dilithium oxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to Li2O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)1206.kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity1175.3kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
6.0EIIkeda, Tamaki, et al., 1982LBLHLM
6.4 ± 0.2EINakagawa, Asano, et al., 1981LLK
6.19 ± 0.20EIHildenbrand, 1972LLK
6.3 ± 1.0EIYamdagni, Pupp, et al., 1970RDSH
7.0 ± 0.5EIZmbov, Ficalora, et al., 1968RDSH
6.9 ± 0.3EIWhite, Seshadri, et al., 1963RDSH
6.8 ± 0.2EIBerkowitz, Chupka, et al., 1959RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Ikeda, Tamaki, et al., 1982
Ikeda, Y.; Tamaki, M.; Matsumoto, G.; Amioka, K.; Mizuno, T., Mass spectrometric studies of lithium-containing oxides at high temperatures, Spectrochim. Acta Part B, 1982, 37, 647. [all data]

Nakagawa, Asano, et al., 1981
Nakagawa, H.; Asano, M.; Kubo, K., Mass spectrometric study of the vaporization of lithium metasilicate, J. Nucl. Mater., 1981, 102, 292. [all data]

Hildenbrand, 1972
Hildenbrand, D.L., Thermochemistry of the molecular species LiO, LiO+, and Li2O+., J. Chem. Phys., 1972, 57, 4556. [all data]

Yamdagni, Pupp, et al., 1970
Yamdagni, R.; Pupp, C.; Porter, R.F., Mass spectrometric study of the evaporation of lithium and sodium molybdates and tungstates, J. Inorg. Nucl. Chem., 1970, 32, 3509. [all data]

Zmbov, Ficalora, et al., 1968
Zmbov, K.F.; Ficalora, P.; Margrave, J.L., Mass spectrometric studies at high temperatures. XXVIII. Gaseous ternary oxides, LiMO and LiMO2, J. Inorg. Nucl. Chem., 1968, 30, 2059. [all data]

White, Seshadri, et al., 1963
White, D.; Seshadri, K.S.; Dever, D.F.; Mann, D.E.; Linevski, M.J., Infrared spectra and the structures and thermodynamics of gaseous LiO, Li2O, and Li2O2, J. Chem. Phys., 1963, 39, 2463. [all data]

Berkowitz, Chupka, et al., 1959
Berkowitz, J.; Chupka, W.A.; Blue, G.D.; Margrave, J.L., Mass spectrometric study of the sublimation of lithium oxide, J. Phys. Chem., 1959, 63, 644. [all data]


Notes

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