«eta»4-Trimethylenemethane-iron tricarbonyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
0.910647IMRESharpe and Kebarle, 1993«DELTA»Gea(343 K)= -17.0 kcal/mol; «DELTA»Sea estimated as -10 eu; B

Ionization energy determinations

IE (eV) Method Reference Comment
8.32 ± 0.02PEDewar and Worley, 1969RDSH
8.63PEWorley, Webb, et al., 1980Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharpe and Kebarle, 1993
Sharpe, P.; Kebarle, P., Electron Affinities, Enthalpy, and Entropy of Electron Attachment of Several eta-4-(Olefin)Fe(CO)3 Complexes and Electron-Transfer Kinetics, J. Am. Chem. Soc., 1993, 115, 2, 782, https://doi.org/10.1021/ja00055a059 . [all data]

Dewar and Worley, 1969
Dewar, M.J.S.; Worley, S.D., Photoelectron spectrum of trimethylenemethane iron tricarbonyl and a theoretical study of trimethylenemethane, J. Chem. Phys., 1969, 51, 1672. [all data]

Worley, Webb, et al., 1980
Worley, S.D.; Webb, T.R.; Gibson, D.H.; Ong, T.-S., The photoelectron spectra of some iron tricarbonyl complexes of 4«pi»-electron donor ligands, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 189. [all data]


Notes

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