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Chromium, tricarbonyl[(1,2,3,4,5,6-«eta»)-hexamethylbenzene]-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
6.4 ± 0.1EIGilbert, Leach, et al., 1973LLK
6.88EIMuller, 1969RDSH
7.24 ± 0.05CTSHuttner and Fischer, 1967RDSH
7.00PEConnor, Martinho-Simoes, et al., 1979Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C11H12O2Cr+6.5 ± 0.1COEIGilbert, Leach, et al., 1973LLK
C12H18+8.6 ± 0.1?EIGilbert, Leach, et al., 1973LLK
C12H18Cr+9.8 ± 0.13COEIGilbert, Leach, et al., 1973LLK
C13H18OCr+7.7 ± 0.12COEIGilbert, Leach, et al., 1973LLK
Cr+13.0 ± 0.1?EIGilbert, Leach, et al., 1973LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gilbert, Leach, et al., 1973
Gilbert, J.R.; Leach, W.P.; Miller, J.R., Ionisation appearance potential measurements in arene chromium tricarbonyls, J. Organomet. Chem., 1973, 49, 219. [all data]

Muller, 1969
Muller, J., Ionisierungspotentiale von substituierten Benzolchrom-tricarbonyl-Komplexen, J. Organometal. Chem., 1969, 18, 321. [all data]

Huttner and Fischer, 1967
Huttner, G.; Fischer, E.O., Uber Aromatenkomplexe von Metallen. XCVIII. Spectroskopische Untersuchungen an Charge-Transfer-Komplexen von Aromaten-Chrom Tricarbonylen mit 1,3,5-Trinitrobenzol, J. Organometal. Chem., 1967, 8, 299. [all data]

Connor, Martinho-Simoes, et al., 1979
Connor, J.A.; Martinho-Simoes, J.A.; Skinner, H.A.; Zafarani-Moattar, M.T., Thermochemistry of bis-arene arenetricarbonyl-chromium compounds containing hexamethylbenzene, 1,3,5-tri-methylbenzene and naphthalene, J. Organomet. Chem., 1979, 179, 331. [all data]


Notes

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