Ga2H6


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

ag 1 GaHt stretch 2000 Ar Ra Souter, Andrews, et al., 1994
1 GaHt stretch 1986 N2 Ra Souter, Andrews, et al., 1994
2 GaHb stretch 1474 Ar Ra Souter, Andrews, et al., 1994
2 GaHb stretch 1471 N2 Ra Souter, Andrews, et al., 1994
3 GaH2 deform. 736 Ar Ra Souter, Andrews, et al., 1994
3 GaH2 deform. 733 N2 Ra Souter, Andrews, et al., 1994
b2u 8 GaHt stretch 1993 m gas IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
8 GaHt stretch 2015 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
8 GaHt stretch 1996 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
8 GaHt stretch 1995.0 H2 IR Wang and Andrews, 2003
8 GaHt stretch 2000 m N2 IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
9 GaH2 rock 760 w gas IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
9 GaH2 rock 773 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
9 GaH2 rock 761 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
9 GaH2 rock 770 m N2 IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
b1g 11 GaHt stretch 2011 Ar Ra Souter, Andrews, et al., 1994
11 GaHt stretch 1997 N2 Ra Souter, Andrews, et al., 1994
b1u 13 GaHb stretch 1202 s gas IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
13 GaHb stretch 1213 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
13 GaHb stretch 1208 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
13 GaHb stretch 1195 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
13 GaHb stretch 1202 H2 IR Wang and Andrews, 2003
13 GaHb stretch 1220 s N2 IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
14 GaH2 rock? 659 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
14 GaH2 rock? 655 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
14 GaH2 rock? 653 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
14 GaH2 rock? 648 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
14 GaH2 rock? 655 s N2 IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
14 GaH2 rock? 647 w N2 IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
b3g 15 GaH2 deform. 763 Ar Ra Souter, Andrews, et al., 1994
15 GaH2 deform. 761 N2 Ra Souter, Andrews, et al., 1994
b3u 16 GaHt stretch 1976 m gas IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
16 GaHt stretch 1985 s Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
16 GaHt stretch 1968 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
16 GaHt stretch 1975.7 H2 IR Wang and Andrews, 2003
16 GaHt stretch 1985 m N2 IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
17 GaHb stretch 1273 s gas IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
17 GaHb stretch 1283 s Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
17 GaHb stretch 1278 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
17 GaHb stretch 1253 m Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
17 GaHb stretch 1272 H2 IR Wang and Andrews, 2003
17 GaHb stretch 1282 m N2 IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
18 GaH2 bend 671 vs T gas IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
18 GaH2 bend 676 vs Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
18 GaH2 bend 666 s Ar IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991
18 GaH2 bend 671 H2 IR Wang and Andrews, 2003
18 GaH2 bend 673 vs N2 IR Downs, Goode, et al., 1989
Pulham, Downs, et al., 1991

Additional references: Jacox, 1994, page 372; Jacox, 1998, page 333

Notes

wWeak
mMedium
sStrong
vsVery strong
TTentative assignment or approximate value

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Souter, Andrews, et al., 1994
Souter, P.F.; Andrews, L.; Downs, A.J.; Greene, T.M.; Ma, B.; Schaefer, H.F., III, Observed and calculated Raman spectra of the Ga2H6 and Ga2D6 molecules, J. Phys. Chem., 1994, 98, 49, 12824, https://doi.org/10.1021/j100100a004 . [all data]

Downs, Goode, et al., 1989
Downs, A.J.; Goode, M.J.; Pulham, C.R., Gallane at last! Synthesis and properties of binary gallium hydride, J. Am. Chem. Soc., 1989, 111, 5, 1936, https://doi.org/10.1021/ja00187a090 . [all data]

Pulham, Downs, et al., 1991
Pulham, C.R.; Downs, A.J.; Goode, M.J.; Rankin, D.W.H.; Robertson, H.E., Gallane: synthesis, physical and chemical properties, and structure of the gaseous molecule Ga2H6 as determined by electron diffraction, J. Am. Chem. Soc., 1991, 113, 14, 5149, https://doi.org/10.1021/ja00014a003 . [all data]

Wang and Andrews, 2003
Wang, X.; Andrews, L., Infrared Spectra of Gallium Hydrides in Solid Hydrogen: GaH, J. Phys. Chem. A, 2003, 107, 51, 11371, https://doi.org/10.1021/jp035393d . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References