Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Titanium monosulfide


Gas phase ion energetics data

Go To: Top, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.1 ± 0.3EIEdwards, Franzen, et al., 1971LLK

Constants of diatomic molecules

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through June, 1975

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for (48)Ti32S
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
C 3Delta3 (11806) 484.12 Z 2.55  0.18905 0.00102 -1.3E-5 [1.22E-7]  2.1610 C lrarrow X R 11582.25 Z
Clements and Barrow, 1969
C 3Delta2 (11716) 484.30 Z 2.515  0.18820 1 0.00099 -1.95 [1.20E-7]  2.1610 C lrarrow X R 11587.05 Z
Clements and Barrow, 1969
C 3Delta1 11624.3    [0.18684] 2  [1.06E-7]  2.1610 C lrarrow X R 11585.31 Z
Clements and Barrow, 1969
(X) 3Delta3 (185) 3 [558.17] Z (1.95)  0.20344 0.00092  [1.12E-7]  2.0825  
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
(X) 3Delta2 (90) 3 [558.30] Z (1.95)  0.20268 0.00092  [1.095E-7]  2.0825  
(X) 3Delta1 0 [558.37] Z (1.95)  0.20180 0.00090  [1.035E-7]  2.0825  

Notes

1Small perturbations in v=0.
2Extensive perturbations.
3Estimated from the effective B values.
4Thermochemical value (mass-spectrometry) Smoes, Coppens, et al., 1969; see also Franzen, 1962 [quoted in Suzuki and Wahlbeck, 1966].

References

Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Edwards, Franzen, et al., 1971
Edwards, J.G.; Franzen, H.F.; Gilles, P.W., High-temperature mass spectrometry, vaporization, and thermodynamics of titanium monosulfide, J. Chem. Phys., 1971, 54, 545. [all data]

Clements and Barrow, 1969
Clements, R.M.; Barrow, R.F., Rotational analysis of bands of infra-red system of gaseous TiS, Trans. Faraday Soc., 1969, 65, 1163-1167. [all data]

Smoes, Coppens, et al., 1969
Smoes, S.; Coppens, P.; Bergman, C.; Drowart, J., Mass spectrometric determination of the dissociation energies of the gaseous rare earth monosulphides, Trans. Faraday Soc., 1969, 65, 682. [all data]

Franzen, 1962
Franzen, Thesis, University of Kansas, Kansas, 1962, 1. [all data]

Suzuki and Wahlbeck, 1966
Suzuki, A.; Wahlbeck, P.G., Vaporization study of the titanium-tellurium system, J. Phys. Chem., 1966, 70, 6, 1914-1923. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, References