Ferrocene-d10
- Formula: C10D10Fe
- Molecular weight: 196.093
- CAS Registry Number: 12082-87-0
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Enthalpy of phase transition
| ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|---|
| 0.878 | 164.1 | crystaline, III | crystaline, II | Sorai and Shiomi, 1984 | Lambda transition. Secondary Cp maximum at 172 K. |
| 4.230 | 251. | crystaline, II | crystaline, I | Sorai and Shiomi, 1984 | |
| 0.878 | 164.1 | crystaline, III | crystaline, II | Shiomi and Sorai, 1983 | Lambda type transition in the metastable state. |
| 4.230 | 251. | crystaline, II | crystaline, I | Shiomi and Sorai, 1983 | Phase transition between stable LT and stable HT phases. |
Entropy of phase transition
| ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
|---|---|---|---|---|---|
| 5.27 | 164.1 | crystaline, III | crystaline, II | Sorai and Shiomi, 1984 | Lambda |
| 16.83 | 251. | crystaline, II | crystaline, I | Sorai and Shiomi, 1984 | |
| 5.27 | 164.1 | crystaline, III | crystaline, II | Shiomi and Sorai, 1983 | Lambda |
| 16.83 | 251. | crystaline, II | crystaline, I | Shiomi and Sorai, 1983 | Phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sorai and Shiomi, 1984
Sorai, M.; Shiomi, Y.,
Thermodynamic properties of ferrocene-d10 crystal: comparison with ferrocene-h10,
Mol. Cryst. Liq. Cryst., 1984, 107, 271-292. [all data]
Shiomi and Sorai, 1983
Shiomi, Y.; Sorai, M.,
Heat capacity in the range 13 to 300 K and phase transitions of ferrocene-d10,
Chem. Phys. Lett., 1983, 95(2), 167-170. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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