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Carbon monoxide, ion(1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CO+ + Argon = (CO+ bullet Argon)

By formula: CO+ + Ar = (CO+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar67.4 ± 5.9kJ/molPIPECONorwood, Guo, et al., 1989gas phase; CO+(X) ground state

CO+ + Carbon monoxide = (CO+ bullet Carbon monoxide)

By formula: CO+ + CO = (CO+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar67.kJ/molPIPECONorwood, Guo, et al., 1988gas phase; CO+ in state B, «DELTA»rH>
Deltar93.7kJ/molPILinn, Ono, et al., 1981gas phase
Deltar120. ± 30.kJ/molEIMunson and Franlin, 1962gas phase; from IP'switching reaction and heats of formation
Deltar106.kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.340.HPMSChong and Franklin, 1971gas phase; equilibrium uncertain
48.1695.PHPMSMeot-Ner (Mautner) and Field, 1974gas phase; «DELTA»rH>, DG>

(CO+ bullet Carbon monoxide) + Carbon monoxide = (CO+ bullet 2Carbon monoxide)

By formula: (CO+ bullet CO) + CO = (CO+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSHiraoka and Mori, 1991gas phase
Deltar15.kJ/molPILinn, Ono, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Deltar149.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 2Carbon monoxide) + Carbon monoxide = (CO+ bullet 3Carbon monoxide)

By formula: (CO+ bullet 2CO) + CO = (CO+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar30.2kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures

(CO+ bullet 3Carbon monoxide) + Carbon monoxide = (CO+ bullet 4Carbon monoxide)

By formula: (CO+ bullet 3CO) + CO = (CO+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar18.4kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers

(CO+ bullet 4Carbon monoxide) + Carbon monoxide = (CO+ bullet 5Carbon monoxide)

By formula: (CO+ bullet 4CO) + CO = (CO+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar17.8kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers

(CO+ bullet 5Carbon monoxide) + Carbon monoxide = (CO+ bullet 6Carbon monoxide)

By formula: (CO+ bullet 5CO) + CO = (CO+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar11.3kJ/molPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase; two isomers, at low and high temperatures

(CO+ bullet 6Carbon monoxide) + Carbon monoxide = (CO+ bullet 7Carbon monoxide)

By formula: (CO+ bullet 6CO) + CO = (CO+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar9.41kJ/molPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot
Quantity Value Units Method Reference Comment
Deltar88.3J/mol*KPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot

(CO+ bullet 7Carbon monoxide) + Carbon monoxide = (CO+ bullet 8Carbon monoxide)

By formula: (CO+ bullet 7CO) + CO = (CO+ bullet 8CO)

Quantity Value Units Method Reference Comment
Deltar6.61kJ/molPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot
Quantity Value Units Method Reference Comment
Deltar51.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase; break in the van't Hoff plot

(CO+ bullet 9Carbon monoxide) + Carbon monoxide = (CO+ bullet 10Carbon monoxide)

By formula: (CO+ bullet 9CO) + CO = (CO+ bullet 10CO)

Quantity Value Units Method Reference Comment
Deltar7.74kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 11Carbon monoxide) + Carbon monoxide = (CO+ bullet 12Carbon monoxide)

By formula: (CO+ bullet 11CO) + CO = (CO+ bullet 12CO)

Quantity Value Units Method Reference Comment
Deltar8.91kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 12Carbon monoxide) + Carbon monoxide = (CO+ bullet 13Carbon monoxide)

By formula: (CO+ bullet 12CO) + CO = (CO+ bullet 13CO)

Quantity Value Units Method Reference Comment
Deltar8.79kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 13Carbon monoxide) + Carbon monoxide = (CO+ bullet 14Carbon monoxide)

By formula: (CO+ bullet 13CO) + CO = (CO+ bullet 14CO)

Quantity Value Units Method Reference Comment
Deltar8.70kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 14Carbon monoxide) + Carbon monoxide = (CO+ bullet 15Carbon monoxide)

By formula: (CO+ bullet 14CO) + CO = (CO+ bullet 15CO)

Quantity Value Units Method Reference Comment
Deltar8.03kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 15Carbon monoxide) + Carbon monoxide = (CO+ bullet 16Carbon monoxide)

By formula: (CO+ bullet 15CO) + CO = (CO+ bullet 16CO)

Quantity Value Units Method Reference Comment
Deltar8.03kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

(CO+ bullet 16Carbon monoxide) + Carbon monoxide = (CO+ bullet 17Carbon monoxide)

By formula: (CO+ bullet 16CO) + CO = (CO+ bullet 17CO)

Quantity Value Units Method Reference Comment
Deltar7.87kJ/molPHPMSHiraoka and Mori, 1991gas phase
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSHiraoka and Mori, 1991gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Norwood, Guo, et al., 1989
Norwood, K.; Guo, J.H.; Luo, G.; Ng, C.Y., A Study of Intramolecular Charge Transfer in Mixed Ar/Co Dimer and Trimer Ions Using the Photoion - Photoelectron Coincidence Method, Chem. Phys., 1989, 129, 1, 109, https://doi.org/10.1016/0301-0104(89)80023-0 . [all data]

Norwood, Guo, et al., 1988
Norwood, K.; Guo, J.H.; Luo, G.; Ng, C.Y., A Photoion - Photoelectron Coincidence Study of (CO)2, J. Chem. Phys., 1988, 88, 6, 4098, https://doi.org/10.1063/1.453814 . [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., Molecular Beam Photoionization Study of CO, N2, and NO Dimers and Clusters, J. Chem. Phys., 1981, 74, 6, 3342, https://doi.org/10.1063/1.441486 . [all data]

Munson and Franlin, 1962
Munson, M.S.B. Field; Franlin, J.L., High-Pressure Mass Spectrometric Study of Reactions of Rare Gases with N2 and CO, J. Chem. Phys., 1962, 37, 8, 1790, https://doi.org/10.1063/1.1733370 . [all data]

Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

Chong and Franklin, 1971
Chong, S.L.; Franklin, J.L., High-Pressure Ion-Molecule Reactions in Carbon Monoxide and Carbon Monoxide - Methane Mixtures, J. Chem. Phys., 1971, 54, 4, 1487, https://doi.org/10.1063/1.1675043 . [all data]

Hiraoka and Mori, 1991
Hiraoka, K.; Mori, T., On the formation of the Isomeric Cluster Ions (CO)n+, J. Chem. Phys., 1991, 94, 4, 2697, https://doi.org/10.1063/1.459844 . [all data]


Notes

Go To: Top, Ion clustering data, References