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«eta»5-Cyclopentadienylnitrosylnickel


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
Proton affinity (review)827.0kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity798.6kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.5EIMuller and Goll, 1975LLK
8.29PEEvans, Guest, et al., 1974LLK
8.5 ± 0.1EIFoffani, Pignataro, et al., 1967RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C5H5Ni+10.5?EIMuller and Goll, 1975LLK
Ni+14.8?EIMuller and Goll, 1975LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Muller and Goll, 1975
Muller, J.; Goll, W., Ion-molekul-reaktionen von (cyclopentadienyl)- nitrosylnickel mit «sigma»- und «pi»-donatoren in der gasphase, Chem. Ber., 1975, 106, 1129. [all data]

Evans, Guest, et al., 1974
Evans, S.; Guest, M.F.; Hillier, I.H.; Orchard, A.F., Theoretical and experimental study of the low energy ionic states of «pi»-cyclopentadienyl- nickel nitrosyl, J. Chem. Soc. Faraday Trans. 2, 1974, 70, 417. [all data]

Foffani, Pignataro, et al., 1967
Foffani, A.; Pignataro, S.; Distefano, G.; Innorta, G., Influence of the ligand donor ability on the ionization potentials and fragmentation patterns of transition metal nitrosyl complexes, J. Organometal. Chem., 1967, 7, 473. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References