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Manganese, tricarbonyl(«eta»5-2,4-cyclopentadien-1-yl)-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-473.5 ± 5.4kJ/molReviewMartinho Simões 
Deltafgas-490.3 ± 9.0kJ/molReviewMartinho Simões 
Deltafgas-426. ± 3.kJ/molReviewMartinho Simões 
Deltafgas-481.9 ± 9.0kJ/molReviewMartinho SimõesSelected data. Average of the values from Evstigneeva and Shmyreva, 1965 and Lautsch, Erzberger, et al., 1958

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-525.9 ± 4.4kJ/molReviewMartinho SimõesMS
Deltafsolid-542.7 ± 8.5kJ/molReviewMartinho SimõesMS
Deltafsolid-534.3 ± 8.4kJ/molReviewMartinho SimõesSelected data. Average of the values from Evstigneeva and Shmyreva, 1965 and Lautsch, Erzberger, et al., 1958; MS
Deltafsolid-478. ± 1.kJ/molCC-SBChipperfield, Sneyd, et al., 1979Value corrected based on a set of ancillary data by J.A. Martinho Simões; The value for the enthalpy of combustion is not reported in Chipperfield, Sneyd, et al., 1979; MS
Quantity Value Units Method Reference Comment
Deltacsolid-3858.1 ± 4.2kJ/molCC-SBEvstigneeva and Shmyreva, 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Deltacsolid-3841.3 ± 8.4kJ/molCC-SBLautsch, Tröber, et al., 1963Please also see Lautsch, Erzberger, et al., 1958, Pedley and Rylance, 1977, and Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
solid,1 bar259.35J/mol*KN/AChhor, Pommier, et al., 1983DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
214.79298.15Chhor, Pommier, et al., 1983T = 10 to 300 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Heptane (solution) = C14H21MnO2 (solution) + Carbon monoxide (solution)

By formula: C8H5MnO3 (solution) + C7H16 (solution) = C14H21MnO2 (solution) + CO (solution)

Quantity Value Units Method Reference Comment
Deltar196. ± 7.kJ/molAVGN/AAverage of 18 values; Individual data points

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Evstigneeva and Shmyreva, 1965
Evstigneeva, E.V.; Shmyreva, G.O., Russ. J. Phys. Chem., 1965, 39, 529. [all data]

Lautsch, Erzberger, et al., 1958
Lautsch, W.F.; Erzberger, P.; Tröber, A., Wiss. Z. Tech. Hochsch. Chem. Leuna-Merseburg, 1958, 1, 31. [all data]

Chipperfield, Sneyd, et al., 1979
Chipperfield, J.R.; Sneyd, J.C.R.; Webster, D.E., J. Organometal. Chem., 1979, 178, 177. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Chhor, Pommier, et al., 1983
Chhor, K.; Pommier, C.; Diot, M., Low-temperature thermodynamic study of cymantrene (C5H5Mn(CO)3) and azacymantrene (C4H4NMn(CO)3), Mol. Cryst. Liq. Cryst., 1983, 100, 193-209. [all data]


Notes

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