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Carbon disulfide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CS2- + Carbon disulfide = (CS2- bullet Carbon disulfide)

By formula: CS2- + CS2 = (CS2- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar21.9 ± 1.5kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Deltar4.4 ± 1.1kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B
Deltar4.10 ± 0.60kcal/molLPESBowen and Eaton, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar30.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.5kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(CS2- bullet Carbon disulfide) + Carbon disulfide = (CS2- bullet 2Carbon disulfide)

By formula: (CS2- bullet CS2) + CS2 = (CS2- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar4.60 ± 0.70kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B
Deltar6.4 ± 1.4kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.1 ± 3.3kcal/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(CS2- bullet 3Carbon disulfide) + Carbon disulfide = (CS2- bullet 4Carbon disulfide)

By formula: (CS2- bullet 3CS2) + CS2 = (CS2- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 6.7kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(CS2- bullet 4Carbon disulfide) + Carbon disulfide = (CS2- bullet 5Carbon disulfide)

By formula: (CS2- bullet 4CS2) + CS2 = (CS2- bullet 5CS2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 6.6kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(CS2- bullet 2Carbon disulfide) + Carbon disulfide = (CS2- bullet 3Carbon disulfide)

By formula: (CS2- bullet 2CS2) + CS2 = (CS2- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar-23.40kcal/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K., Frontier-controlled Structures of the Gas Phas Clusters A+/-(CS2)n, A+/- = S2+, CS2+, S2-, and CS2-, J. Phys. Chem. (1994), 1994, 98, 7, 1802-1809, https://doi.org/10.1021/j100058a014 . [all data]

Tsukuda, Hirose, et al., 1997
Tsukuda, T.; Hirose, T.; Nagata, T., Negative-ion photoelectron spectroscopy of (CS2)(n)(-): coexistence of electronic isomers, Chem. Phys. Lett., 1997, 279, 3-4, 179-184, https://doi.org/10.1016/S0009-2614(97)01021-X . [all data]

Bowen and Eaton, 1988
Bowen, K.H.; Eaton, J.G., Photodetachment Spectroscopy of Negative Cluster Ions, in The Structure of Small Molecules and Ions, Ed. R. Naaman, Z. Vager, Plenum NY, 1988, 1988, p.147-169. [all data]

Hiraoka, Fujimaki, et al., 1994, 2
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Frontier-Controlled Structures of the Gas-Phase A+-(CS2)n Clusters ,A+- = S2+, CS2+, S2-, and CS2-, J. Phys. Chem., 1994, 98, 7, 1802, https://doi.org/10.1021/j100058a014 . [all data]


Notes

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