Molybdenum,tricarbonyl[(1,2,3,4,5,6-η)-1,3,5-cycloheptatriene]-

• Formula: C₁₀H₈MoO₃
• Molecular weight: 272.13
• IUPAC Standard InChI: InChI=1S/C7H8.3CO.Mo/c1-2-4-6-7-5-3-1;3*1-2;/h1-6H,7H2;;;; Copy

  
• IUPAC Standard InChIKey: WQAVHVQYKSYTII-UHFFFAOYSA-N Copy
• CAS Registry Number: 12125-77-8
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Cycloheptatriene molybdenum tricarbonyl; Molybdenum, tricarbonyl(1,3,5-cycloheptatriene)-; Tricarbonyl(η-1,3,5-cycloheptatriene)molybdenum; Tricarbonyl(cycloheptatriene)molybdenum; Molybdenum,tricarbonyl[(1,2,3,4,5,6-η⁶)-1,3,5-cycloheptatriene]-; tricarbonyl[(1,2,3,4,5,6-η)cyclohepta-1,3,5-triene]molybdenum
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Brown, Connor, et al., 1977
Brown, D.L.S.; Connor, Joseph A.; Demain, Christopher P.; Leung, May L.; Martinho-Simoes, Jose A.; Skinner, Henry A.; Zafarani Moattar, Mohamed T., The thermochemistry of carbonyl complexes of Cr, Mo, Wand Co with arenes, cycloheptatriene, and norbornadiene, Journal of Organometallic Chemistry, 1977, 142, 3, 321-335, https://doi.org/10.1016/S0022-328X(00)88348-5 . [all data]

Fragala, Ciliberto, et al., 1979
Fragala, I.; Ciliberto, E.; Granozzi, G.; Deganello, G., He-I and He-II excited photoelectron spectra of cycloheptatrienetricarbonyl complexes of group VIA metals, J. Organomet. Chem., 1979, 182, 511. [all data]

Gower, Kane-Maguire, et al., 1977
Gower, M.; Kane-Maguire, L.A.P.; Maier, J.P.; Sweigart, D.A., Ultraviolet photoelectron spectra of cyclohepta-1,3,5-triene and mesitylene tricarbonyl complexes of the group 6A metals, J. Chem. Soc. Dalton Trans., 1977, 316. [all data]

Notes

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• Symbols used in this document:
  

  ΔsubH°

  Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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