Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Sulfur dioxide anion


Ion clustering data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(O2S- bullet Water bullet 3Sulfur dioxide) + Water = (O2S- bullet 2Water bullet 3Sulfur dioxide)

By formula: (O2S- bullet H2O bullet 3O2S) + H2O = (O2S- bullet 2H2O bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar29.7 ± 1.7kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar15.9 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet Water bullet 4Sulfur dioxide) + Water = (O2S- bullet 2Water bullet 4Sulfur dioxide)

By formula: (O2S- bullet H2O bullet 4O2S) + H2O = (O2S- bullet 2H2O bullet 4O2S)

Quantity Value Units Method Reference Comment
Deltar29.7 ± 2.9kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar12.6 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 2Water bullet 3Sulfur dioxide) + Water = (O2S- bullet 3Water bullet 3Sulfur dioxide)

By formula: (O2S- bullet 2H2O bullet 3O2S) + H2O = (O2S- bullet 3H2O bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar27.6 ± 1.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar12.6 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 2Water bullet 4Sulfur dioxide) + Water = (O2S- bullet 3Water bullet 4Sulfur dioxide)

By formula: (O2S- bullet 2H2O bullet 4O2S) + H2O = (O2S- bullet 3H2O bullet 4O2S)

Quantity Value Units Method Reference Comment
Deltar29.7 ± 2.9kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.9 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 4294967295Sulfur monoxide) + Sulfur monoxide = O2S-

By formula: (O2S- bullet 4294967295OS) + OS = O2S-

Quantity Value Units Method Reference Comment
Deltar516.7 ± 5.0kJ/molN/ANimlos and Ellison, 1986gas phase; B

O2S- + Sulfur dioxide = (O2S- bullet Sulfur dioxide)

By formula: O2S- + O2S = (O2S- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar100.4 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Deltar89.1 ± 5.4kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Deltar77.40kJ/molN/ADresch, Kramer, et al., 1991gas phase; Both dissociation and electron detachment?; B
Deltar76.57kJ/molN/ASnodgrass, Coe, et al., 1988gas phase; Appears to be dissociation + electron detachment; B
Quantity Value Units Method Reference Comment
Deltar141.J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar58.2 ± 1.7kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B
Deltar43.5 ± 9.2kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet Sulfur dioxide) + Water = (O2S- bullet Water bullet Sulfur dioxide)

By formula: (O2S- bullet O2S) + H2O = (O2S- bullet H2O bullet O2S)

Quantity Value Units Method Reference Comment
Deltar37.2 ± 3.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar18.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 2Sulfur dioxide) + Water = (O2S- bullet Water bullet 2Sulfur dioxide)

By formula: (O2S- bullet 2O2S) + H2O = (O2S- bullet H2O bullet 2O2S)

Quantity Value Units Method Reference Comment
Deltar31.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar15.1 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 3Sulfur dioxide) + Water = (O2S- bullet Water bullet 3Sulfur dioxide)

By formula: (O2S- bullet 3O2S) + H2O = (O2S- bullet H2O bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar31.8 ± 1.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar14.2 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 4Sulfur dioxide) + Water = (O2S- bullet Water bullet 4Sulfur dioxide)

By formula: (O2S- bullet 4O2S) + H2O = (O2S- bullet H2O bullet 4O2S)

Quantity Value Units Method Reference Comment
Deltar31.4 ± 1.7kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.8 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 5Sulfur dioxide) + Water = (O2S- bullet Water bullet 5Sulfur dioxide)

By formula: (O2S- bullet 5O2S) + H2O = (O2S- bullet H2O bullet 5O2S)

Quantity Value Units Method Reference Comment
Deltar27.2 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 5Sulfur dioxide bullet 2Water) + Sulfur dioxide = (O2S- bullet 6Sulfur dioxide bullet 2Water)

By formula: (O2S- bullet 5O2S bullet 2H2O) + O2S = (O2S- bullet 6O2S bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar15.9 ± 3.8kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.60 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 6Sulfur dioxide bullet Water) + Sulfur dioxide = (O2S- bullet 7Sulfur dioxide bullet Water)

By formula: (O2S- bullet 6O2S bullet H2O) + O2S = (O2S- bullet 7O2S bullet H2O)

Quantity Value Units Method Reference Comment
Deltar13.4 ± 2.5kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.9 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet 6Sulfur dioxide bullet 2Water) + Sulfur dioxide = (O2S- bullet 7Sulfur dioxide bullet 2Water)

By formula: (O2S- bullet 6O2S bullet 2H2O) + O2S = (O2S- bullet 7O2S bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar15.5 ± 2.9kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.5 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- bullet Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 2Sulfur dioxide)

By formula: (O2S- bullet O2S) + O2S = (O2S- bullet 2O2S)

