO+ bullet 12Carbon monoxide)

By formula: (CO+ bullet 11CO) + CO = (CO+ bullet 12CO)

Quantity Value Units Method Reference Comment
Deltar8.91kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 12Carbon monoxide) + Carbon monoxide = (CO+ bullet 13Carbon monoxide)

By formula: (CO+ bullet 12CO) + CO = (CO+ bullet 13CO)

Quantity Value Units Method Reference Comment
Deltar8.79kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 13Carbon monoxide) + Carbon monoxide = (CO+ bullet 14Carbon monoxide)

By formula: (CO+ bullet 13CO) + CO = (CO+ bullet 14CO)

Quantity Value Units Method Reference Comment
Deltar8.70kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 14Carbon monoxide) + Carbon monoxide = (CO+ bullet 15Carbon monoxide)

By formula: (CO+ bullet 14CO) + CO = (CO+ bullet 15CO)

Quantity Value Units Method Reference Comment
Deltar8.03kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 15Carbon monoxide) + Carbon monoxide = (CO+ bullet 16Carbon monoxide)

By formula: (CO+ bullet 15CO) + CO = (CO+ bullet 16CO)

Quantity Value Units Method Reference Comment
Deltar8.03kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 16Carbon monoxide) + Carbon monoxide = (CO+ bullet 17Carbon monoxide)

By formula: (CO+ bullet 16CO) + CO = (CO+ bullet 17CO)

Quantity Value Units Method Reference Comment
Deltar7.87kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 9Carbon monoxide) + Carbon monoxide = (CO+ bullet 10Carbon monoxide)

By formula: (CO+ bullet 9CO) + CO = (CO+ bullet 10CO)

Quantity Value Units Method Reference Comment
Deltar7.74kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase

CO+ + Argon = (CO+ bullet Argon)

By formula: CO+ + Ar = (CO+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar67.4 ± 5.9kJ/molPIPECONorwood, Guo, et al., 1989gas phase; CO+(X) ground state

Ion clustering data

Go To: Top, Reaction thermochemistry data, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CO+ + Argon = (CO+ bullet Argon)

By formula: CO+ + Ar = (CO+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar67.4 ± 5.9kJ/molPIPECONorwood, Guo, et al., 1989gas phase; CO+(X) ground state

CO+ + Carbon monoxide = (CO+ bullet Carbon monoxide)

By formula: CO+ + CO = (CO+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar67.kJ/molPIPECONorwood, Guo, et al., 1988gas phase; CO+ in state B, «DELTA»rH>
Deltar93.7kJ/molPILinn, Ono, et al., 1981gas phase
Deltar120. ± 30.kJ/molEIMunson and Franlin, 1962gas phase; from IP'switching reaction and heats of formation
Deltar106.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.340.HPMSChong and Franklin, 1971gas phase; equilibrium uncertain
48.1695.PHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>

(CO+ bullet Carbon monoxide) + Carbon monoxide = (CO+ bullet 2Carbon monoxide)

By formula: (CO+ bullet CO) + CO = (CO+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSHiraoka and Mori, 1991gas phase
Deltar15.kJ/molPILinn, Ono, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Deltar149.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 2Carbon monoxide) + Carbon monoxide = (CO+ bullet 3Carbon monoxide)

By formula: (CO+ bullet 2CO) + CO = (CO+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar30.2kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures

(CO+ bullet 3Carbon monoxide) + Carbon monoxide = (CO+ bullet 4Carbon monoxide)

By formula: (CO+ bullet 3CO) + CO = (CO+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar18.4kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers

(CO+ bullet 4Carbon monoxide) + Carbon monoxide = (CO+ bullet 5Carbon monoxide)

By formula: (CO+ bullet 4CO) + CO = (CO+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar17.8kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers

(CO+ bullet 5Carbon monoxide) + Carbon monoxide = (CO+ bullet 6Carbon monoxide)

By formula: (CO+ bullet 5CO) + CO = (CO+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar11.3kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures

(CO+ bullet 6Carbon monoxide) + Carbon monoxide = (CO+ bullet 7Carbon monoxide)

