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Indium monoxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference
13.3 ± 0.2EIGomez, Chatillon, et al., 1982

Constants of diatomic molecules

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through January, 1977

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for (115)In16O
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
A 23595.1 626.66 H 3.40  1      A rarrow X RV 23557.0 H
missing citation
23033.1 626.66 H 3.40  1      A rarrow X RV 22995.0 H
missing citation
(X 2Sigma) 0 703.09 H 3.71 -0.285 1       

Notes

1A satisfactory interpretation of the observed bands is still lacking; see Watson and Shambon, 1936, Howell, 1945. Preliminary rotational analysis of two bands by Jacquinot and Lavendy, 1975.
2The lower limit is D00(InS); the upper limit, also based on mass-spectrometric evidence, was estimated by Burns, DeMaria, et al., 1963, Colin and Drowart, 1968.

References

Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gomez, Chatillon, et al., 1982
Gomez, M.; Chatillon, C.; Allibert, M., Thermodynamics of gaseous and condensed indium oxides by mass spectrometry with controlled oxygen oressure, J. Chem. Thermodyn., 1982, 14, 447. [all data]

Watson and Shambon, 1936
Watson, W.W.; Shambon, A., The spectrum of indium oxide, Phys. Rev., 1936, 50, 607. [all data]

Howell, 1945
Howell, H.G., Resonance in precessional states of diatomic molecules, Proc. Phys. Soc. London, 1945, 57, 32. [all data]

Jacquinot and Lavendy, 1975
Jacquinot, D.; Lavendy, H., Analyse de rotation de la transition 2«SIGMA»+ --> 2«SIGMA»+ de InO, C.R. Acad. Sci. Paris, Ser. B, 1975, 281, 397. [all data]

Burns, DeMaria, et al., 1963
Burns, R.P.; DeMaria, G.; Drowart, J.; Inghram, M.G., Mass spectrometric investigation of the vaporization of In2O3, J. Chem. Phys., 1963, 38, 1035. [all data]

Colin and Drowart, 1968
Colin, R.; Drowart, J., Mass spectrometric determination of dissociation energies of gaseous indium sulphides, selenides and tellurides, J. Chem. Soc. Faraday Trans., 1968, 64, 2611. [all data]


Notes

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