Quantity Value Units Method Reference Comment
Deltar33.9 ± 1.3kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Deltar35.kJ/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar66.9J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar16.3 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 2Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 3Sulfur dioxide)

By formula: (O2S- bullet 2O2S) + O2S = (O2S- bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar26.8 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar12.6 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 3Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 4Sulfur dioxide)

By formula: (O2S- bullet 3O2S) + O2S = (O2S- bullet 4O2S)

Quantity Value Units Method Reference Comment
Deltar22.6 ± 1.3kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar9.20 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 4Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 5Sulfur dioxide)

By formula: (O2S- bullet 4O2S) + O2S = (O2S- bullet 5O2S)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.02 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 5Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 6Sulfur dioxide)

By formula: (O2S- bullet 5O2S) + O2S = (O2S- bullet 6O2S)

Quantity Value Units Method Reference Comment
Deltar15.1 ± 1.3kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar3.8 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 6Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 7Sulfur dioxide)

By formula: (O2S- bullet 6O2S) + O2S = (O2S- bullet 7O2S)

Quantity Value Units Method Reference Comment
Deltar14.2 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.1 ± 0.84kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 7Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 8Sulfur dioxide)

By formula: (O2S- bullet 7O2S) + O2S = (O2S- bullet 8O2S)

Quantity Value Units Method Reference Comment
Deltar14.2 ± 1.3kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar1. ± 5.0kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 8Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 9Sulfur dioxide)

By formula: (O2S- bullet 8O2S) + O2S = (O2S- bullet 9O2S)

Quantity Value Units Method Reference Comment
Deltar12.6 ± 1.7kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar1. ± 6.3kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 9Sulfur dioxide) + Sulfur dioxide = (O2S- bullet 10Sulfur dioxide)

By formula: (O2S- bullet 9O2S) + O2S = (O2S- bullet 10O2S)

Quantity Value Units Method Reference Comment
Deltar12.6 ± 2.5kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar0.4 ± 9.6kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet Sulfur dioxide bullet Oxygen) + Sulfur dioxide = (O2S- bullet 2Sulfur dioxide bullet Oxygen)

By formula: (O2S- bullet O2S bullet O2) + O2S = (O2S- bullet 2O2S bullet O2)

Quantity Value Units Method Reference Comment
Deltar19.2 ± 1.7kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar10. ± 8.4kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet 2Sulfur dioxide bullet Oxygen) + Sulfur dioxide = (O2S- bullet 3Sulfur dioxide bullet Oxygen)

By formula: (O2S- bullet 2O2S bullet O2) + O2S = (O2S- bullet 3O2S bullet O2)

Quantity Value Units Method Reference Comment
Deltar15.1 ± 1.7kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar6. ± 13.kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

(O2S- bullet Oxygen) + Sulfur dioxide = (O2S- bullet Sulfur dioxide bullet Oxygen)

By formula: (O2S- bullet O2) + O2S = (O2S- bullet O2S bullet O2)

Quantity Value Units Method Reference Comment
Deltar46.0 ± 4.2kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Deltar26. ± 9.2kJ/molTDAsVacher, Jorda, et al., 1992gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vacher, Leduc, et al., 1994
Vacher, J.R.; Leduc, E.; Fitaire, M., Stabilities of Anionic Mixed Clusters of Sulfur Dioxide and Water, Int. J. Mass Spectrom. Ion Proc., 1994, 135, 2-3, 139, https://doi.org/10.1016/0168-1176(94)03985-2 . [all data]

Nimlos and Ellison, 1986
Nimlos, M.R.; Ellison, G.B., Photoelectron spectroscopy of SO2-, S3-, and S2O-, J. Phys. Chem., 1986, 90, 2574. [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Dresch, Kramer, et al., 1991
Dresch, T.; Kramer, H.; Thurner, Y.; Weber, R., Photoelectrons from Negative Dimers and Clusters of Sulfur Dioxide, Chem. Phys. Lett., 1991, 177, 4-5, 383, https://doi.org/10.1016/0009-2614(91)85070-D . [all data]

Snodgrass, Coe, et al., 1988
Snodgrass, J.T.; Coe, J.V.; Friedhoff, C.B.; McHugh, K.M.; Bowen, K.H., On the Photodissociation of (SO2)2-, J. Chem. Phys., 1988, 88, 12, 8014, https://doi.org/10.1063/1.454261 . [all data]

Vacher, Jorda, et al., 1992
Vacher, J.R.; Jorda, M.; Leduc, E.; Fitaire, M., A Determination of the Stabilities of Negative Ion Clusters in SO2 and SO2-O2 Mixtures, Int. J. Mass Spectrom. Ion Proc., 1992, 114, 3, 149, https://doi.org/10.1016/0168-1176(92)80033-W . [all data]


Notes

Go To: Top, Ion clustering data, References