By formula: (CO+ bullet 6CO) + CO = (CO+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar9.41kJ/molPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot
Quantity Value Units Method Reference Comment
Deltar88.3J/mol*KPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot

(CO+ bullet 7Carbon monoxide) + Carbon monoxide = (CO+ bullet 8Carbon monoxide)

By formula: (CO+ bullet 7CO) + CO = (CO+ bullet 8CO)

Quantity Value Units Method Reference Comment
Deltar6.61kJ/molPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot
Quantity Value Units Method Reference Comment
Deltar51.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot

(CO+ bullet 9Carbon monoxide) + Carbon monoxide = (CO+ bullet 10Carbon monoxide)

By formula: (CO+ bullet 9CO) + CO = (CO+ bullet 10CO)

Quantity Value Units Method Reference Comment
Deltar7.74kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 11Carbon monoxide) + Carbon monoxide = (CO+ bullet 12Carbon monoxide)

By formula: (CO+ bullet 11CO) + CO = (CO+ bullet 12CO)

Quantity Value Units Method Reference Comment
Deltar8.91kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 12Carbon monoxide) + Carbon monoxide = (CO+ bullet 13Carbon monoxide)

By formula: (CO+ bullet 12CO) + CO = (CO+ bullet 13CO)

Quantity Value Units Method Reference Comment
Deltar8.79kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 13Carbon monoxide) + Carbon monoxide = (CO+ bullet 14Carbon monoxide)

By formula: (CO+ bullet 13CO) + CO = (CO+ bullet 14CO)

Quantity Value Units Method Reference Comment
Deltar8.70kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 14Carbon monoxide) + Carbon monoxide = (CO+ bullet 15Carbon monoxide)

By formula: (CO+ bullet 14CO) + CO = (CO+ bullet 15CO)

Quantity Value Units Method Reference Comment
Deltar8.03kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 15Carbon monoxide) + Carbon monoxide = (CO+ bullet 16Carbon monoxide)

By formula: (CO+ bullet 15CO) + CO = (CO+ bullet 16CO)

Quantity Value Units Method Reference Comment
Deltar8.03kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 16Carbon monoxide) + Carbon monoxide = (CO+ bullet 17Carbon monoxide)

By formula: (CO+ bullet 16CO) + CO = (CO+ bullet 17CO)

Quantity Value Units Method Reference Comment
Deltar7.87kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Norwood, Guo, et al., 1988
Norwood, K.; Guo, J.H.; Luo, G.; Ng, C.Y., A Photoion - Photoelectron Coincidence Study of (CO)2, J. Chem. Phys., 1988, 88, 6, 4098, https://doi.org/10.1063/1.453814 . [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., Molecular Beam Photoionization Study of CO, N2, and NO Dimers and Clusters, J. Chem. Phys., 1981, 74, 6, 3342, https://doi.org/10.1063/1.441486 . [all data]

Munson and Franlin, 1962
Munson, M.S.B. Field; Franlin, J.L., High-Pressure Mass Spectrometric Study of Reactions of Rare Gases with N2 and CO, J. Chem. Phys., 1962, 37, 8, 1790, https://doi.org/10.1063/1.1733370 . [all data]

Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

Chong and Franklin, 1971
Chong, S.L.; Franklin, J.L., High-Pressure Ion-Molecule Reactions in Carbon Monoxide and Carbon Monoxide - Methane Mixtures, J. Chem. Phys., 1971, 54, 4, 1487, https://doi.org/10.1063/1.1675043 . [all data]

Hiraoka and Mori, 1991
Hiraoka, K.; Mori, T., On the formation of the Isomeric Cluster Ions (CO)n+, J. Chem. Phys., 1991, 94, 4, 2697, https://doi.org/10.1063/1.459844 . [all data]

Norwood, Guo, et al., 1989
Norwood, K.; Guo, J.H.; Luo, G.; Ng, C.Y., A Study of Intramolecular Charge Transfer in Mixed Ar/Co Dimer and Trimer Ions Using the Photoion - Photoelectron Coincidence Method, Chem. Phys., 1989, 129, 1, 109, https://doi.org/10.1016/0301-0104(89)80023-0 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, NIST Free Links, References