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vanadium dioxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.83570 ± 0.00050N/AKim, Weichman, et al., 2014B
2.030 ± 0.010LPESWu and Wang, 199814KIM/WEi: this energy is an incorrect assignment; B
2.31 ± 0.21R-ARudnyi, Kaibicheva, et al., 1993value altered from reference due to conversion from electron convention to ion convention; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.7 ± 0.2EIBennett, Lin, et al., 1974LLK
10. ± 2.EIFarber, Uy, et al., 1972LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kim, Weichman, et al., 2014
Kim, J.B.; Weichman, M.L.; Neumark, D.M., Vibronic structure of VO2 probed by slow photoelectron velocity-map imaging spectroscopy, J. Chem. Phys., 2014, 140, 3, 034307, https://doi.org/10.1063/1.4861667 . [all data]

Wu and Wang, 1998
Wu, H.; Wang, L.-S., A Photoelectron Spectroscopic Study of Monovanadium Oxide Anions (VOx-, x=1-4), J. Phys. Chem., 1998, 108, 13, 5310, https://doi.org/10.1063/1.475966 . [all data]

Rudnyi, Kaibicheva, et al., 1993
Rudnyi, E.B.; Kaibicheva, E.A.; Sidorov, L.N., Negative Ions VO2(-), VO3(-), V2O5(-), V3O8(-), and V4O10(-) in the Vapors of Vanadium Oxides - Determining Enthalpies of Formation from Equ, J. Chem. Thermodyn., 1993, 25, 8, 929, https://doi.org/10.1006/jcht.1993.1090 . [all data]

Bennett, Lin, et al., 1974
Bennett, S.L.; Lin, S.-S.; Gilles, P.W., High-temperature vaporization of ternary systems. I. Mass spectrometry of oxygen-rich vanadium-tungsten-oxygen species, J. Phys. Chem., 1974, 78, 266. [all data]

Farber, Uy, et al., 1972
Farber, M.; Uy, O.M.; Srivastava, R.D., Effusion-mass spectrometric determination of the heats of formation of the gaseous molecules V4O10, V4O8, VO2, and VO, J. Chem. Phys., 1972, 56, 5312. [all data]


Notes

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